Project supported by the Scientific Research Foundation of Hunan Provincial Education Department(No.23B0650);the Natural Science Foundation of Hunan Province(No.2022JJ30418);the Key Scientific Research Foundation of Hunan University of Arts and Science(No.22ZD04);the Innovation and Entrepreneurship Training Program for College Students of Hunan University of Arts and Science(No.XDC202318)。
An efficient visible-light-induced radical cascade azidation/cyclization of 2-aryl indoles with trimethylsilyl azide(TMSN3)has been developed using organic dye Rose Bengal as the photocatalyst.This method did not requ...
We appreciate the National Natural Science Foundation of China(22071160)for financial support.
Chiral Lewis acid-catalyzed enantioselective nitrooxylation of cyclic and acyclicβ-keto amides/esters with hypervalent iodine(III)reagents is reported.A number ofα-nitrooxy-β-keto amides/esters were obtained with g...
financial support from the National Natural Science Foundation of China(Nos.21672200,21772185,21801233);the assistance of the product characterization from the Chemistry Experiment Teaching Center of University of Science and Technology of China;supported by China Postdoctoral Science Foundation(No.2018M632532);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000)。
An electrochemical amino-azidation of 2-aminostyre ne with sodium azide(NaN3)was developed,which can be carried out smoothly in water under metal-free condition,affording a series of 3-azido indolines with high yields.
We thank the National Key R&D Program of China(No.2017YFA0700103);the National Natural Science Foundation of China(Nos.21672213,21871258,21922112);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);the Haixi Institute of CAS(No.CXZX-2017-P01);the Innovative Research Teams Program II of Fujian Normal University in China(No.IRTL1703)for financial support.We thank Professor Kuiling Ding,Xue-Long Hou and Chaozhong Li from Shanghai Institute of Organic Chemistry,Armido Studer from University of Münster,Ning Jiao from Peking University,and Weiping Su from our institute for inspiring discussions on this review.
The azido group is found in large numbers of natural products,drugs,biochemicals and materials and to date,many elegant and useful methods for the synthesis of organic azides and their transformations have been docume...
the National Natural Science Foundation of China(Nos.21472172,21272212);Natural Science Foundation of Zhejiang Province(No.LY17B060009)。
The copper-catalyzed directed dearomatization of indoles with the assistance of directing groups has been developed for the synthesis of 2,3-diazido indolines with good yields and excellent diastereoselectivities in a...
We are grateful for financial support from the Na- tional Basic Research Program of China (No. 973-2015CB856600), and the National Natural Science Foundation of China (Nos. 21225210, 21421091 and 21532009).
A palladium-catalyzed oxidative vicinal diazidation of alkenes has been developed, in which TMSN3 was used as azide source. Both styrenes and unactivated alkenes are suitable for this reaction. And trans-alkyldiazides...
1 Introduction Heteroatom-stabilized carbenium ions have been widely recognized as potential electrophilic reagents.However,in contrast with the extensive works on thionium ion series,the highly labile character of se...