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SKELETON: 作品数：439被引量：687H指数：12; 导出分析报告; 相关领域：理学更多>>; 相关作者：赵冰心叶文才董文莉刘宏新郭金庚更多>>; 相关机构：中国科学院软件研究所江西师范大学上海交通大学清华大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划国家高技术研究发展计划中国博士后科学基金更多>>

A Double Helicene with Quadruple Indole-Fused Skeleton and Double NBN-Type Cove-Edged Structure: 《Chinese Journal of Chemistry》2024年第23期3069-3074,共6页Lingjuan Chen Jiaqi Dong Dehui Tan Jianfeng Wu Deng-Tao Yang; the National Natural Science Foundation of China(22001211);the Key Research and Development Program of Shaanxi Province(2023YBGY-454);Shaanxi Fundamental Science Research Project for Chemistry&Biology(Grant No.22JHQ015)for financial support;This project is also supported by the Opening Project of Key Laboratory of Optoelectronic Chemical Materials and Devices of Ministry of Education,Jianghan University(No.JDGD-202208);the Fundamental Research Funds for the Central Universities.; Construction of helicenes by inducing heteroatoms has regarded as an effective strategy to enhance the chiroptical properties.We report a facile synthesis of a multiple helicene based on four indoles with two electron...; 关键词：NBN Double helicene Cove-edged Indole-fused π-conjugated

Skeleton Rearranged and Oxygenated ent-Rosane Diterpenoids with Antiadipogenic Activity from Euphorbia milii: 《Chinese Journal of Chemistry》2024年第24期3211-3218,共8页Qin-Qin Song Yue Guo Peng Sun Yao-Yue Fan Kai-Long Ji; Financial support from the National Natural Science Foundation of China(No.82122062);the 145 Programs(XTBG-145)of Xishuangbanna Tropical Botanical Garden,Chinese Academy of Sciences(CAS);the Program of CAS Key Laboratory of Tropical Plant Resources and Sustainable Use(No.20228012802)is highly acknowledged.; Five unreported and oxygenated ent-rosane diterpenoids(ent-RDs),Euphomillanols A—E(1—5),were isolated from Euphorbia milii.Among them,compounds 1 and 2 are unprecedented 7/7/6-fused tricyclic 5,10-seco-ent-RDs and p...; 关键词：ent-Rosane diterpenoids Euphorbia milii Structure elucidation Configuration determination Biosynthetic pathway hypothesis Oxidation Biological activity Antiadipogenic activity

A Series of Soluble Planar Oligorylenes up to Hexarylene: 《Chinese Journal of Chemistry》2023年第9期1023-1027,共5页Ryuichi Fujita Shoko Yoshida Haruka Kano Kyohei Matsuo Hironobu Hayashi Hiroko Yamada Naoki Aratani; supported by Grants-in-Aid for Scientific Research(Nos.JP20H02816(HH),JP20H00379(HY),JP20H05833(HY),JP20H02711(NA),JP22H19067(NA),JP22K05225(KM),JP20K15261(KM))。; Preparation of large rylenes often needs the use of solubilizing groups along the rylene backbone,which results in the distortion of the skeleton and thus broadening of the absorption spectrum.In this work,we successf...; 关键词：Oligorylenes Undistorted skeleton Near infrared absorption Crystal structure Effective conjugation length

A New Polynitrogen-Heterocyclic Scaffold 2,4,6,8-Tetraazanoradamantane Skeleton:Synthesis and Conversion of Its Functionalities: 《Chinese Journal of Chemistry》2023年第7期783-789,共7页ongbin Cai Bing Li Tianjiao Hou Qi Zhou Yunzhi Liu Huan Li Yuan Gao Longyi Zhu Jun Luo; financial support from the National Natural Science Foundation of China(22075144);the Natural ScienceFoundationof Jiangsu Province(BK20200459).; Comprehensive Summary 2,4,6,8-Tetraazanoradamantane skeleton is a unique rigid cage-like organic structure that has not been established.In this article,a facile protocol to build all-bridge-position-functionalized 2,...; 关键词：Cage compounds Tetraazanoradamantane Multicomponent reactions Nitrogen heterocycles CONDENSATION

A New Discovery towards Novel Skeleton of Benzimidazole-Conjugated Pyrimidinones as Unique Effective Antibacterial Agents被引量：2: 《Chinese Journal of Chemistry》2022年第22期2642-2654,共13页Xi Yang Rasheed Syed Bo Fang Cheng-He Zhou; supported by grants from the National Natural Science Foundation of China(No.21971212);the Research Fellowship for International Young Scientists from International(Regional)-Cooperation and Exchange Program of China National Natural ScienceFoundation(No.81350110523);theKey Project of Innovation Research 2035Pilot Plan of Southwest University(SWU-XDZD22007).; A class of new potential antibacterial agents with distinctive pyrimidinone benzimidazole skeleton was developed through nucleophilic substitution and Biginelli reaction starting from urea,ethyl 4-chloroacetoacetate a...; 关键词：PYRIMIDINONE BENZIMIDAZOLE Antibacterial Resistance Membrane

Construction of the Hexacyclic Core of Dispirocochlearoids A-C via a Diels-Alder Reaction被引量：1: 《Chinese Journal of Chemistry》2022年第13期1566-1570,共5页Qiang Fu Yonghui Wang Fajun Nan; The natural products of dispirocochlearoids are complex Ganoderma meroterpenoids featuring a 6/6/5/6/6/6 ring system and are selective cox-2 inhibitors.Herein,we describe our progress regarding the total synthesis of ...; 关键词：Natural products Dispirocochlearoids Hexacyclic skeleton CYCLOADDITION Total synthesis

Anisotanols A—D,Four Norsesquiterpenoids with an Unprece-dented Sesquiterpenoid Skeleton from Anisodus tanguticus被引量：4: 《Chinese Journal of Chemistry》2021年第12期3375-3380,共6页Hao-Yu Zhao Qin-Mei Zhou Huan Zhu Fei Zhou Chun-Wang Meng Hong-Zhen Shu Zhao-Hua Liu Cheng Peng Liang Xiong; This work was supported by the National Natural Science Foundation of China(NNSFC,Grant Nos.82022072 and 81891012);the Fok Ying Tung Education Foundation(Grant No.171037);the Sichuan Science and Technology Program(Grant No.2018JZ0081);the"Xinglin Scholar"Plan of Chengdu University of TCM(Grant Nos.YXRC2018005,BSH2018009,and QNXZ2019030).; Anisotanols A—D(1-4),four new compounds possessing an unprecedented sesquiterpenoid skeleton with a congested tricyclic 6/3/5 ring system,were obtained from Anisodus tanguticus.Their structures were elucidated by com...; 关键词：Anisodus tanguticus TERPENOIDS Structure elucidation Anisotane-type ANGIOGENESIS

Ag Nanoparticles Anchored on Nanoporous Ge Skeleton as High-Performance Anode for Lithium-ion Batteries被引量：2: 《Chinese Journal of Chemistry》2021年第10期2881-2888,共8页Ji Zhou Peng Huang Qin Hao Lina Zhang Hong Liu Caixia Xu Jinghua Yu; supported by National Natural Science Foundation of China(51772133);Shandong Province(ZR2017JL022);the Taishan Scholar Project of Shandong Province,the project of"20 Items of University"of Jinan(2018GXRC001);Case-by-Case Project for Top Outstanding Talents of Jinan.; Main observation and conclusion Nanoporous(NP)Ge/Ag composite is controllably fabricated via one simple dealloying method under mild conditions.After corroding the well-designed Ge9Ag1Al90 source alloy,the resulting G...; 关键词：Germanium Nanostructures DEALLOYING ANODE Lithium-ion batteries

A Journey to SPSiOL,a New Type of Chiral Ligand Scaffold被引量：1: 《Chinese Journal of Chemistry》2020年第10期1203-1204,共2页Hong-Chao Chen Xin Chang; The development of privileged chiral architectures,which are versatile for various chiral ligands or organocatalysts preparation with superior performance in a variety of organic transformations,has significantly push...; 关键词：CHIRAL SKELETON BACKBONE

Controllable Skeleton Rearrangement of 3-Substituted Cyclobutanones under Basic Conditions被引量：1: 《Chinese Journal of Chemistry》2020年第10期1103-1106,共4页Peng Yan Qiang Zhou Jun Chen Ping Lu; This work was supported by the National Natural Science Foundation of China(Nos.21772024,21921003);1000-Youth Talents Program and Fudan University(for the start-up grant)。; Summary of main observation and conclusion Divergent skeleton rearrangements of cyclobutanones under simply basic conditions have been de-scribed.The reaction pathway is controlled by the nature of 2 group on 3-substi...; 关键词：SUBSTITUTED SKELETON simply

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