ALLYLIC

作品数：51被引量：38H指数：4
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相关领域：理学更多>>
相关作者：王刚伟张万斌杨尚东徐永强涂永强更多>>
相关机构：兰州大学上海交通大学华南理工大学更多>>
相关期刊：《有机化学》《Science Bulletin》《Green Synthesis and Catalysis》《Science China Chemistry》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry更多>>
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Rhodium-Catalyzed Asymmetric Trifluoromethoxylation of Racemic Allylic Trichloroacetimidates
《CCS Chemistry》2024年第8期1885-1894,共10页Liyan Wang Yafeng Si Yu-Xin Luan Pingping Tang 
supported by the National Key Research and Development Program of China(grant no.2021YFF0701700);the National Natural Science Foundation of China(grant nos.21925105,92156001,and 22101141);the Natural Science Foundation of Tianjin(grant no.18JCJQJC47000);the Haihe Laboratory of Sustainable Chemical Transformations,and the Fundamental Research Funds for the Central Universities.
A rhodium/diene catalyzed asymmetric allylic trifluoromethoxylation reaction is reported,which afforded chiral trifluoromethoxylated allylic compounds in 52%–97%yields with up to 97%enantiomeric excess.These are the ...
关键词：asymmetric trifluoromethoxylation trifluoromethyl arylsulfonates rhodium trichloroacetimidates chiral diene ligand 
Copper-Catalyzed Highly Enantioselective 1,4-Protoboration of Terminal 1,3-Dienes
《CCS Chemistry》2022年第5期1545-1556,共12页Qitao Guan Yuqi Ji Qian Zhao Chun Zhang 
a generous grant from Tianjin University,National Natural Science Foundation of China(no.21801181).
The copper-catalyzed,highly enantioselective 1,4-protoboration of terminal 1,3-dienes with proton source and B2Pin2 has been developed.Chiral allylic boronate reagents,which are significant precursors for many well-es...
关键词：COPPER-CATALYZED ENANTIOSELECTIVITY regioselectivity conjugated addition chiral borated allylic reagents 
Stereodivergent Pd/Cu Catalysis for Asymmetric Desymmetric Alkylation of Allylic Geminal Dicarboxylates被引量：2
《CCS Chemistry》2022年第5期1720-1731,共12页Xiaohong Huo Ling Zhao Yicong Luo Yue Wu Yuwen Sun Guanlin Li Tatiana Gridneva Jiacheng Zhang Yong Ye Wanbin Zhang 
supported by the National Natural Science Foundation of China(nos.21620102003,21831005,21901158,and 21991112);the Shanghai Sailing Program(no.19YF1421900);Shanghai Municipal Education Commission(no.201701070002E00030);National Key R&D Program of China(no.2018YFE0126800);the Science and Technology Commission of Shanghai Municipality(no.19JC1430100);Zhiyuan Scholar Program(no.ZIRC2020-04).
AstereodivergentPd/Cucatalyst systemforasymmetric desymmetric alkylation of allylic geminal dicarboxylates has been developed,which was successfully applied to the asymmetric synthesis of β-hydroxycarbonylmotifs bear...
关键词：stereodivergent synthesis bimetallic catalysis DESYMMETRIZATION Pd/Cu dual catalysis asymmetric allylic substitution 
Platinum-Catalyzed Allylic C-H Alkylation with Malononitriles被引量：2
《CCS Chemistry》2022年第4期1366-1375,共10页Lian-Feng Fan Pei-Pei Xie Pu-Sheng Wang Xin Hong Liu-Zhu Gong 
The financial support from the National Nature Science Foundation of China(NSFC)(nos.21831007 and 21672197 for L.-Z.G.and nos.21702182 and 21873081 for X.H.);the Chinese Academy of Sciences(grant no.XDB20020000);Youth Innovation Promotion Association CAS,Fundamental Research Funds for the Central Universities(no.2020XZZX002-02 for X.H.);the State Key Laboratory of Clean Energy Utilization(no.ZJUCEU2020007 for X.H.)is gratefully acknowledged.
The direct functionalization of allylic C-H bonds is distinguished by enabling rapid assembly of structural complexity from simple molecules.Although Pd-catalyzed allylic C-H functionalization has been extensively stu...
关键词：platinum catalysis PHOSPHORAMIDITE C-H activation allylic alkylation concerted proton and two-electron transfer 
Highly Diastereo-and Enantioselective Synthesis of Quinuclidine Derivatives by an Iridium-Catalyzed Intramolecular Allylic Dearomatization Reaction被引量：1
《CCS Chemistry》2019年第1期106-116,共11页Lin Huang Yue Cai Hui-Jun Zhang Chao Zheng Li-Xin Dai Shu-Li You 
Asymmetric construction of quinuclidine derivatives has been realized by an iridium-catalyzed allylic dearomatization reaction.The catalytic system,derived from[Ir(cod)Cl]2 and the Feringa ligand,tolerates a broad ran...
关键词：asymmetric catalysis DEAROMATIZATION INDOLE IRIDIUM 
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