supported by grants from the Fundamental Research Funds for Central Universities(No.2042021kf0190)。
2-Deoxy-α-C-Glycosides are a significant class of carbohydrates found in numerous bioactive molecules and medicines.Developing a concise strategy for the assembly of theseα-configured C-glycosides is crucial in the ...
supported by the National Natural Science Foundation of China(22122107).
The synthesis of N-glycosides has received significant attention due to their crucial role in carbohydrate chemistry.Despite considerable advancements developed in the construction of N-glycosides,methods for the ster...
Fuzhou University (No. 511041);the Fujian Provincial Department of Education (No. 602512) for financial support。
A highly efficient coupling of glycosyl stannanes and sulfonium salts enabled by synergistic Pd/Cu catalysis is disclosed, facilitating the construction of C-aryl/alkenyl glycals under mild conditions in high yields.T...
We thank the National Natural Science Foundation of China(NSF 22171114 and 21772075)for its financial support.
Efficiently modifying glycals by directly introducing functional groups into their double bonds is a longstanding challenge.Here,the strategy of introducing two different functional groups into 1-iodoglycals to obtain...
We gratefully acknowledge the National Natural Science Foundation of China(NSFC 21725204,NSFC-22071119);the“111”project(B06005)of MOE China,and NCC2020FH02 for financial support of this work.
A new protocol for the synthesis of 2-deoxy-C-aryl-glycosides and 2-deoxy-C-alkyl-glycosides via iridium-catalyzed directed C—H glycosylation with glycals is reported.The method is amenable for both the C_(2)C—H gly...
A convenient and environmentally benign procedure for the synthesis of glycals from glycosyl bromides with very low zinc dust loading (1.5 equiv.) is described. The process is activated by β-cyclodextrin and ultras...