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Room-Temperature Electroreductiveα-Alkylation of N-Heteroarenes with Styrenes
《CCS Chemistry》2024年第2期342-352,共11页Maorui Wang Chengqian Zhang He Zhao Huanfeng Jiang Pierre HDixneuf Min Zhang 
support of the National Natural Science Foundation of China(grant no.21971071);the Natural Science Foundation of Guangdong Province(grant no.2021A1515010155).
Despite their interesting applications,direct and diverse syntheses of aryl-fused 2-alkyl cyclic amines still remain challenging.Here,the concept of incorporating a C–C coupling process into the N-heteroaryl reductio...
关键词：electroreductive C-C cross-coupling N-heteroarenes STYRENES 2-alkyl cyclic amines ALKYLATION 
High-Performance D-A Copolymer Donor Based on Difluoroquinoxaline A-Unit with Alkyl-Chlorothiophene Substituents for Polymer Solar Cells被引量：2
《CCS Chemistry》2023年第10期2378-2388,共11页Can Zhu Ke Hu Lei Meng Xiaolei Kong Wenbin Lai Shucheng Qin Beibei Qiu Jinyuan Zhang Zhanjun Zhang Yilei Wu Xiaojun Li Yongfang Li 
supported by National Key Research and Development Program of China(grant no.2019YFA0705900)funded by MOST,the National Natural Science Foundation of China(grant nos.51820105003,21734008,61904181,and 52173188);the Key Research Program of the Chinese Academy of Sciences(grant no.XDPB13);the Basic and Applied Basic Research Major Program of Guangdong Province(grant no.2019B030302007);Y.W.acknowledges financial support from the Office of Naval Research(award no.N00014-19-1-2453);the use of the Stanford Synchrotron Radiation Light-source,SLAC National Accelerator Laboratory,which is supported by the U.S.Department of Energy,Office of Science,Office of Basic Energy Sciences(contract no.DE-AC02-76SF00515).
Side chain engineering with fluorine substitution is widely used to enhance photovoltaic performance of polymer donors in the research field of polymer solar cells(PSCs).However,fluorine substitution has disadvantages...
关键词：D-A copolymer donors polymer solar cells difluoroquinoxaline A-unit chlorothiophene substituents 
Visible Light Promoted Direct Deuteration of Alkenes via Co(III)–H Mediated H/D Exchange被引量：1
《CCS Chemistry》2023年第5期1069-1076,共8页Zongbin Jia Sanzhong Luo 
the Natural Science Foundation of China(grant nos.91956000,22031006,21861132003),Tsinghua University Initiative Scientific Research Program,and Haihe Laboratory of Sustainable Chemical Transformations for financial support.
We report herein a visible light-mediated direct deuteration of alkenes with D_(2)O or deuterated methanol(MeOD)using a cobaloxime as a hydrogen/deuterium(H/D)exchange catalyst.The synergistic photoredox/Co catalysis ...
关键词：DEUTERATION COBALOXIME hydrogen isotope exchange alkyl cobalt PHOTOREDOX 
Catalytic[2+2+2]Tandem Cyclization with Alkyl Substituted Methylene Malonate Enabling Concise Total Synthesis of Four Malagasy Alkaloids
《CCS Chemistry》2023年第1期124-132,共9页Yu-Jing Cheng Liu-Peng Zhao Lijia Wang Yong Tang 
This research was made possible as a result of a generous grant from the National Natural Science Foundation of China(NSFC,grant nos.21772224 and 91956103).
Myrtoidine and malagashanine,highly complex indole alkaloids,are effective adjuvants in developing cures for plasmodium malaria and potent multi-drug resistant agents.Despite nearly 30 years of progress,myrtoidine and...
关键词：tandem cyclization [2+2+2] methylene malonate indole alkaloids myrtoidine malagashanine 
Transition-Metal-Free Reductive Cross-Coupling Employing Metabisulfite as a Connector:General Construction of Alkyl–Alkyl Sulfones被引量：2
《CCS Chemistry》2021年第12期17-24,共8页Yingying Meng Ming Wang Xuefeng Jiang 
support provided by NSFC(nos.22071057,21971065,and 21871089);STCSM(nos.20XD1421500,20JC1416800,and 18JC1415600);Innovative Research Team of High-Level Local Universities in Shanghai(no.SSMU-ZLCX20180501);Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning.
A multicomponent reductive cross-coupling of unactivated alkyl halides and alkyl tosylates connected via sodium metabisulfite was established for the general construction of alkyl-alkyl sulfones.Neither a metal cataly...
关键词：alkyl sulfone formate sodium metabisulfite reductive cross-coupling transition-metal-free 
Rational Preparation of Atomically Precise Non-Alkyl Tin-Oxo Clusters with Theoretical to Experimental Insights into Electrocatalytic CO_(2)Reduction Applications
《CCS Chemistry》2021年第10期2607-2616,共10页Di Wang Zhe-Ning Chen Qing-Rong Ding Cheng-Cheng Feng San-Tai Wang Wei Zhuang Lei Zhang 
supported by the National Natural Science Foundation of China(nos.91961108,21922111,and 21973094);the National Key Research and Development Program of China(no.2017YFA0206801);the Strategic Priority Research Program of the Chinese Academy of Sciences(no.XDB20000000);the Natural Science Foundation of Fujian Province(no.2019J01131).
Tin oxides(SnO_(2))have been widely utilized in electronics,nanolithography,and catalysis.As the atomically precise models of SnO_(2),tin-oxo clusters(TOCs)not only provide opportunities for mechanism studies,but they...
关键词：cluster compounds tin oxides atomic structure green synthesis electrocatalytic CO_(2)red uction 
Iron-Catalyzed Borylation and Silylation of Unactivated Tertiary,Secondary,and Primary Alkyl Chlorides
《CCS Chemistry》2021年第9期2164-2173,共10页Siyu Wang Minghui Sun Huan Zhang Juan Zhang Yun He Zhang Feng 
support from the National Natural Science Foundation of China(no.21801029);the Fundamental Research Funds for the Central Universities(no.2020CDJQY-A043);the Sichuan Key Laboratory of Medical Imaging(North Sichuan Medical College,no.SKLMI201901);the Strategic Cooperation of Science and Technology between Nanchong City and North Sichuan Medical College(nos.19SXHZ0441 and 19SXHZ0227);the Chongqing Postdoctoral Science Foundation(no.cstc2020jcyj-bsh0061);the China Postdoctoral Science Foundation(no.2020M673121);the Natural Science Foundation of Chongqing(no.cstc2019jcyj-msxmX0048).
Herein,we describe an iron-catalyzed borylation and silylation of unactivated alkyl chlorides,delivering the tertiary,secondary,and primary alkylboronic esters,and secondary,primary alkylsilanes with high efficiency.T...
关键词：iron catalysis BORYLATION SILYLATION unactivated alkyl chlorides 
Degradable Hybrid CuS Nanoparticles for Imaging-Guided Synergistic Cancer Therapy via Low-Power NIR-II Light Excitation被引量：3
《CCS Chemistry》2021年第5期1336-1349,共14页Yidan Sun Hua Shi Xiaoyang Cheng Luyan Wu Yuqi Wang Zhengyang Zhou Jian He Hong-Yuan Chen Deju Ye 
Financial supports from the National Key R&D Program of China(no.2017YFA0701301);the National Natural Science Foundation of China(nos.21922406,21775071,and 21632008);the Natural Science Foundation of Jiangsu Province(no.BK20190055);the Fundamental Research Funds for the Central Universities(no.020514380185);the Excellent Research Program of Nanjing University(no.ZYJH004)are acknowledged.
Near-infrared(NIR)-II light-excitable photonic agents capable of generating tumor hyperthermia and cytotoxic free radicals are promising for synergistic phototherapy of tumors.However,the lack of NIR-II excitable agen...
关键词：NIR-II copper sulfide alkyl radical synergistic therapy imaging 
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