support from the National Natural Science Fund for Distinguished Young Scholars of China(No.22025107);Shaanxi Fundamental Science Research Project for Chemistry&Biology(No.22JHZ003);the National Youth Top-notch Talent Support Program of China,Xi’an Key Laboratory of Functional Supramolecular Structure and Materials,and the FM&EM International Joint Laboratory of Northwest University。
Conventionally,organic radicals adhere to the Aufbau principle,the energy level of the singly occupied molecular orbital(SOMO)is not below the highest occupied molecular orbital(HOMO),but somewhat abnormal phenomena h...