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作品数:1132被引量:1374H指数:10
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相关领域:理学更多>>
相关作者:滕怀龙祝诗发陈自立姚小泉石先莹更多>>
相关机构:中国科学院南开大学郑州大学武汉大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家教育部博士点基金更多>>
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Advances in Mechanistic Studies of Metal-Catalyzed Hydrophosphinylation of Non-Activated Alkynes
《有机化学》2024年第12期3678-3685,共8页Liu Yi-Yu Hu Yudong Zhang Qing-Wei 
国家自然科学基金(No.22071224)资助项目.
The synthesis of phosphine compounds through the addition reaction of H-[P(O)]species to olefins and alkynes has been extensively studied.Two different mechanisms of the addition of H-[P(O)]species to non-activated al...
关键词:HYDROPHOSPHORYLATION mechanistic study Chalk-Harrod type mechanism proton transfer ligand to ligand hydrogen transfer 
Organophosphoric Acid Catalyzed[3+3]Cyclization for the Synthesis of Indenoquinolinedione Derivatives
《有机化学》2024年第12期3727-3738,共12页Guo Xinyan Yu Haolei Wan Honglin Lu Yua Tan Wei Shi Feng 
国家自然科学基金(Nos.22125104,22301112);江苏省自然科学基金(No.BK20210916);本科生创新项目(Nos.202410320104Y,XSJCX14139);江苏省优秀科技创新团队资助项目.
An organophosphoric acid catalyzed[3+3]cyclization of 2-arylidene-indan-1,3-diones with enaminones has been established,which afforded a series of structurally diverse indenoquinolinedione derivatives in moderate to e...
关键词:organophosphoric acid [3+3]cyclization ORGANOCATALYSIS ENAMINONE 1 4-DIHYDROPYRIDINE 
Cu(OTf)_(2) Catalyzed Rapid Nucleophilic Substitution of Propargyl Alcohols
《有机化学》2024年第11期3531-3540,共10页Shunji Zhang Huili Liu Yun Jin 
安徽高校自然科学研究(No.2022AH050409)资助项目。
The propargylation of various nucleophiles including indoles,phenol,anisole,enoxysilanes,and alcohols was rapidly achieved using catalytic copper(Ⅱ)triflate.The reaction conditions are mild,allowing for quick reactio...
关键词:Cu(OTf)_(2) CATALYSIS propargyl alcohol VELOCITY nucleophilic substitution 
Visible-Light Photoredox-Catalyzed Carbon/Carboxylation of Alkenes with Malonates and CO_(2)
《有机化学》2024年第10期3159-3168,共10页Zhang Aolong Yang Han Cheng Peidong Yao Yang Sun Song 
国家自然科学基金(No.21602019);环保功能吸附材料制备技术国地联合工程实验室开放基金(No.SDGC2125)资助项目.
A photoredox-catalyzed cascade carbon/carboxylation of activated alkenes with malonates acetals and CO_(2) has been achieved,leading to a range of functionalized 1,1,3-tricarboxylates in good efficiency under mild rea...
关键词:carbon dioxide CARBOXYLATION alkene difunctionalization visible-light catalyzed 
Boron-Promoted Co-Catalyzed N-Methylation of Secondary Aromatic Amines with CO_(2) and H_(2)
《有机化学》2024年第10期3233-3240,共8页Shi Qin Li Zhen He Lin Li Yudong Li Yuehui 
国家自然科学基金(Nos.22022204,22102197);江苏省国家自然基金(Nos.BK20211096,BK20211093)资助项目.
Development of catalytic methods using CO_(2)/H_(2) as methylating reagent for selective methylation of amines is highly attractive.Herein,the methylation of N—H bond via boron promoted activation of Co-formate inter...
关键词:CO_(2)/H_(2) N-METHYLATION cobalt catalysis 
Solvent-Controlled Sc(OTf)_(3)-Catalyzed Ring Opening Reaction of 2-(Hetero)aryl-N-sulfonylazetidines:Synthesis of Allylic Amines/1,3-Oxazinane Derivatives
《有机化学》2024年第9期2796-2809,共14页Zhu Jie Tang Sidan Kan Xiumei Fan Shizhu Wang Pengfei Yang Peijun 
国家自然科学基金(No.22001007);安徽工程大学科研基金(No.2020YQQ025);安徽省重点分子基材料省级实验室开放基金(No.fzj22012)资助项目.
Allylic amines and 1,3-oxazinanes are valuable molecular skeletons in organic synthesis and pharmaceutical industry.A straightforward way to such two types of compounds by solvent-controlled rare-earth metal Lewis aci...
关键词:rare-earth metal Lewis acid solvent control AZETIDINE regioselectivity ring opening reaction 
An Expeditious Synthesis of β-Indolylketones Catalyzed by p-Toluenesulfonic Acid (PTSA) Using Ultrasonic Irradiation
《有机化学》2004年第z1期260-261,共2页WANG,Shun-Yi SHI,Hai-Bin JI,Shun-Jun 
Project supported by the National Natural Science Foundation of China (No. 20172039).
  The investigation of the chemistry of indoles has been, and continues to be, one of the most active areas of heterocyclic chemistry.[1] In particular, β-indolylketones have received much attention as important bu...
Facile Synthesis of 3,3-Di(1H-indol-3-yl)indolin-2-ones Catalyzed by Ceric Ammonium Nitrate (CAN) under Ultrasound Irradiation
《有机化学》2004年第z1期262-263,共2页WANG,Shun-Yi ZENG,Xiao-Fei ZHOU,Wei-Juan JI,Shun-Jun 
Project supported by the National Natural Science Foundation of China (No. 20172039).
Indole fragment is featured widely in a wide variety of pharmacologically and biologically active compounds.[1] The 3,3-bis(3-indolyl)oxindole has been shown to possess antibiotic activities against Escherichia coli, ...
Gold-catalyzed Synthesis of Pyridine Containing Macrocycles, Related to Porphyrin
《有机化学》2004年第z1期59-,共1页DYKER,Gerald LIU,Jian-Hui MERZ,Klaus 
  Porphyrins are very important substances used in a wide range of model systems in many areas, such as biomimic chemistry and material science. This kind of macrocycle generally consists of 5-membered ring to form ...
Enantioselective Addition of Diethylzinc to Aldehydes Catalyzed by N-Sulfonylated Amino Alcohols
《有机化学》2004年第z1期172-,共1页HUI,Xin-Ping XU,Peng-Fei GAU,Han-Mou 
Project supported by the Natural Science Foundation of Gansu Province (No. YS-011-A25-001).
  Asymmetric C-C bond forming reactions are of prime importance in modem synthetic organic chemistry. The use of chiral amino alcohol ligands is widespread in this area.[1] Herein, we describe the synthesis of N-sul...
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