SULFOXIMINE

作品数：14被引量：43H指数：3
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相关作者：张宇孙健更多>>
相关机构：中国科学院成都生物研究所中国科学院研究生院更多>>
相关期刊：《Acta Pharmacologica Sinica》《Science China Chemistry》《World Journal of Gastroenterology》《Advances in Parkinson's Disease》更多>>
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Catalytic enantioselective N-silylation of sulfoximine
《Chinese Chemical Letters》2024年第4期352-356,共5页Xingfen Huang Jiefeng Zhu Chuan He 
financial support from the National Natural Science Foundation of China (Nos.22122102, 22101120, 22271134);Guangdong Provincial Key Laboratory of Catalysis (No.2020B121201002);Guangdong Pearl River Talent Program (No.2019QN01Y628);Shenzhen Science and Technology Innovation Committee (No.RCJC20221008092723013);Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education (No.KFJJ2022012)。
A rhodium/diphosphine-catalyzed asymmetric cross-dehydrogenative coupling between sulfoximines and dihydrosilanes has been achieved. This is the first report on the enantioselective N-silylation of sulfoximines. The p...
关键词：N-Silylation of sulfoximine Chiral silylamine Si-stereogenic silanes Si-CADC Asymmetric catalysis 
Discovery of Novel Anthranilic Diamide Derivatives Bearing Sulfoximine Group as Potent Insecticide Candidates
《Chemical Research in Chinese Universities》2024年第1期96-108,共13页ZHANG Hongyuan PENG Jinmin ZHONG Yuanhan CHEN Yue WANG Qing Haditullah HADIATULLAH XIE Weibin XIONG Lixia YUCHI Zhiguang LIU Jingbo LI Yuxin 
Nankai University Cangzhou Bohai New Area Green Chemical Research Institute(NCC)Fund,the National Natural Science Foundation of China(Nos.31972287,32022073);the National Key Research and Development Program of China(No.2022YFE0108400);the Scientific Project of Tianjin Municipal Education Commission,China(No.2022KJ026).
The fall armyworm,Spodoptera frugiperda(S.frugiperda),represents the most resistant insect species and poses serious threat to grain yield.Chlorantraniliprole(CHL),which targets the ryanodine receptors(RyRs)in insects...
关键词：Anthranilic diamide derivative SULFOXIMINE Spodoptera frugiperda Mode of action Molecular docking 
Cp*Rh/Ag catalyzed C–H activation/cyclization sequences of NH-sulfoximines to fused aza-polyheterocycles under gentle conditions
《Green Synthesis and Catalysis》2023年第2期160-168,共9页Jiapian Huang Fei Liu Feihua Du Linghui Zeng Zhiyuan Chen 
the National Natural Science Foundation of China(No.21961015);the Natural Science Foundation of Jiangxi Province(No.20202ACBL203005)for their financial support.
Disclosed herein is a novel Rh/Ag co-catalyzed S=NH directed C–H activation and C–H/N–H bond functionalization protocol of free NH-sulfoximines with hypervalent iodonium ylides.With the aid of AgOTf,these C–H func...
关键词：Rhodium catalysis C-H activation SULFOXIMINE Polyheterocycle CYCLIZATION 
Multipurpose sulfoximine-mediated radicalγ-heteroarylation of unactivated C(sp^(3))–H bonds被引量：1
《Science China Chemistry》2023年第5期1435-1442,共8页Yuqian Sun Xinxin Wu Zhu Cao Chen Zhu 
supported by the National Natural Science Foundation of China(21971173,22001185,22171201);the Natural Science Foundation of Jiangsu Province(BK20200852);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)。
A conceptually novel,trifunctional sulfoximine-mediatedγ-functionalization of unactivated C(sp^(3))–H bonds has been achieved.The reaction is initiated by the photo-induced homolytic cleavage of an N–S bond in the ...
关键词：SULFOXIMINE hydrogen atom transfer functional group migration C(sp^(3))–H functionalization heteroarylation PHOTOCHEMISTRY 
Difluoromethyl 2-Pyridyl Sulfoximine:A Stereoselective Nucleophilic Reagent for Difluoro(aminosulfinyl)methylation and Difluoro(aminosulfonyl)methylation
《CCS Chemistry》2022年第11期3648-3659,共12页Qinghe Liu Chuanfa Ni Qian Wang Depei Meng Jinbo Hu 
Financial support was provided by the National Key Research and Development Program of China(no.2016YFB0101200);the National Natural Science Foundation of China(no.21632009);the Key Programs of CAS(no.KGZD-EW-T08);the Key Research Program of Frontier Sciences of CAS(no.QYZDJ-SSW-SLH049);Shanghai Science and Technology Program(no.16QA1404600).
1,1-Difluorinated sulfonamides are known to have better anti-inflammatory activity and enzyme inhibitory potency than their nonfluorinated counterparts.Two geminal fluorine atoms cause electronic perturbation of the n...
关键词：difluoro(aminosulfonyl)methylation difluoro(aminosulfinyl)methylation STEREOSELECTIVE NUCLEOPHILIC SULFOXIMINE 
Synthesis,Crystal Structure and Biological Activity of N-cyanosulfoximine Derivative Containing 1,2,3-Thiadiazole被引量：2
《Chinese Journal of Structural Chemistry》2015年第9期1428-1433,共6页毛武涛 宗广宁 范志金 李凤云 宋海斌 李娟娟 Kalinina A.Tatiana Khazhieva Inna Lugovik Ksenia Morzherin Yu.Yury Belskaya P.Nataliya 
funded in part by the National Natural Science Foundation of China(21372132);Nataliya P.Belskaya thanks Russian State Task of Ministry Education and Science No.4.560.2014;K.Kalinina A.Tatiana thanks RFBF№13-03-00137
The title compound N-cyanosulfoximine derivative containing 1,2,3-thiadiazole （C6HsN4OS2, Mr = 216.28） has been synthesized using 4-（chloromethyl）-5-methyl-1,2,3-thiadiazole as the starting material, and its struc...
关键词：1 2 3-thiadiazole SULFOXIMINE crystal structure SYNTHESIS biological activity 
Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF_(2)H: Facile Entry into gem-Difluoroalkenes
《Chinese Journal of Chemistry》2014年第8期703-708,共6页Xiao Shen Qinghe Liu Chuanfa Ni Jinbo Hu 
Support of our work by the National Basic Research Program of China(Nos.2012CB215500 and 2012CB821600);the NNSFC(No.21372246);Shanghai QMX program(No.13QH1402400);the Chinese Academy of Sciences is gratefully acknowledged.
An efficient nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated primary alkyl bromides with PhSO(NTBS)CF_(2)H has been developed.It is particularly remarkable that,when 1.5 equiv.of alkyl bromides ar...
关键词：nucleophilic fluoroalkylation β-elimination difluoroalkene SULFOXIMINE 
通过α-甲基烷基化反应合成Sulfoximine类衍生物
《合成化学》2009年第1期97-99,共3页张宇 孙健 
从Sulfoximine A出发,选取对甲氧基苄基(PMB)为N-保护基,通过α-甲基的烷基化反应合成了一系列新的Sulfoximine类衍生物,其结构经1HNMR确证。
关键词：SULFOXIMINE α-甲基 烷基化 保护基 合成 
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