The synthesis of phosphine compounds through the addition reaction of H-[P(O)]species to olefins and alkynes has been extensively studied.Two different mechanisms of the addition of H-[P(O)]species to non-activated al...
An organophosphoric acid catalyzed[3+3]cyclization of 2-arylidene-indan-1,3-diones with enaminones has been established,which afforded a series of structurally diverse indenoquinolinedione derivatives in moderate to e...
The propargylation of various nucleophiles including indoles,phenol,anisole,enoxysilanes,and alcohols was rapidly achieved using catalytic copper(Ⅱ)triflate.The reaction conditions are mild,allowing for quick reactio...
A photoredox-catalyzed cascade carbon/carboxylation of activated alkenes with malonates acetals and CO_(2) has been achieved,leading to a range of functionalized 1,1,3-tricarboxylates in good efficiency under mild rea...
Development of catalytic methods using CO_(2)/H_(2) as methylating reagent for selective methylation of amines is highly attractive.Herein,the methylation of N—H bond via boron promoted activation of Co-formate inter...
Allylic amines and 1,3-oxazinanes are valuable molecular skeletons in organic synthesis and pharmaceutical industry.A straightforward way to such two types of compounds by solvent-controlled rare-earth metal Lewis aci...
Project supported by the National Natural Science Foundation of China (No. 20172039).
The investigation of the chemistry of indoles has been, and continues to be, one of the most active areas of heterocyclic chemistry.[1] In particular, β-indolylketones have received much attention as important bu...
Project supported by the National Natural Science Foundation of China (No. 20172039).
Indole fragment is featured widely in a wide variety of pharmacologically and biologically active compounds.[1] The 3,3-bis(3-indolyl)oxindole has been shown to possess antibiotic activities against Escherichia coli, ...
Porphyrins are very important substances used in a wide range of model systems in many areas, such as biomimic chemistry and material science. This kind of macrocycle generally consists of 5-membered ring to form ...
Project supported by the Natural Science Foundation of Gansu Province (No. YS-011-A25-001).
Asymmetric C-C bond forming reactions are of prime importance in modem synthetic organic chemistry. The use of chiral amino alcohol ligands is widespread in this area.[1] Herein, we describe the synthesis of N-sul...