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国家自然科学基金(20462002): 作品数：10被引量：8H指数：2; 导出分析报告; 相关作者：蔡明中王冬桑晓燕许秋华余腊妹更多>>; 相关机构：江西师范大学南昌航空工业学院江西科技师范学院九江学院更多>>; 相关期刊：《有机化学》《江西师范大学学报（自然科学版）》《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>; 相关主题：MCM-41STEREOSELECTIVEMCM-41负载负载钯催化剂芳基卤化物更多>>; 相关领域：理学更多>>

A one-pot stereoselective synthesis of 1,4-dienyl selenides by hydrostannylation-Stille tandem reaction of acetylenic selenides with Bu_3SnH and allylic bromides: 《Chinese Chemical Letters》2008年第9期1047-1050,共4页La Mei Yu Wen Yan Hao Ming Zhong Cai; the National Natural Science Foundation of China (No.20462002);Natural Science Foundation of Jiangxi Province (No.2007GZW0172) for financial support.; 1,4-Dienyl selenides can be stereoselectively synthesized in one pot under mild conditions in good yields by the palladiumcatalyzed hydrostannylation of acetylenic selenides, followed by Stille coupling with allylic b...; 关键词：Acetylenic selenide Hydrostannylation Stille coupling 1 4-Dienyl selenide Stereoselective synthesis

A facile synthesis of terminal arylacetylenes via Sonogashira coupling reactions catalyzed by MCM-41-supported mercapto palladium(0) complex: 《Chinese Chemical Letters》2008年第7期783-787,共5页Ya Ping Xu Rong Hua Hu Ming Zhong Cai; the National Natural Science Foundation of China (No.20462002);Natural Science Foundation of Jiangxi Province (No.0420015)for financial support.; A variety of terminal arylacetylenes have been conveniently synthesized in good to high yields via Sonogashira coupling of aryl iodides with （trimethylsilyl）acetylene catalyzed by MCM-41-supported mercapto palladium...; 关键词：Sonogashira coupling MCM-41-supported catalyst Mercapto palladium（0） complex Terminal arylacetylene HETEROGENEOUSCATALYSIS

MCM-41负载硫醚钯配合物的合成及其催化芳基卤化物的羰基化性能被引量：4: 《有机化学》2008年第2期256-260,共5页余腊妹许秋华蔡明中; 国家自然科学基金(No.20462002)资助项目; γ-(β-氰乙硫基)丙基三乙氧基硅烷依次用纳米介孔分子筛(MCM-41)固载、与氯化钯反应,合成了MCM-41负载硫醚钯配合物.该新型负载钯配合物是芳基卤化物的羰基化反应的有效催化剂,为各种取代的N-苯基苯甲酰胺、苯甲酸丁酯的合成提供了方...; 关键词：负载钯催化剂 MCM-41 硫醚钯配合物羰基化芳基卤化物

MCM-41负载巯基钯配合物的合成及其催化芳基卤化物的羰基化性能被引量：2: 《江西师范大学学报（自然科学版）》2007年第6期551-556,共6页王萍萍叶兴琳蔡明中; 国家自然科学基金资助课题(20462002); γ-巯丙基三乙氧基硅烷依次用纳米介孔分子筛(MCM-41)固载,与氯化钯反应,合成了MCM-41负载巯基钯配合物.该新型负载钯配合物是芳基卤化物羰基化反应的有效催化剂,能重复使用多次活性基本不变,为各种取代的N-苯基苯甲酰胺、取代的苯甲酸...; 关键词：负载钯催化剂 MCM-41 巯基钯配合物羰基化芳基卤化物

A Novel Stereoselective Synthesis of （1Z,3E）-2-Phenyl（or p-Tolyl）sulfonyl-substituted 1,3-Dienes via Palladium Catalyzed Cross-coupling Reactions of （E）-α-lodovinyl Sulfones: 《Chinese Journal of Chemistry》2007年第12期1927-1931,共5页胡荣华陈桂琴蔡明中; Project supported by the National Natural Science Foundation of China （No. 20462002） and the Natural Science Foundation of Jiangxi Province in China （No. 0420015）.; （E）-α-Stannylvinyl phenyl（or p-tolyl）sulfones underwent an iododestannylation reaction to afford （E）-α-iodovinyl phenyl（or p-tolyl）sulfones 1, which reacted with （E）-alkenylzirconium（IV） complexes 2 prod...; 关键词：（E）-α-iodovinyl sulfone HYDROZIRCONATION 1 3-dien-2-yl sulfone palladium CROSS-COUPLING

A facile stereospecific synthesis of (Z)-2-sulfonyl-substituted 1,3-enynes via Sonogashira coupling of (E)-α-iodovinyl sulfones with 1-alkynes: 《Chinese Chemical Letters》2007年第7期773-776,共4页Wen Yan Hao Jian Wen Jiang Ming Zhong Cai; the National Natural Science Foundation of China(No.20462002);Natural Science Foundation of Jiangxi Province(No.0420015)for financial support.; （E）-α-Iodovinyl sulfones 1 underwent the Sonogashira coupling reactions with terminal alkynes 2 in piperidine at room temperature in the presence of 5 mol% of Pd（PPh3）4 and 10 mol% of CuI to stereospecifically af...; 关键词：（E）-α-Iodovinyl sulfone 1 3-Enynylsulfone Sonogashira coupling Terminal alkyne

Dicyano-Functionalized MCM-41-Supported Palladium Complex as An Efficient Catalyst for Allylation of Aldehydes and Ketones: 《Chinese Journal of Chemistry》2006年第11期1669-1673,共5页赵红蔡明中; Project supported by the National Natural Science Foundation of China （No. 20462002）.; Dicyano-functionalized MCM-41-supported palladium complex was prepared from dicyano-functionalized MCM-41 and palladium chloride. This complex exhibited high catalytic activity in the allylation of aldehydes and keton...; 关键词：ALLYLATION dicyano-functionalized MCM-41 heterogeneous palladium catalysis homoallylic alcohol

Novel Stereoselective Synthesis of （E）-β-Silylvinylstannanes via Hydromagnesiation of Silylarylacetylenes: 《Chinese Journal of Chemistry》2006年第10期1469-1471,共3页黄斌周舟蔡明中; Project supported by the National Natural Science Foundation of China （No. 20462002） and the Natural Science Foundation of Jlangxl Province （No. 0420015）.; Hydromagnesiation of silylarylacetylenes 1 in diethyl ether gave （E）-β-silylvinyl Grignard reagents 2, which reacted with trialkylstannyl chlorides 3 to afford stereoselectively （E）-β-silylvinylstannanes 4 in go...; 关键词：hydromagnesiation silylarylacetylene （E）-β-silylvinylstannane stereoselective synthesis

炔基硫醚的制备和(E)-α-碘代烯基硫醚的立体选择性合成: 《江西师范大学学报（自然科学版）》2006年第3期205-208,共4页桑晓燕王冬蔡明中; 国家自然科学基金资助课题(20462002); 乙基溴化镁与末端炔烃反应生成炔基Grignard试剂,后者与芳(烷)基硫氯作用高产率地制得了炔基硫醚.通过炔基硫醚与碘化氢在二氯甲烷中的加成反应,高产率且立体选择性地合成了(E)-α-碘代烯基硫醚.; 关键词：炔基硫醚 (E)-α-碘代烯基硫醚炔基Grignard试剂立体选择性合成

聚-ω-(甲硒基)十一烷基硅氧烷钯(0)配合物的合成与催化性能被引量：2: 《有机化学》2006年第2期215-218,共4页刘刚章荣立蔡明中; 国家自然科学基金(No.20462002)资助项目.; ω-氯代十一烷基三乙氧基硅烷依次用气相法二氧化硅固载、与甲硒基钠和氯化钯作用,再用水合肼还原,合成了气相法二氧化硅负载的聚-ω-(甲硒基)十一烷基硅氧烷钯(0)配合物.该钯(0)配合物对丙烯腈和丙烯酸与芳基碘的Heck芳基化反应具有很...; 关键词：负载型钯催化剂硒钯(0)配合物 Heck芳基化肉桂腈肉桂酸立体选择合成氯化钯配合物硅氧烷催化性能烷基

国家自然科学基金(20462002)