supported by the National Natural Science Foundation of China (Nos. 21432004 and 21890732)
Ru(bpy)3]2+-cored supramolecular organic framework SMOF-1, assembled from a [Ru(bpy)3]2+-derived hexaarmed molecule and cucurbit[8]uril, has been demonstrated to heterogeneously catalyze visible light-induced reductio...
supported by the National Natural Science Foundation of China(No.21302081);the Scientific Fund of Sichuan Province,China(No.2014JQ0052)
A highly efficient coupling reaction of N-heterocyclic carbene precursors with sulfonyl azides has been developed, affording a variety of pyrido[1,2-c][1,2,4]triazole-based π-conjugated triazenes. The present reactio...
Financial support was provided by the National Natural Science Foundation of China (Nos. 21525209, 21621002, 21772225, and 21761142003);the Chinese Academy of Sciences (Strategic Priority Research Program (No. XDB20000000);Key Research Program of Frontier Sciences (No. QYZDB-SSW-SLH040));Shanghai Science and Technology Commission (Nos. 15JC1400400 and 17XD1404600);the National Program for Support of TopNotch Young Professionals of China;the K. C. Wong Education Foundation
On the basis of the mild transformation of alkenyl triflates into alkynes promoted by LiCl, a one-pot protocol using alkenyl triflate precursors was developed for copper-mediated azide–alkyne cycloaddition. This prot...
An efficient and facile approach for tetrachlorosilane as an in situ mediated transformation via a one-pot, synthesis of vicinal bromoazides through the generation of BrN3 from azidochlorosilane and N-bromosuccinimide...
supported by the National Natural Science Foundation of China(NNSFC,No.21372238);National 1000-Young-Talent Program of China;Shanghai Pujiang Talent Program(No.13PJ1410200)
Here, we report a new strategy for rapid synthesis of branched peptide by side-chain hydrazide ligation at Asn. The hydrazide was converted to thioester at Asn side chain by Na NO2 and thiol reagent, and sequential li...
the NSFC (Nos. 21172058, 20802017);HASTIT (No. 2012HASTIT10);PCSIRT (No. IRT1061);Key Technologies R & D Program of Henan Province (No. 112102310319) for financial support
In this paper, an efficient synthesis of 5-alkynyl-1,2,3-triazoles through a one-pot aerobic oxidative coupling reaction of various alkynes and azides has been developed. Further derivatization of 5-alkynyl-1,2,3-tria...
Azide-functionalization of single-walled carbon nanotubes (SWCNTs) was achieved by electrochemical oxidation of N3 in situ. The functionalized nanotubes were characterized in details by single internal reflection in...
the financial support by the Natural Science Foundation of China(No.21203085);Promotive Research Fund for Young and Middle-aged Scientists of Shandong Province(doctor fund)(Nos.BS2011CL011 and BS2012CL009)
The random copolymers grafted onto the surfaces of SiO2 hollow sphere via reverse atom transfer radical polymerization (RATRP) and "click" chemistry were investigated. A sufficient amount of peroxides, as initiati...
financial support from National Science Foundation of China(No.20902002);Anhui Provincial Natural Science Foundation(No.10040606Q04)
A powerful approach to the synthesis of an unprecedented polynorbornene with pendant moiety bearing azide and terminal alkyne groups is developed. Two key intermediates, namely, 3-azido-5-(2-(trimethylsilyl)ethynyl...
A new method for the synthesis of 4,4′,6,6′-tetra(azido)azo-1,3,5-triazine (TAAT) is described. The key intermediate 4,4′,6,6′-tetra(azido)hydrazo-1,3,5-triazine (TAHT) was synthesized by nucleophilic substitution...