ALLYLTRICHLOROSILANE

作品数：4被引量：2H指数：1
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相关期刊：《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》《复旦学报（自然科学版）》更多>>
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Enantioselective Addition of Allyltrichlorosilane to Bulky-substituted Aldehydes Catalyzed by Axial N,N'-Dioxide Pivalate被引量：1
《Chemical Research in Chinese Universities》2019年第4期604-608,共5页WANG Jie WU Shijie WANG Xiaoke LI Longfei YANG Kan ZHU Huajie LI Wan LIU Li 
Allylation of bulky-substituted aromatic aldehydes with allyltrichlorosilanes were catalyzed by axial biscarboline N.N-dioxide esters with high enaiitioselectivities up to 92% e.e. for l-(4-chlorophenyl)-9-methyl-9Hpy...
关键词：Enantioselective ALLYLATION Biscarboline N N'-dioxide pivalate DRIVING-FORCE Catalytic space 
Asymmetric Synthesis of Novel Axially Chiral 2,2＇-Bipyridine N,N＇-Dioxides Bearing α-Amino Acid Residues and Their Applications in Enantioselective Allylation of Aromatic Aldehydes with Allyltrichlorosilane被引量：1
《Chinese Journal of Chemistry》2013年第4期485-493,共9页Hongwu Zhao Yuanyuan Yue Hailong Li Zhihui Sheng Zhao Yang Wei Meng 
We thank Beijing Municipal Commission of Edu- cation （No. JC015001200902）, Beijing Municipal Natu- ral Science Foundation （Nos. 710201, 2122008）, Basic Research Foundation of Beijing University of Technol- ogy （X40 15001201101）, Funding Project for Academic Human Resources Development in Institutions ofHigher Learning Under the Jurisdiction of Beijing Municipality （No. PHR201008025）, Doctoral Scientific Research Start-up Foundation of Beijing University of Technology （No. 52015001200701） for financial sup- ports.
A series of novel axially chiral 2,2＇-bipyridine N,N＇-dioxides bearing C1 or C2-symmetry have been synthesized by the use of enantiopure a-amino acids as chiral sources. The absolute stereochemistry of the axial chi...
关键词：2 2＇-bipyridine N N＇-dioxide organocatalyst asymmetric catalysis enantioselective allylation allyl-trichlorosilane 
Chiral Phosphoric Acid Catalyzed Enantioselective Allylation of Aldehydes with Allyltrichlorosilane
《Chinese Journal of Chemistry》2011年第8期1669-1671,共3页程柯 范甜甜 孙健 
Project supported by the National Natural Science Foundation of China （Nos. 20732006 and 20972152）.
Easily accessible chiral phosphoric acid lb has been applied as efficient organocatalyst for the asymmetric al- lylation of aldehydes with allyltrichlorosilane. In the presence of 20 mol% of lb, the allylation of a br...
关键词：phosphoric acid ALLYLATION ALDEHYDES ALLYLTRICHLOROSILANE 
Synthesis of Chiral Sulfoxides and Application in Enantioselective Allylation of Aldehydes with Allyltrichlorosilane
《复旦学报（自然科学版）》2007年第5期571-,共1页A.Massa V.De Sio R.Villano A.Scettri 
1 Results The enantioselective addition of allylic organometallic reagents to aldehydes is a fundamental tool in organic synthesis.The high degree of both diastereo-and enantioselectivity gives the possibility to obta...
关键词：SULFOXIDES lewis bases ORGANOCATALYSIS allylation reaction 
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