云南高校图书馆联盟文献共享服务平台- RHODIUM

RHODIUM: 作品数：162被引量：179H指数：7; 导出分析报告; 相关领域：理学更多>>; 相关作者：王佰全李存耀丁云杰姜淼刘佳更多>>; 相关机构：南开大学中国科学院大学中国科学院华东师范大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>

Rhodium-Catalyzed Asymmetric Hydrogenation of Tetrasubstitutedα,β-Unsaturated Amides:Efficient Access to Chiralβ-Amino Amides: 《Chinese Journal of Chemistry》2024年第21期2641-2646,共6页Bing Jiao Fangyuan Wang Hui Lv; financial support from the National Natural Science Foundation of China(Grant Nos.22071188,22371217);Hubei Provincial Natural Science Foundation of China(2023AFA011).; The first asymmetric hydrogenation of acyclic tetrasubstitutedα,β-unsaturated amides has been achieved by using Rh/DuanPhos complex as a catalyst,delivering chiralβ-amino amides with two contiguous chiral centers i...; 关键词：Asymmetric hydrogenation β-Amino amides Asymmetric catalysis Contiguous chiral centers RHODIUM AMINES Reduction ENANTIOSELECTIVITY

Rhodium-Catalyzed Regioselective C-O and C-C Bonds Formation of 3-Oxopent-4-enenitriles with Alkynes for the Synthesis of Polysubstituted 2H-Pyrans: 《Chinese Journal of Chemistry》2024年第17期1986-1992,共7页Kelu Yan Xiao Liu Jiangwei Wen Qiuyun Li Junjie Wang Yang Zheng Xiu Wang; supported by the National Natural Science Foundation of China(No.22101152);the Youth Talent Program Startup Foundation of Qufu Normal University(No.614201);the School-Level Research Projects of Yancheng Institute of Technology(No.xjr2020044).; The rhodium-catalyzed C-H bond activation and cyclization of 3-oxopent-4-enenitriles with alkynes proceed efficiently.Various 2H-pyrans with multiple substituents are achieved in good yields through regioselective for...; 关键词：Rhodium/C-H activation 3-Oxopent-4-enenitriles ALKYNES 2H-Pyrans Transition metals Regioselectivity Cyclization Comprehensive Summary

Rhodium-Catalyzed Asymmetric Transfer Hydrogenation of Heterocyclic Diaryl Ketones:Facile Access to Key Intermediate of Baloxavir: 《Chinese Journal of Chemistry》2024年第1期43-47,共5页Li Wang Renwei Xiao Jingyuan Song Long-Sheng Zheng Qiwei Lang Gen-Qiang Chen Xumu Zhang; the Southern University of Science and Technology(start-up fund),Shenzhen Science and Technology Innovation Committee(No.KQTD20150717103157174);Stable Support Plan Program of Shenzhen Natural Science Fund(Program Contract No.20200925161222002);Key-Area Research and DevelopmentPt rogramofGuangdong Province((No.2020B010188001);Innovative Team of Universities in Guangdong Province(No.2020KCXTD016);National Natural Science Foundation of China(No.21991113);the National Natural Science Foundation of China(No.22171129);Shenzhen Science and Technology Innovation Committee(JCYJ20210324104202007)for financial support.; Transition metal-catalyzed asymmetric transfer hydrogenation has been proven to be a powerful approach for the synthesis of chiral alcohols.Herein,a highly efficient and enantioselective transfer hydrogenation of dibe...; 关键词：Asymmetric transfer hydrogenation Baloxavir Chiral alcohol ENANTIOSELECTIVITY Heterocyclic diaryl ketone Rhodium(Ⅱ)

Rhodium(III)-Catalyzed Atroposelective C-H Indolylization of 1-Aryl Isoquinolines with 3-Indolylphenyliodonium Salts: 《Chinese Journal of Chemistry》2023年第20期2684-2690,共7页Dong-Song Zheng Jun Zheng Qiang Wang Qing Gu Shu-Li You; We thank the National Key R&D Program of China(2021YFA1500100);National Natural Science Foundation of China(21821002,92256302,22071260);Science and Technology Commission of Shanghai Municipality(21520780100)for generous financial support.S.-L.Y.thanks the supports from the New Cornerstone ScienceFoundation.; Rhodium(III)-catalyzed enantioselective C-H indolylization of isoquinolines was developed.The C-H coupling reactions between 1-aryl isoquinoline derivatives and 3-indolylphenyliodonium salts proceeded smoothly in the ...; 关键词：Asymmetric catalysis Axially chiral biaryl compounds C-H indolization CROSS-COUPLING ENANTIOSELECTIVITY Rh catalysis

Derivation of Benzothiadiazine-1,1-dioxide Scaffolds via Transition Metal-Catalyzed C-H Activation/Annulation: 《Chinese Journal of Chemistry》2023年第16期1973-1978,共6页Ruizhi Lai Shuran Xu Qingyao Zhang Hui Zhou Cankun Luo Yuerong Wang Li Hai Yong Wu; Sichuan Science and Technology Program(No:2020YJ0221);the Natural Science Foundation of Shandong Province,China(No.ZR2021QH362).; Comprehensive Summary Benzothiadiazine-1,1-dioxide scaffold is bioactive framework with wild utility and applications.Synthesis of benzothiadiazine-fused isoquinoline derivatives and spiro benzothiadiazine derivatives...; 关键词：C-H activation ANNULATION RUTHENIUM RHODIUM HETEROCYCLES Fused-ring systems Spiro compounds Diazo compounds

A One-Pot Strategy for the Synthesis of β-Substituted Rhoda-and Irida-Carbolong Complexes被引量：2: 《Chinese Journal of Chemistry》2022年第15期1777-1784,共8页Binbin Xu Wei Mao Chengcheng Wu Jinhua Li Zhengyu Lu Ming Luo Liu Leo Liu Lingling Mao Dafa Chen Haiping Xia; We gratefully acknowledge the NSFC(Nos.22071098,21871068,22101123 and 22101115);the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);the Shenzhen Science and Technology Innovation Committee(Nos.JCYJ20200109140812302 and JCYJ20210324105013035),for their financial support.; Comprehensive Summary Starting from an organic multiyne,three steps are normally needed for the preparation of non-βphosphonium functionalized rhodaand irida-carbolong complexes.Herein,a one-pot strategy,by mixing a ...; 关键词：Carbolong chemistry METALLACYCLES RHODIUM IRIDIUM Tridentate ligands

A Rhein-Based Rh(Ⅲ) Arene Complex with Anti-tumor Cell Proliferative Activity Inhibits RNA Demethylase FTO被引量：3: 《Chinese Journal of Chemistry》2022年第10期1156-1164,共9页Lu Liu Yaqiong Kong Liang He Xiuxiu Wang Meng-Meng Wang Hongjiao Xu Cai-Guang Yang Zhi Su Jing Zhao Zong-Wan Mao Yue Huang Hong-Ke Liu; We thank NSFC(Nos.22077066,21771109,21778033,21701195,21837006,21977052 and 21907101).; Metallodrugs with fine-tuned coordination between metals and bioactive ligands can achieve cytotoxic effects in cancer therapy and have been considered as a new approach for drug design.However,it has yet to be elucid...; 关键词：RHODIUM mRNA ANTIPROLIFERATION FTO m^(6)A

Rhodium-Catalyzed Direct C-H Alkenylation of Indoles with Alkenyl Borates: 《Chinese Journal of Chemistry》2021年第10期2823-2828,共6页Ze-Tian Wang Zi-Ang Zheng Peng-Jie Li Chun-Ni Zhou Shao-Jun Cai Biao Xiao Liang Wang; We are grateful to the National Natural Science Foundation of China(No.21302064);the Natural Science Foundation of Hubei Province(No.2017CFB690).; Main observation and conclusion A new Rh(Ⅲ)-catalyzed direct C—H alkenylation of 2,3-unsubstitued indoles with alkenyl borates through C—H activation followed by transmetallation was described.This protocol provide...; 关键词：RHODIUM C-H activation Terminal alkenylindoles Alkenyl borates Nitrogen heterocycles

Rhodium(Ⅰ)-Catalyzed Enantioselective C(sp^(3))-H Functionalization via Carbene-Induced Asymmetric Intermolecular C-H Insertion: 《Chinese Journal of Chemistry》2021年第7期1911-1915,共5页Bo Liu Ming-Hua Xu; Financial support from the National Natural Science Foundation of China(Nos.21971103,21672229);the National Science&Technology Major Project"Key New Drug Creation and Manufacturing Pro-gram",China(No.2018ZX09711002-006);the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002)is gratefully acknowledged.; Main observation and conclusion Transition-metal-catalyzed C-H insertion of metal-carbene represents an excellent and powerful approach for C-H functionalization.However,despite remarkable advances in metal-carbene ch...; 关键词：Asymmetric catalysis C-H functionalization CARBENE C-H insertion RHODIUM

Understanding Mechanistic Differences between 3-Diazoindolin-2-lmines and N-Sulfonyl-1,2,3-Triazoles in the Rh_(2)(ll)-Catalyzed Reactions with Nitrosoarenes: 《Chinese Journal of Chemistry》2021年第6期1565-1572,共8页Rui Fu Luyao Kou Ke Gao Shaofang Zhou Xiaoguang Bao; the National Natural Science Foundation of China(No.21973068);the Project of Scientific and Technologic Infrastructure of Suzhou(No.SZS201708);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)for financial support.; The employment of α-iminometallocarbenes to construct valuable N-containing compounds has attracted significant research interest.Herein,the nucleophilic addition of nitrosoarenes with the α-imino rhodium carbene sp...; 关键词：a-lmino rhodium carbene Nitrosoarene Reaction mechanism Chemo-selectivity Density functional theory

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