HYDROACYLATION

作品数：7被引量：3H指数：1
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相关期刊：《Science China Chemistry》《Chinese Journal of Chemistry》《Chinese Chemical Letters》《CCS Chemistry》更多>>
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Homogeneous catalysis and heterogeneous separation:Ionic liquids as recyclable photocatalysts for hydroacylation of olefins
《Chinese Chemical Letters》2025年第2期389-393,共5页Hao-Cong Li Ming Zhang Qiyan Lv Kai Sun Xiao-Lan Chen Lingbo Qu Bing Yu 
financial support from the National Natural Science Foundation of China(Nos.22071222,22171249);the Natural Science Foundation of Henan Province(Nos.232300421363,242300420526);Key Research Projects of Universities in Henan Province(No.23A180010);Science&Technology Innovation Talents in Universities of Henan Province(No.23HASTIT003);Science and Technology Research and Development Plan Joint Fund of Henan Province(No.242301420006)。
The photoinduced ligand-to-metal charge transfer(LMCT)process has been extensively investigated,however,the recovery of photocatalysts has remained a persistent challenge in the field.In light of this issue,a novel ap...
关键词：LMCT Ionic liquids Homogeneous catalysis Heterogeneous separation Recyclable photocatalysts 
Visible-Light-Mediated Photocatalyst-Free Hydroacylation of Azodicarboxylic Acid Derivatives with 4-Acyl-1,4-dihydropyridines
《Chinese Journal of Chemistry》2024年第11期1230-1236,共7页Li Liu Jing Wang Xiaoying Feng Kun Xu Wei Liu Xia Peng Hongguang Du Jiajing Tan 
support from the National Natural Science Foundation of China(21702013 and 22271010);the Fundamental Research Funds for the Central Universities(XK1802-6)at the BUCT.
A visible-light-enabled,photocatalyst-free hydroacylation reaction of azodicarboxylic acid derivatives was described.This radical conjugate addition(RCA)protocol relied on the dual role of 4-acyl-1,4-dihydropyridine(a...
关键词：Azo compounds Radicals ACYLATION 4-Acyl-1 4-dihydropyridine PHOTOCHEMISTRY 
Formal Deoxygenative Cross-Coupling of Aldehydes to Ketones throughα-Haloboronates:A Route to Deoxygenative Hydroacylation of Aldehydes
《Chinese Journal of Chemistry》2023年第24期3593-3597,共5页Zihao Hu Wanqi Zhang Tao XU 
the National Natural Science Foundation of China(Grant No.22071183)for financial support.
Aldehydes are a kind of important synthons and reagents in organic synthesis.The efforts on transformations of aldehydes are highly rewarding and have always attracted considerable attention.Herein,a cross-coupling of...
关键词：CROSS-COUPLING Haloboronate Nickel Deoxygenative difunctionalization of carbonyls Photocatalysis 
Base-Promoted Catalyst-Free Regioselective Hydroacylation of Styrenes with Hydrazones via Carbanion Addition
《CCS Chemistry》2022年第10期3254-3263,共10页Pan Pan Yatao Lang Dawei Cao Huiying Zeng Chao-Jun Li 
from the National Natural Science Foundation of China(grant no.21971093);the International Joint Research Centre for Green Catalysis and Synthesis(grant no.2016B01017),and the 111 project.
Wereport a base-promoted catalyst-free protocol for the highly regioselective hydroacylation of styrenes with hydrazones derived from naturally abundant aldehydes.This protocolgeneratedlinearketoneswith goodfunctional...
关键词：CATALYST-FREE regioselective hydroacylation hydrazone carbanion addition base-promoted 
Ketone Synthesis by Direct, Orthogonal Chemoselective Hydroacylation of Alkenes with Amides: Use of Alkenes as Surrogates of Alkyl Carbanions被引量：3
《Chinese Journal of Chemistry》2019年第8期811-816,共6页Hui Geng Pei-Qiang Huang 
support provided by the National Key R&D Program of China (No.2017YFA0207302);the National Natural Science Foundation of China (Nos.21672176 and 21332007).
Summary of main observation and conclusion Direct functionalization of alkenes and direct transformation of carboxamides are two exciting areas that have attracted considerable attention in recent years.We report here...
关键词：ALKENES AMIDES ALKYL CARBANIONS 
Mechanistic study on the regioselectivity of Co-catalyzed hydroacylation of 1,3-dienes
《Chinese Chemical Letters》2015年第1期58-62,共5页Yuan-Ye Jiang Hai-Zhu Yu Jing Shi 
the NSFC(Nos.21325208,21172209,21361140372,21202006);SRFDP(No.20123402110051);FRFCU(No.WK2060190025);CAS(No.KJCX2-EW-J02);Fok Ying Tung Education Foundation,Anhui Provincial Natural Science Foundation(No.1308085QB38);China National Grid Project funded by MOE of China;the supercomputer center of Shanghai and USTC
Density functional theory（DFT） method was used to explore the origin of the regioselectivity of Cocatalyzed hydroacylation of 1,3-dienes.The reaction of 2-methyl-1,3-butadiene and benzaldehyde with1,3-bis（diphenylp...
关键词：Density functional theory COBALT Regioselectivity HYDROACYLATION 
A theoretical study on the mechanisms of intermolecular hydroacylation of aldehyde catalyzed by neutral and cationic rhodium complexes
《Science China Chemistry》2014年第9期1264-1275,共12页WANG Min ZHANG Xin CHEN Zhuo TANG YanHui LEI Ming 
supported by the National Natural Science Foundation of China(21373023,21203006,21072018)
In this paper, we used density functional theory(DFT) computations to study the mechanisms of the hydroacylation reaction of an aldehyde with an alkene catalyzed by Wilkinson's catalyst and an organic catalyst 2-amino...
关键词：C-H activation DFT HYDROACYLATION metal organic cooperative catalyst reaction mechanism rhodium complex 
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