supported by the National Natural Science Foundation of China(21961045 and 22061048);Yunnan Provincial Key Laboratory Construction Plan Funding of Universities,the Reserve Talents of Young and Middle-aged Academic Leaders of Yunnan Province(202005AC160016);Yunnan Provincial Engineering Research Center Construction Plan Funding of Universities.
An efficient stereoselective cobalt-catalyzed hydrovinylative cyclization of 1,6-enynes with chalcones toobtain functionalized pyrrolidines has been developed. The products were furnished in good yields withup to 93% ...
support from the National Natural Science Foundation of China(Nos.22171046 and 21901041);the Hundred-Talent Project of Fujian(No.50012742);Fuzhou University(No.510841)is gratefully acknowledged.
A cobalt-catalyzed modular[3+2]assembling of unsaturated hydrocarbons andβ-dicarbonyls isreported.This protocol features mild reaction conditions and a broad substrate scope,providing facileentries toward diverse mul...
support from the National Natural Science Foundation of China(21772043);the Shanghai Pujiang Program(No.19PJ1403000)is greatly acknowledged.
We report a KOtBu-catalyzed α-homoallylic alkylation of lactams with 1,3-dienes. With this transitionmetal-free and atom-economical protocol, a variety of α-homoallylic alkylated lactams bearingα-quaternary carbon ...
supported by the National Natural Science Foundation of China(Grants 21903071);the Program for Science Technology Innovation Talents in Universities of Henan Province(No.20HASTIT004).
The mechanism and the regioselectivity of Pd-catalyzed B(4)–H arylation and B(4,5)–H diarylation foro-carborane with bidentate directing groups were investigated. The complete catalytic cycle involves Pdmediated con...
We appreciate Sichuan Agricultural University for financial support.
The catalyticα-C–H fluorination of aryl acetic acids was achieved with good functional group tolerance in the presence of a boron catalyst.A series ofα-fluoro aryl acetic acids were obtained in a single step with h...
Jialun Li thanks the China Scholarship Council(CSC)for a PhD fellowship(202108050140).
An unsymmetrical diboron,(pin)B–B(aam),is smoothly added across a carbon–carbon triple bond of various terminal alkynes under platinum catalysis,resulting in the regio-and stereoselective formation of cis-vic-dibory...
We thank the National Science Foundation of China(22001051);the start-up funding of Hangzhou Normal University for financial support。
A nickel-catalyzed reductive cross coupling between organic iodides and thiosulfonates and a selenosulfo-nate under mild conditions is disclosed.This practical method provides a facile access to a series of unsym-metr...
We thank the National Natural Science Foundation of China(No.21625203 and 21871126);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2021ZD01)for financial support.
A new method for the synthesis of 3-ethynyl-1-methylene-1,2-dihydronaphthalenes via copper-pro-moted palladium-catalyzed intermolecular alkynylative[5+1]carboannulation of 1-arylphenyl-prop-2-yn-1-yl acetates involvin...
supported by the Department of Science and Technology(DST)INSPIRE faculty award[DST/INSPIRE/04/2016/000414]。
The increasing demand for the development of unprecedented routes to access fluorinated molecules hasled researchers to perform intriguing research around the world. In this context, fluorinating reagents andfluorinat...
Financial support from the NSFC(21925109,21772170,21801223,and 21772179);the China Postdoctoral Science Foundation(No.2020M671689);the Center of Chemistry for Frontier Technologies of Zhejiang University is gratefully acknowledged.
Transition-metal-catalyzed asymmetric C–H functionalization has gradually emerged as a powerful tool for the creation of structural and chiral complexity in an atom-and step-economical fashion.The nature of this stra...