supported by the National Natural Science Foundation of China(Nos.22076185,21771183,21373223,21221001,21171164,20873149 and 20771102);the 973 programs(Nos.2014CB845603,2012CB821702 and 2006CB932904);the Natural Science Foundation of Fujian Province(Nos.2020J06033,2018J01027,2010J01056);FJIRSM&IUE Joint Research Fund(No.RHZX-2018-005);Chunmiao project of Haixi institute of Chinese Academy of Sciences(CMZX-2014-001);the Youth Innovation Promotion Association of Chinese Academy of Sciences(2011220)。
The nuclear fuel cycle inevitably generates a large amount of radioactive waste liquid,which will pose a serious threat to the ecological environment and human health.Ion exchange method has received wide attention fo...
Presented here is the solvothermal preparation of two luminescent coordination polymers (L-CPs) based on the same mixed ligands, namely [Cd2(1,4-NDC)2(dppe)] (1) and [Mn3(OH)2(1,4-NDC)2(dppe)(H2O)] (2...
supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21571175);the State Key Laboratory of Structural Chemistry
Utilizing two polycarboxylic acids as primary ligands and 1,10-phenanthrolion as an auxiliary ligand in the existence of lanthanide nitrates, two lanthanide-based complexes formulated as [Nd4(2,6-pydc OH)6(Phen)4...
supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221);the State Key Laboratory of Structural Chemistry
Two new europium-based metal-organic-frameworks (MOFs), namely [NMen][Eu(m- BDC)2] (1) and [Eu3(p-BDC)4(ClO4)(H2O)4] (2), have been synthesized and structurally characte- rized. Single-crystal X-ray diff...
supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221);the State Key Laboratory of Structural Chemistry
Temperature dependent assembly of two novel Cd coordination polymers with the phen and H2MIP ligands (phen = 1,10-phenanthrolion and H2MIP = 5-methyl-isophthalic acid), formulated as Cd2(MIP)2(phen)2 (1) and ...
supported by the 973 Program(2012CB821702,2014CB845603);the National Natural Science Foundation of China(21233009,21203194 and 21173223)
A new mixed-valence cyanide-bridged complex, Br3Fe(p-NC)RuBr(dppm)2 (dppm = bis(diphenylphosphino)methane), was obtained through the reaction between trans-(dppm)2C1- RuCN and FeBr3. Its crystal structure wa...
supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221);the State Key Laboratory of Structural Chemistry
Solvothermal reactions of Zn(NO3)2·6H20 with isophthalic acid in the presence of potassium nitrate lead to an acentric three-dimensional (3D) hereto-metallic inorganic-organic hybrid framework [ZnK2(m-BDC)ffH20...
supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221);the State Key Laboratory of Structural Chemistry
Reactions of Zn(NO3)E'6H20 and MNO3 (M = Na, K and Rb) with HEmip (HEmip = 5-methylisophthalic acid) in DMF (DMF = N,N'-dimethylformamide) resulted in the formation of novel heterometallic metal-organic fram...
supported by the National Ministry of Science and Technology of China(2012CB821702);the National Science Foundation of China(21073192,21203194 and 21233009);the Science Foundation of CAS and Fujian Province for research funding support(KJCX2-YW-H20)
A new metal-organic framework, {[Cd(DPA)(OBA)]'(HzO)}n (1, DPA = 4,4"-dipyri- dylamine, H2OBA = 4,4"-oxybisbenzoic acid), has been synthesized and characterized by elemental analysis, IR and single-crystal ...
supported by the National Basic Research Program of China(973 Program,2012CB821702);the National Natural Science Foundation of China(21233009 and 21173221)
Two homochiral enantiomorphic 3D coordination polymers: (D-HAPA)2[Cd2Cs(D- HAPA)(m-BDC)4]'(EtOH) (1D) and (L-HAPA)2[Cd2Cs(L-HAPA)(m-BDC)a]'(EtOH) (1L) (APA = 2-amino-l-propanol, m-H2BDC = 1,3-b...