supported by the Program for Public Technology of Jiaxing Province,China (No.2023AD11041);the Natural Science Foundation of Zhejiang Province,China (No.LY22E020009);the National Undergraduate Training Programs for Innovation of China (No.202110354038);the Student Research Training Program of Jiaxing University,China (No.8517231462).
Metal acetylacetonates,a type of readily synthesized or commercially available metal complex,were demonstrated to be robust catalysts for the synthesis of oxazolidinone from CO_(2);aziridine under condition of atmosph...
supported by the National Natural Science Foundation of China(No.21772038);the China Postdoctoral Science Foundation(No.2018M632037)。
A Sc(OTf)3-catalyzed[3+3]cycloaddition of 2,2’-diester aziridines withβ-(indol-2-yl)-α,β-unsaturated ketones was developed,affording polysubstituted tetrahydro-y-carbolines in single diastereoisomers in good to ex...
Supported by the National Natural Science Foundation of China(No.21172014).
Aziridine derivatives of N^5-methyltetrahydrofolate were designed and synthesized based on the mechanism of methionine synthase, and their biological activities were investigated as well. The aziridine derivatives 1 a...
We thank the National Basic Research Program of China(No.2010CB833300);the National Natural Science Foundation of China(Nos.21025209,21121062,21332009,and 21302209)for generous financial support.
A Fe(OTf)_(3) catalyzed[3+2]annulation reaction between 2,3-disubstituted indoles and N-Ts aziridines is described herein.A series of hexahydropyrrolo[3,4-b]indole derivatives bearing two consecutive quaternary carbon...
Project(50903031) supported by the National Natural Science Foundation of China;Project(2009ZM0046) supported by the Fundamental Research Funds for the Central Universities in China;Project(N9100240) supported by the Foundation for Distinguished Young Talents in Higher Education of Guangdong Province, China
Polyfunctional aziridine/polyester microcapsules as control-release waterborne cross-linker were synthesized by multiple emulsion-solvent evaporation method. The results show that,a lower surface free energy with shel...
supported by the National Natural Science Foundation of China (20672054 & 20872073);the 111 Project of the Ministry of Education of China (B06005)
Basic ion-exchange resins,one kind of polystyryl-supported tertiary amine,were demonstrated to be highly efficient and recyclable catalysts for the fixation of carbon dioxide with aziridines under mild conditions,lead...
Project supported by key subject of Luoyang Normal University (No. 2004yzk90)
A novel compound of chiral 4-hydroxy-4-butyrolactam fused aziridine was synthesized via tandem nucleophilic displacement reaction under mild condition. Its structure was determined by IR, 1H NMR, elemental analysis an...
Aziridines and epoxides were reacted with diphenyl diselenide in the presence of a stoichiometric amount of (n-Bu)3P, respectively, giving β-amino- or β-hydroxy selenides in moderate to excellent yields under mild...
Aziridines are valuable synthetic reagents and intermediates.[1~3] The highly strained three membered ring readily opens with excellent stereo- and regio-control to afford a wide variety of more stable ring opene...
Supported by the science and technology fund of Wuhan city (No:996 0 0 10 16 G)
(2S, 3R)-2-acetooxymethanyl-3-(P-nitrophenyl)-N-tosylaziridine 5 was synthesized from (1S, 2S)-2-amino-1-(4-nitrophenyl)-1, 3-propanediol 1 in four steps with a 24.8% overall yield. This reaction is stereospecific and...