supported by the National Key Research and Development Project of China(No.2022YFE0113800);the National Natural Science Foundation of China(No.22102013);Natural Science Foundation of Chongqing(No.cstc2021jcyj-msxmX0945);Venture and Innovation Support Program for Chongqing Overseas Returnees(No.cx2020107);Thousand Talents Program for Distinguished Young Scholars,Postdoctoral Fellowship Program of CPSF(No.GZB20230910)。
Propane dehydrogenation(PDH)is a vital industrial process for producing propene,utilizing primarily Cr-based or Pt-based catalysts.These catalysts often suffer from challenges such as the toxicity of Cr,the high costs...
supported by the National Natural Science Foundation of China(Nos.82130103,82151525 and 81903465);the Central Plains Scholars and Scientists Studio Fund(2018002);the Natural Science Foundation of Henan Province(No.212300410051);the Science and Technology Major Project of Henan Province(No.221100310300)。
Herein,we report the dynamic kinetic resolution asymmetric acylation ofγ-hydroxy-γ-perfluoroalkyl butenolides/phthalides catalyzed by amino acid-derived bifunctional organocatalysts,and a series of ketals were obtai...
supported financially by the Youth Innovation Promotion Association CAS(No.2022375);National Nature Science Foundation of China(No.22171258);the Biological Resources Programme,Chinese Academy of Sciences(No.KFJ-BRP-008);the Sichuan Science and Technology Program(No.2022ZYD0038)。
Increasing interests of difluorinated amino acids(DFAAs)have been raised in recent years due to their widespread bio-organic and medical applications.However,to date,only few investigations focused on their asymmetric...
supported by the Educational Foundation of Zhejiang University of Technology(No.KYY-HX-20220471)。
A copper-catalyzed three-component reaction involving cyclic carbonates,elemental sulfur,and H-phosphonates is presented.It proceeds with excellent yields and provides an attractive approach for the construction of va...
funding support of the National Natural Science Foundation of China(NSFC,Nos.22071060 and 22031004);the National Key R&D Program of China(No.2021YFF0701600);Shanghai Municipal Education Commission(No.20212308)。
Metal-catalyzed alkene arylalkoxylation is a powerful complexity-building strategy for the synthesis of oxygen heterocycles from simpleγ-unsaturated alcohols,but only a few examples of catalytic enantioselective meth...
Financial support from the NSFC(Nos.21972073,22136003,21805166 and 22206188);the 111 Project of China(No.D20015)and Natural Science Foundation of Hubei Province,China(No.2022CFB275)is gratefully acknowledged。
Sodium percarbonate(Na_(2)CO_(3)·1.5H_(2)O_(2),SPC)has been extensively employed as a solid substitute of H_(2)O_(2)for Fenton process in water treatment,because of its high stability during the production,transport,...
supported by the Youth Innovation Promotion Association,CAS(No.2018456);Major Program of Lanzhou Institute of Chemical Physics,CAS(No.ZYFZFX-10);State Key Laboratory Program of the Lanzhou Institute of Chemical Physics,CAS(No.CHGZ-202211).
In Fenton-like oxidation,the catalyst directly influences the reaction mechanism for the degradation of pollutants from water.Here,a α-MnO_(2)catalyst(OAm-1)was synthesized via a self-assembly method with the assista...
the National Key R&D Program of China(No.2022YFA1302900 to H.Liu);National Natural Science Foundation of China(Nos.82130105,22337003,82121005 to H.Liu;and Nos.22177124,82322063 to J.Wang);Program of Shang-hai Academic Research Leader(No.23XD1460300 to J.Wang);the Lingang Laboratory(No.LG-GG-202204-02 to J.Wang)for supporting this work.We would like to acknowledge Shanghai Highline Therapeutics.
Heterocycle-braced cyclic peptides have demonstrated enhanced metabolic stability,increased potency and selectivity.Here,we present a rapid synthesis method for constructing Trp(C7)-alkene(E)-crosslinked cyclic peptid...
supported by the National Natural Science Foundation of China(NSFC,Nos.22002023,21973113,21977019);the Guangdong Natural Science Funds for Distin-guished Young Scholar(No.2015A030306027);the Tip-top Youth Talents of Guangdong special support program(No.20153100042090537);the Fundamental Research Funds for the Central Universities。
Herein,we report the NHC-Ru catalyst system that realizes the chemo-selective transformation of ketones with methanol.By simply changing the base,a broad range of structurally diverse ketones,could be selectively and ...
supported by the National Natural Science Foundation of China(NSFC,Nos.22001251,21922112,and 22225107);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);National Key R&D Program of China(No.2017YFA0700103);the Guizhou Provincial S&T Project(No.2018[4007]).
Borylation of 1,3-enynes with bis(boronate)compounds often ends up with the formation of hydroborylated products,leaving the diborylation of 1,3-enynes for the formation of 1,4-diborylated allenes to be challenging.He...