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作品数:1141被引量:1378H指数:10
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相关领域:理学更多>>
相关作者:滕怀龙祝诗发陈自立姚小泉石先莹更多>>
相关机构:中国科学院南开大学郑州大学武汉大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家教育部博士点基金更多>>
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Iron carbide-catalyzed deoxygenative coupling of benzyl alcohols toward bibenzyls under hydrogen atmosphere
《Chinese Journal of Catalysis》2025年第4期179-186,共8页Yichao Wang Leilei Zhang Xiaoli Pan Aiqin Wang Tao Zhang 
国家重点研发计划(2023YFA1506603);国家自然科学基金(22132006,22172159);中国科学院稳定支持基础研究领域青年团队计划(YSBR-022);中国科学院青年创新促进会(2022185).
The direct deoxygenative homo-coupling of benzyl alcohols holds great promise to build up bibenzyl motifs in organic synthesis,yet it remains a grand challenge in selectivity and activity control.Herein,we first disco...
关键词:Deoxygenative coupling reaction Benzyl alcohols BIBENZYLS Iron carbide Hydrogen atmosphere 
Pt nanocluster-catalyzed hydrogen evolution reaction:Recent advances and future outlook
《Chinese Chemical Letters》2025年第3期52-69,共18页Hongliang Zeng Yuan Ji Jinfeng Wen Xu Li Tingting Zheng Qiu Jiang Chuan Xia 
the National Key Research and Development Program of China(No.2022YFB4102000);the National Natural Science Foundation of China(NSFC,Nos.22102018 and 52171201);the Huzhou Science and Technology Bureau(No.2022GZ45);the Hefei National Research Center for Physical Sciences at the Microscale(No.KF2021005);the China Postdoctoral Science Foundation-Funded Project(No.2022M710601);the Huzhou Science and Technology Bureau(No.2023GZ02);the Natural Science Foundation of Sichuan Province(No.24NSFSC5779)。
As hydrogen energy technologies gain momentum,the role of renewable energy in facilitating sustainable hydrogen production is becoming increasingly critical.As a hydrogen production method,water electrolysis has attra...
关键词:PLATINUM NANOCLUSTERS Electronic interaction Hydrogen evolution Active sites 
Photoredox-catalyzed synthesis of α,α-difluoromethyl-β-alkoxysulfones from sulfur dioxide
《Chinese Chemical Letters》2025年第3期248-252,共5页Minjun Yin Yuhui Lin Manli Zhuang Wei Xiao Jie Wu 
Financial support from National Natural Science Foundation of China(Nos.22201202,22171206 and 22371201);Natural Science Foundation of Zhejiang Province(No.LZ23B020001);Open Foundation of Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers(No.E22307);Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2020ZD04);Open Research Fund of Key Laboratory of the Ministry of Education for Advanced Catalysis Materials and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces,Zhejiang Normal University。
A photoredox-catalyzed synthesis ofα,α-difluoromethyl sulfones from sulfur dioxide with readily available gem–difluoroalkenes is reported.This protocol features mild reaction conditions,broad substrate scope and go...
关键词:Sulfur dioxide gem-Difuloroalkenes Photoredox catalysis α α-Difluoromethyl-β-alkoxysulfones Arylsulfonyl radical 
Adduct-catalyzed tandem electro-thermal synthesis of organophosphorus(III)compounds from white phosphorus
《National Science Review》2025年第3期201-210,共10页Jingcheng Hu Haoyu He Minghao Xu Xiaotian Qi Chao Fu Hong Yi Aiwen Lei 
supported by the National Key R&D Program of China(2021YFA1500100,A.L.);the National Natural Science Foundation of China(22031008,A.L.);the Science Foundation of Wuhan(2020010601012192,A.L.).
Electrooxidation strategies for synthesizing readily oxidizable products face notable challenges,especially when the oxidation potential of the products is lower than that of the reactants or when high current densiti...
关键词:organic electrosynthesis P_(4)activation trivalent organophosphorus adduct-catalyzed green electricity 
Efficient propane dehydrogenation catalyzed by Ru nanoparticles anchored on a porous nitrogen-doped carbon matrix
《Chinese Chemical Letters》2025年第2期202-205,共4页Tianyi Yang Fangxi Su Dehuan Shi Shenghong Zhong Yalin Guo Zhaohui Liu Jianfeng Huang 
supported by the National Key Research and Development Project of China(No.2022YFE0113800);the National Natural Science Foundation of China(No.22102013);Natural Science Foundation of Chongqing(No.cstc2021jcyj-msxmX0945);Venture and Innovation Support Program for Chongqing Overseas Returnees(No.cx2020107);Thousand Talents Program for Distinguished Young Scholars,Postdoctoral Fellowship Program of CPSF(No.GZB20230910)。
Propane dehydrogenation(PDH)is a vital industrial process for producing propene,utilizing primarily Cr-based or Pt-based catalysts.These catalysts often suffer from challenges such as the toxicity of Cr,the high costs...
关键词:Propane dehydrogenation Ru nanoparticles Porous carbon matrix Ru@NC Electronic interaction 
Transition Metal-Catalyzed Asymmetric Migratory Allylic C—H Functionalization of Remote Dienes
《有机化学》2025年第2期592-601,共10页Jingming Zhang Zhitao He 
国家自然科学基金(22071262);国家自然科学基金(22371292);上海市科学技术委员会(22ZR1475200);宁波市自然科学基金(2023J036);中国科学院战略先导研究计划(XDB0610000)。
Asymmetric allylic C—H functionalization is a valuable and challenging research area. Different from the conventional direct allylic C—H cleavage strategy, transition metal-catalyzed migratory allylic substitution o...
关键词:remote dienes metal walking migratory allylic substitution allylic C-H bond functionalization asymmetric synthesis 
Energy-Saving Hydrogen Production from Methanol Electrocatalysis Catalyzed by Molybdenum Phosphide/Nitrogen-Doped Carbon Polyhedrons Supported Pt Nanoparticles
《Chinese Journal of Chemistry》2025年第2期146-154,共9页Jiaojiao Li Meng Li Fulin Yang Ligang Feng 
supported by the National Natural Science Foundation of China(Nos.22272148,22102105).
Improving the catalytic efficiency and anti-poisoning ability of Pt-based catalysts is very critical in methanol electrolysis technology for high-purity hydrogen generation.Herein,the nitrogen-doped carbon polyhedrons...
关键词:Molybdenum phosphide Methanol oxidation reaction Pt-based catalyst Hydrogen evolution reaction ELECTROCATALYST 
Copper-catalyzed C–H bond functionalization enabled by programmed alternating current
《Science China Chemistry》2025年第1期10-11,共2页Zhoumei Tan Kun Xu Chengchu Zeng 
Synthetic electrochemistry has been selected as one of the Top Ten Emerging Technologies in Chemistry in 2023 by International Union of Pure and Applied Chemistry(IUPAC)^([1]).It has emerged as a sustainable platform ...
关键词:CATALYZED COPPER IUPAC 
A round-trip journey of electrons:Electron catalyzed direct fixation of N_(2)to azos
《Chinese Journal of Catalysis》2025年第1期386-393,共8页Baijing Wu Jinrui Li Xiaoxue Luo Jingtian Ni Yiting Lu Minhua Shao Cunpu Li Zidong Wei 
国家重点研发计划(2022YFC2105904);国家自然科学基金(22478043,2209003052021004,U21A20312,22075033)。
The triple bond in N_(2)has an extremely high bond energy and is thus difficult to break.N_(2)is commonly converted into NH3 artificially via the Haber-Bosch process,and NH_(3)can be utilized to produce other nitrogen...
关键词:Fixed N_(2) AZO Electron catalyzed strategy "Brick trowel"transition state Arylradicals 
Trinuclear gold-catalyzed site-selective alkylation of peptides
《Science China Chemistry》2025年第1期249-256,共8页Qing-Yun Fang Chengyihan Gu Yinghan Chen Wencheng Yan Yong Liang Weipeng Li Chengjian Zhu Jie Han Jin Xie 
the National Key Research and Development Program of China(2021YFC2101900,2022YFA1503200);the National Natural Science Foundation of China(22122103,22101130,22001117,22471121,22271144);the Fundamental Research Funds for the Central Universities(020514380327);the open project of state key laboratory of natural medicines(SKLNMKF202401)for financial support。
Selective modification of peptides has always been a challenging issue.The selective alkylation of peptides can alter the biological activity and physical properties of molecules,and it has gained significant research...
关键词:gold catalysis PEPTIDE ALKYLATION C-C coupling RADICAL 
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