the National Natural Science Foundation of China(Nos.22371273,22293011 and T2341001);the Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2023476);the National Science Foundation of Anhui Province(No.2208085J26)。
Transition-metal-catalyzed cross-electrophile coupling has emerged as a reliable method for constructing carbon–carbon bonds.Herein,we report a general method,cobalt-catalyzed reductive alkynylation,to construct C(sp...
the financial supports of the National Natural Science Foundation of China(Nos.82173684 and 82204181);Nanjing University of Chinese Medicine National Natural Science Foundation of China Counterpart Funding(No.XPT82204181);General Project of Basic Science in Colleges and Universities of Jiangsu Province(No.21KJB350007);Jiangsu Provincial Health Commission(No.Z2021057);the Open Project of Chinese Materia Medica First Class Discipline of Nanjing University of Chinese Medicine(No.2020YLXK010);the Priority Academic Program Development of Jiangsu Higher Education Institutions(Integration of Chinese and Western Medicine);the experimental support from the Experiment Center for Science and Technology,Nanjing University of Chinese Medicine;financially supported by the“Innovative and Entrepreneurial Team”Program of Jiangsu Province(2020)。
Bioorthogonal reactions can take place in biological environments without interfering with biochemical processes.In this study,Pd(PPh_(3))_(2)Cl_(2)was used as a bioorthogonal catalyst to in situ transform the stable ...
Financial support from National Natural Science Foundation of China(No.21871053);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang(No.2019R01005);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(2020ZD04)。
Trifluoromethylation/sulfonylation of alkynes from trifluoromethyl thianthrenium triflate and sulfur dioxide under extremely mild reaction conditions provides a facile access to trifluoromethyl-substituted vinyl sulfo...
the financial support from the Natural Science Foundation of China and Shandong Province(Nos.21971149,92156007,ZR2019ZD45,ZR2020KB005);the Fundamental Research Funds of Shandong University。
Polysubstituted pyrroles are very important scaffolds in many bioactive natural products and synthetic pharmaceuticals.Here,a new gold-catalyzed cycloaddition of alkynes with azadienes to access tetrasubstituted pyrro...
Support for this research from the National Natural Science Foundation of China (Nos. 21971262, 81702255);National Postdoctoral Program for Innovative Talents (No. BX20190399);Guangdong Provincial Key Laboratory of Chiral Molecule and Drug Discovery (No. 2019B030301005);The Program for Guangdong Introducing Innovative and Entrepreneurial Teams (No. 2016ZT06Y337)
Homogeneous gold catalysis has demonstrated the preponderant capability of realizing a broad range of synthetically versatile alkyne functionalization over the last two decades.Though catalytic asymmetric alkyne trans...
Financial supports from the Natural Science Foundation of Zhejiang Province(No.LY22B020010);the National Natural Science Foundation of China(Nos.21772067,21801096 and 22161043);The Youth Jinggang Scholars Program in Jiangxi Province。
A palladium-catalyzed formal[2+2+1]cyclization of 1-alkynyl-8-iodonaphthalene with double isocyanides is developed herein.The transformation worked well to produce a series of 7 H-acenaphtho[1,2-b]pyrrole with a broad...
financially supported by the National Natural Science Foundation of China (Nos. 91961105, 21822107,21571115, 21827801);the Natural Science Foundation of Shandong Province (Nos. ZR2019ZD45, JQ201803 and ZR2017MB061);the Taishan Scholar Project of Shandong Province of China (Nos.tsqn201812003 and ts20190908);Project for Scientific Research Innovation Team of Young Scholar in Colleges and Universities of Shandong Province (No. 2019KJC028);Natural Science Foundation of Shandong Province (No. ZR2020ZD35)。
The construction of all-carbon molecule frameworks remains challenging. Herein, we report a facile and efficient one-pot synthesis of a novel all-carbon stair containing dimerized pentalene core using inexpensive cycl...
We gratefully acknowledge the National Natural Science Foundation of China(Nos.21671097 and 21573106);the Fundamental Research Funds for the Central Universities for financial support.
An electron-deficient[CpERhCl2]2 catalyzed annulation of N-pentafluorophenylbenzamides with internal alkynes was successfully established under mild reaction conditions,with the assistance of Lewis acid silver salt.Pa...
the financial support from the National Natural Science Foundation of China(Nos.21772185,21672200);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)。
By virtue of electrochemistry,a series ofα,α-dihaloacetophenones were easily obtained with good to excellent yields.This electrochemical procedure was taken in a divided cell with constant current in aqueous media.T...
National Natural Science Foundation of China(Nos.21672193,21272218);Henan Province postdoctoral research start-up project;Zhengzhou University of China for financial support of this research。
A divergent intramolecular reaction of phosphine tethered alkyne in protic solvent was developed.This provided a novel and simple access to a large variety of(Z)-alkenylphosphine oxides and phospholane oxides.Our prel...