the National Natural Science Foundation of China(22271295);Gansu Provincial Natural Science Foundation Key Project(23JRRA606);Major Program of the Lanzhou Institute of Chemical Physics,CAS(No.ZYFZFX-9);State Key Laboratory Program of the Lanzhou Institute of Chemical Physics(CHGZ-202208)for generous financial support.
Boronate esters are highly valued in synthetic and pharmaceutical industries for their versatility in creating C—C and C—X bonds.They also find applications as catalysts in chemical transformations as well as stimul...
supported by the National Natural Science Foundation of China (21973047 and 62074082);Jiangsu Province Double Innovation Talent Program (090300014001).
A luminescent lanthanide-organic framework[Eu_(2)(adip)(H_(2)adip)(DMF)_(2)]·CH_(3)OH(1)was synthesized by a solvothermal method using anthracene-based ligand 5,5’-(anthracene-9,10-diyl)diisophthalic acid(H4adip).1 ...
We are grateful for financial support from Guangzhou Laboratory,Bioland Laboratory,and the National Natural Science Foundation of China(No.22071249).
Though alcohol oxidations were considered as well-established reactions,selecting productive conditions or predicting reaction yields for unseen alcohols remained as major challenges.Herein,an auto machine learning(ML...
We gratefully acknowledge the financial support from the National Natural Science Foundation of China(Nos.21772202,21701073,21831008);Beijing Municipal Science&Technology Commission(No.Z181100004218004);Beijing National Laboratory for Molecular Sciences(No.BNLMS-CXXM-201901);the Fundamental Research Funds for the Central Universities(lzujbky-2017-12 and lzujbky-2019-kb06).
Summary of main observation and conclusion Herein,unprecedented rhenium-catalyzed decarboxylative oxytri-/difluoromethylation and Heck-type trifluoromethylation of styrenes have been developed by using hypervalent iod...
An aerobic oxidation of aldehydes towards carboxylic acids in MeCN using 1 atm of pure oxygen or oxygen in air as the oxidant and a catalytic amount of single component catalyst, Fe(NO3)3.9H20, has been developed. C...
We gratefully acknowledge the financial support of this work by the "111" Project of Ministry of Education of China (No. B06005) and the Natural Science Foundation of China (No. 31370039).
Based on the structure of natural product 2-aryl-4,5-dihydrothiazole-4-carboxylic acid, a series of novel (R)-2-aryl-4,5-dihydrothiazole-4-carboxylic acid derivatives were designed and synthesized. Their structures ...
This work was supported by the National Natural Science Foundation of China (Nos. 20961007 and 21264011), the Aviation Fund (No. 2010ZF56023) and the Young Scientists Program of Jiangxi Province (No. 2008DQ00600).
Five new transition metal complexes [Cu(HL)2(H20)2] (1), [Cu(HL)z(phen)] (2), [Cu(HL)2(H20)]2(4,4′-bipy) (3), [Zn(HL)2(HzO)2].(4,4′-bipy) (4), [Ag(HL)(4,4′-bipy)]n (5), (H2L=5-chl...
A series of rare-earth luminescent complexes {[Eu(pta)(H2O)3]·H2O}n(1, H3pta=pyridine-2,4,6-tricarboxylic acid) and {[EuxY(1-x)(pta)(H2O)3]·H2O}n(2-10) have been synthesized. Complexes 1 and 8 were det...
The HNO3-mediated commercially important 2-nitrophenylacetic acid. CH2 extrusion reactions product 4-nitrobenzoic of phenylacetic acid lead to acid through the formation one pot synthesis of unexpected of 4-nitropheny...