AZIRIDINE

作品数:21被引量:9H指数:2
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相关领域:理学化学工程更多>>
相关作者:柴卓更多>>
相关机构:安徽师范大学更多>>
相关期刊:《Science China Chemistry》《航空动力学报》《Chemical Research in Chinese Universities》《Chinese Journal of Polymer Science》更多>>
相关基金:国家自然科学基金高等学校学科创新引智计划中国博士后科学基金更多>>
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Metal Acetylacetonates as Robust Catalysts for the Synthesis of Oxazolidinone from CO_(2);Aziridine Under Atmospheric Pressure
《Chemical Research in Chinese Universities》2024年第6期1041-1049,共9页LI Bohan GONG Yujie LOU Huimin WEI Yujuan GUO Liping WANG Hongmei ZHANG Zulei LI Lei 
supported by the Program for Public Technology of Jiaxing Province,China (No.2023AD11041);the Natural Science Foundation of Zhejiang Province,China (No.LY22E020009);the National Undergraduate Training Programs for Innovation of China (No.202110354038);the Student Research Training Program of Jiaxing University,China (No.8517231462).
Metal acetylacetonates,a type of readily synthesized or commercially available metal complex,were demonstrated to be robust catalysts for the synthesis of oxazolidinone from CO_(2);aziridine under condition of atmosph...
关键词:Metal acetylacetonate Carbon dioxide AZIRIDINE OXAZOLIDINONE Atmospheric pressure 
Diastereoselective synthesis of functionalized tetrahydro-γ-carbolines via a[3+3] cycloaddition of 2,2’-diester aziridines with β-(indol-2-yl)-α,β-unsaturated ketones
《Chinese Chemical Letters》2020年第5期1293-1296,共4页Xuejie Zou Yangzi Liu Shaojing Shang Wulin Yang Weiping Deng 
supported by the National Natural Science Foundation of China(No.21772038);the China Postdoctoral Science Foundation(No.2018M632037)。
A Sc(OTf)3-catalyzed[3+3]cycloaddition of 2,2’-diester aziridines withβ-(indol-2-yl)-α,β-unsaturated ketones was developed,affording polysubstituted tetrahydro-y-carbolines in single diastereoisomers in good to ex...
关键词:AZIRIDINE Tetrahydro-γ-carboline [3+3]cycloaddition Sc(OTf)3 DIASTEREOSELECTIVITY 
Design, Synthesis and Activities of Aziridine Derivatives of N^5-Methyltetrahydrofolate Against Methionine Synthase被引量:2
《Chemical Research in Chinese Universities》2015年第5期742-745,共4页DENG Xiling GUO Ying TIAN Chao LIU Junyi WANG Xiaowei ZHANG Zhili 
Supported by the National Natural Science Foundation of China(No.21172014).
Aziridine derivatives of N^5-methyltetrahydrofolate were designed and synthesized based on the mechanism of methionine synthase, and their biological activities were investigated as well. The aziridine derivatives 1 a...
关键词:AZIRIDINE Methionine synthase Ring closure reaction N^5-Methyltetrahydrofolate 
Fe(OTf)_(3) Catalyzed Annulation of 2,3-Disubstituted Indoles with Aziridines
《Chinese Journal of Chemistry》2014年第8期709-714,共6页Hua Liu Chao Zheng Shu-Li You 
We thank the National Basic Research Program of China(No.2010CB833300);the National Natural Science Foundation of China(Nos.21025209,21121062,21332009,and 21302209)for generous financial support.
A Fe(OTf)_(3) catalyzed[3+2]annulation reaction between 2,3-disubstituted indoles and N-Ts aziridines is described herein.A series of hexahydropyrrolo[3,4-b]indole derivatives bearing two consecutive quaternary carbon...
关键词:ANNULATION INDOLE AZIRIDINE Lewis acid catalysis 
Synthesis and characterization of polyfunctional aziridine/polyester microcapsules by multiple emulsion-solvent evaporation method
《Journal of Central South University》2011年第2期337-342,共6页胡剑青 朱海军 涂伟萍 王锋 
Project(50903031) supported by the National Natural Science Foundation of China;Project(2009ZM0046) supported by the Fundamental Research Funds for the Central Universities in China;Project(N9100240) supported by the Foundation for Distinguished Young Talents in Higher Education of Guangdong Province, China
Polyfunctional aziridine/polyester microcapsules as control-release waterborne cross-linker were synthesized by multiple emulsion-solvent evaporation method. The results show that,a lower surface free energy with shel...
关键词:MICROCAPSULE AZIRIDINE POLYESTER multiple emulsion-solvent evaporation 
Environmentally benign chemical fixation of CO_(2) catalyzed by the functionalized ion-exchange resins被引量:2
《Science China Chemistry》2010年第7期1578-1585,共8页LIU AnHua HE LiangNian PENG ShiYong PAN ZhongDa WANG JingLun GAO Jian 
supported by the National Natural Science Foundation of China (20672054 & 20872073);the 111 Project of the Ministry of Education of China (B06005)
Basic ion-exchange resins,one kind of polystyryl-supported tertiary amine,were demonstrated to be highly efficient and recyclable catalysts for the fixation of carbon dioxide with aziridines under mild conditions,lead...
关键词:CYCLOADDITION carbon dioxide AZIRIDINE ion-exchange resin solvent-free process 
Synthesis and Crystal Structure of Chiral 4-Hydroxy-4-butyrolactam Fused Aziridine
《Chinese Journal of Structural Chemistry》2008年第2期133-136,共4页WANG Jian-Ping WANG Jian-Ge FU Yong-Ju LI Ying-Fei 
Project supported by key subject of Luoyang Normal University (No. 2004yzk90)
A novel compound of chiral 4-hydroxy-4-butyrolactam fused aziridine was synthesized via tandem nucleophilic displacement reaction under mild condition. Its structure was determined by IR, 1H NMR, elemental analysis an...
关键词:butyrolactam AZIRIDINE asymmetric synthesis crystal structure 
Tri-n-butylphosphine Mediated Ring-Opening Reactions of Aziridines or Epoxides with Diphenyl Diselenide
《Chinese Journal of Chemistry》2007年第11期1758-1761,共4页张万轩 叶康 阮珊 陈祖兴 夏清华 
Aziridines and epoxides were reacted with diphenyl diselenide in the presence of a stoichiometric amount of (n-Bu)3P, respectively, giving β-amino- or β-hydroxy selenides in moderate to excellent yields under mild...
关键词:AZIRIDINE epoxide ring opening SELENIDE reduction 
Amino Trans-position through the Chiral Aziridine
《有机化学》2003年第z1期266-266,共1页FENG Xi-Chun LIANG Shu-Cai SU Jiang-Tao QIU Quo-Fu HU Xian-Ming 
  Aziridines are valuable synthetic reagents and intermediates.[1~3] The highly strained three membered ring readily opens with excellent stereo- and regio-control to afford a wide variety of more stable ring opene...
Synthesis of Substituted Aziridine from (1S,2S)-2-Amino-1- (4-Nitrophenyl)- 1,3-Propanediol被引量:1
《Wuhan University Journal of Natural Sciences》2000年第3期345-347,共3页Yang Shao-rong Hu Xian-ming Liu Jun Shu Jia-you Feng Dai-jun Huang Jin-xia 
Supported by the science and technology fund of Wuhan city (No:996 0 0 10 16 G)
(2S, 3R)-2-acetooxymethanyl-3-(P-nitrophenyl)-N-tosylaziridine 5 was synthesized from (1S, 2S)-2-amino-1-(4-nitrophenyl)-1, 3-propanediol 1 in four steps with a 24.8% overall yield. This reaction is stereospecific and...
关键词:AZIRIDINES synthesis CHLORAMPHENICOL 
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