DICHLOROCARBENE

作品数:11被引量:9H指数:2
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相关领域:理学更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Chinese Journal of Chemistry》《Science China Chemistry》《Chemical Research in Chinese Universities》更多>>
相关基金:国家自然科学基金更多>>
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Quantum chemical study on insertion and abstraction reaction of dichlorocarbene with methyl alcohol and methyl mercaptan被引量:1
《Science China Chemistry》2009年第3期304-312,共9页LI ZhiFeng ZHU YuanCheng LI HuiXue LIU XinWen LU XiaoQuan 
Supported by the National Natural Science Foundation of China (Grant No. 20335030);Foundation of Education Committee of Gansu Province (Grant No. 0708-11)
The insertion and abstraction reaction mechanisms of singlet and triplet CCl2 with CH3MH (M=O, S) have been studied by using the DFT, NBO and AIM methods. The geometries of reactions, the transition state and products...
关键词:CARBENE alcohol DFT NBO AIM INSERTION REACTION abstraction REACTION 
A New Target for Synthesis: Theoretical Prediction for the Reaction between Boron Nitride Nanotube and Dichlorocarbene被引量:1
《Chinese Journal of Structural Chemistry》2009年第1期113-119,共7页李瑞芳 尚贞锋 王贵昌 许秀芳 
supported by the National Natural Science Foundation of China (No 20303010, 20273034 and 20673063);NKStar HPC Program The authors appreciate the assistance provided by Professor Zun-Sheng Cai
Understanding the chemistry of BNNT is a crucial step toward their ultimate practical use. A comparative study of Reactions A (ASWCNT (5,5) and CCl2) and B (ASWBNNT (5,5) and CCl2) have been performed by using...
关键词:carbon nanotube boron nitride nanotube DICHLOROCARBENE reaction mechanism theoretical study 
Preparation and Characterization of Dichlorocarbene Modified Multiple-walled Carbon Nanotubes被引量:2
《Chemical Research in Chinese Universities》2007年第5期505-507,共3页YU Jin-gang HUANG Ke-long HONG Yong HUANG Du-shu 
Supported by the National Natural Science Foundation of China(Nos.20576142and50772133);the Doctor's Scientific Re-search and Innovation Foundation of Central South University of China(No.134376211).
Multiple-walled carbon nanotubes were functionalized by cycloaddition of dichlorocarbene.The chemical modification was performed by using chloroform and sodium hydroxide.Various phase transfer catalysts were used to i...
关键词:Multiple-wa/led carbon nanotubes MODIFICATION DICHLOROCARBENE 
Theoretical Study on the Reaction Mechanism between Dichlorocarbene and Armchair Single-walled Carbon Nanotubes
《Chinese Journal of Structural Chemistry》2006年第9期1120-1128,共9页LI Rui-Fang SHANG Zhen-Feng XU Xiu-Fang WANG Gui-Chang 
This work was supported by the National Natural Science Foundation of China (No. 20303010), NKStar HPC Program and the Science Foundation of Nankai University
The reaction mechanism between CC12 and armchair single-walled carbon nanotubes (ASWCNTs) (3,3) and (4,4) has been studied by semiempirical AM1 and ab initio methods. The activation barriers of CC12 adding to AS...
关键词:armchair single-walled carbon nanotubes DICHLOROCARBENE reaction mechanism theoretical study 
Characteristics of mass spectra of dichlorocarbene derivatives of isomeric dodecen-1-ols
《Chinese Journal of Chemistry》2000年第2期198-200,共3页袁谷 魏颜军 陈钢 
Project supported by the National Natural Science Foundation of China (No. 29575190) and the Foundation of Bioorganee and Molecular Engineering Laboratory.
The m/z of characteristic ion of the mass spectra of the dichlorocarbene of dodecen-1-ols was used as a parameter to locate the position of double bond in these isomers by a new formula.
关键词:Mass spectra isomeric dodecen-1-ols double bond 
Cycloaddition of benzoheteroazepine Ⅲ Reaction of 2,3-dihydro-lH-l,5-benzodiazepines with dichlorocarbene and stereo-structures of products被引量:1
《Chinese Journal of Chemistry》1999年第4期404-410,4,共8页张新宇 许家喜 金声 
Reaction of 2,3-dihydro-1H-l,5-benzodiazepines with dichlorocarbene generated in situ using benzyltriethylammonium chloride (TEBA) as a phase transfer catalyst in chloroform-aqueous sodium hydroxide mixture gave main...
关键词:BENZODIAZEPINE azirinobenzodiazepine DICHLOROCARBENE cycloaddition. 
Trapping of the Dichlorocarbene Intermediate in the Reaction of α-Cyanobenzyl carbanion with Carbon Tetrachloride被引量:1
《Chinese Chemical Letters》1998年第10期895-896,共2页Jin Pei CHENG Zi Rong ZHENG(Department of Chemistry, Nankai University, Tianjin 300071) 
In Me2SO, an X-philic reaction took place between α-cyanobenzyl carbanion and CCl4. The intermediate dichlorocarbene was trapped by the primary product dicyanostilbene to give the alkene-carbene adduct, 1, 1-dichloro...
关键词:DICHLOROCARBENE S_N2vs. ET mechanism CCl_4 
REACTION OF HETEROCYCLIC KETENE AMINALS WITH DICHLOROCARBENE被引量:1
《Chinese Chemical Letters》1995年第1期5-8,共4页Zhi Tang HUANG Jian Chao WANG and Li Ben WANG Institute of Chemistry, Academia Sinica. Beijing, 100080.Absrtact: Heterocyclic ketene aminals 1 or 2 react with dichlorocarbene to give the formyl substituted heterocylic ketene aminals 3 or 4through the ca 
REACTIONOFHETEROCYCLICKETENEAMINALSWITHDICHLOROCARBENEZhiTangHUANG;JianChao;WANGandLiBenWANGInstituteofChemi...
INSERTION OF PTC-GENERATED DICHLOROCARBENE INTO C-B BO ND.A FACILE SYNTHESIS OF KETONES FROM ALKENES VIA ORGANOBORATES
《Chinese Chemical Letters》1993年第6期471-474,共4页De Jie ZHAO Tian Yi KE Chang Mei KE Zi Xing SHAN Chemistry Department,Wuhan University,Wuhan 430072 
The insertion of dichlorocarbene generated from chloroform by Phase Transfer Catalysis(PTC)into carbon-boron bond of dialkylborate anions 3,obtained by method A and B,resulted in the formation of the inter- mediates 5...
关键词:CI INSERTION OF PTC-GENERATED DICHLOROCARBENE INTO C-B BO ND.A FACILE SYNTHESIS OF KETONES FROM ALKENES VIA ORGANOBORATES PTC CHC TEBA OH BO ND VIA 
NEW HETEROCYCLIC SYSTEM SYNTHESIS III REACTIONS OF 1,2-DIHYDRO-2,4-DISUBSTITUTED-1,5-BENZODIAZEPINE WITH DICHLOROCARBENE
《Chinese Chemical Letters》1992年第3期179-180,共2页Xin Yu ZHANG Sheng JIN Ren An LIAO 
Three kinds of products have been separated from the reaction mixtures of 1,2-dihydro-2, 4-disubstituted-1,5-benzodiazepine with: CCI_2.Besides the addition products of: CCI_2 to C=N.the inserted products of: CCI_2 to...
关键词:CCI Pro NEW HETEROCYCLIC SYSTEM SYNTHESIS III REACTIONS OF 1 2-DIHYDRO-2 4-DISUBSTITUTED-1 5-BENZODIAZEPINE WITH DICHLOROCARBENE III 
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