相关期刊:《Chemical Research in Chinese Universities》《Modeling and Numerical Simulation of Material Science》《Journal of Environmental Sciences》《Science China Chemistry》更多>>
supported by the National Natural Science Foundation of China (52203241,21905225,22005121);the Science and Technology Program of Shaanxi Province (2022JM-229,2023-JC-QN-0448);Jiangsu Key Laboratory for Carbon-Based Functional Materials&Devices,Soochow University (KJS2208);H.Y.W.acknowledges the financial support from the National Research Foundation of Korea (2019R1A6A1A11044070,2020M3H4A3081814).
Developing novel unfused building blocks with simple synthesis and low cost is essential to advance and enrich cost-effective poly-mer donors;however,it remains a challenge due to the lack of efficient molecular strat...
supported the Natural Science Foundation of Higher Education Institutions in Anhui Province(2022AH030133,2022AH051340);National Natural Science Foundation of China(22231003,22271008);Shenzhen Science and Technology Program(Grant No.KQTD20190929174023858);Shenzhen Science and Technology Innovation Committee(GXWD20201231165807007-20200812100115001);Shenzhen-Hong Kong Institute of Brain Science-Shenzhen Fundamental Research Institutions(2023SHIBS0004);Horizontal Cooperation Project of Fuyang Municipal Government(SXHZ202201);Key Projects of the Support Program for Outstanding Young Talents in Anhui Province Colleges and Universities(gxyqZD2020030);Yifan Pharmaceutical Co.,Ltd.(HX2019033);Innovative Drug Design&Development Collaborative Team(TDYY2021009).
A metal-free,green,and sustainable functionalization of unactivated alkyl sp^(3) C—H bonds is reported using iodine(III)as a feasible dehydrogenation agent under visible light or KBr,and alkyl chlorides,bromides,alco...
the National Natural Science Foundation of China(No.21105091)for financial support.
A CuX-mediated regioselective halogenation reaction of 2-phenylimidazo[1,2-a]pyridine in the presence of oxygen is introduced in this paper.This reaction provides an effective method for the production of C-3 halogena...
financial support from the NSFC(Nos.21871096,22071062,22001077);the Ministry of Science and Technology of the People’s Republic of China(No.2016YFA0602900);the Guangdong Science and Technology Department(Nos.2018B030308007,2021A1515012331);the China Postdoctoral Science Foundation(Nos.2018M643062,2019T120723).
A TEMPO catalyzed cross-dihalogenation reaction was established via redox-regulation of the otherwise complex system of dual electrophilic X+reagents.Formally,the ICl,BrCl,I_(2) and Br_(2) were generated in-situ,which...
the National Key R&D Program of China(No.2019YFC0312501);the National Natural Science Foundation of China(No.31929001);the Special Project for Marine Economic Development(Six Major Marine Industries)of Guangdong Province Department of Natural Resources of Guangdong Province(No.[2020]039);the Construction Project of Shanghai Key Laboratory of Molecular Imaging(No.18DZ2260400);the Innovative Research Team of High-Level Local Universities in Shanghai,and the Taishan Scholar Project from Shandong Province to H.L.The authors are grateful to Ying Wu for QTOF mass analysis,Hong-Yan Liu for NMR analysis,and Prof.Meifeng Tao from School of Life Sciences and Biotechnology,Shanghai Jiao Tong University for kindly providing the indicator strains for bioactivity assay.
Four new chlorinated carbazole alkaloids,chlocarbazomycins(CCBs)A-D,were isolated from sponge associated bacterium Streptomyces diacarni LHW51701.Their structures were elucidated via spectroscopic techniques(including...
the National Natural Science Foundation of China (No.21520102003);Introducing Talents of Discipline to Universities of China (111 Program).
We herein uncovered an electrochemical C—H halogenation protocol that synergistically combines anodic oxidation and cathodic reduction for C—X bond formation. The reaction was demonstrated under exogenous-oxidant-fr...
A general atom-economical approach for the synthesis of a-halomethyl ketones is demonstrated through Ce(SO4)z/acid co-catalyzed hydration of a wide range of haloalkynes. The reactions are conducted under convenient ...
Project supported by the National Natural Science Foundation of China (No. 20172016) and the Shanghai Phosphor Project of Science & Technology for Excellent Young Research (No. 01QA14017).
HX is immobilized by reaction of halogen acid with methylimidazole, and the formed ionic liquid [Hmim]X was used as halogenating agent, catalyst as well as medium for conversion of alcohols to alkyl halides. Excellent...
Project (No. 29170084) supported by the National Natural Science Foundation of China
Synthesis and characterization of (Z)-1-[2-(triphenylstannyl)vinylj-l-cyclododecanol,c-(CH2)11C(OH)CH=CHSnPh3,are reported,together with its halogenation by I2,Br2 and IC1 to yield derivatives of the types c-(CH2)11C(...
Project (No. 29632003 and No. 29672041) supported by the National Natural Science Foundation of China.
Halogenation of the potassium or silver salts of bis(trifluoromethanesulfonyl)methane (CF3SO2)2CH2 and its cyclo analogues 1 with N-fluoro-bis(trifluoromethanesulfonyl)imine [(CF3SO3)2NF], chlorine or bromine gave goo...