This work is supported by the National Natural Science Foundation of China(Nos.21772038,21971062,and 21901072);Shanghai Sailing Program(No.18YF140560).
of main observation and conclusion A palladium-catalyzed asymmetric[4+3]cycloaddition of trimethylenemethanes and indoline-derived aza-dienes has been developed.The potential[3+2]side pathway was completely suppressed...
A regio- and stereo-selective reduction of diketo-n-butylphosphonates by baker's yeast was reported. The chemical yield and ee value of these reactions are highly dependent on the structure of substrates. The result...
Reaction of 2,3-dihydro-1H-l,5-benzodiazepines with dichlorocarbene generated in situ using benzyltriethylammonium chloride (TEBA) as a phase transfer catalyst in chloroform-aqueous sodium hydroxide mixture gave main...
Project supported by the National Natural Science Foundation of China and Chinese Academy of Sciences.
The nucleophilic hydrohalogenation of 2-alkynoic acids anti their derivatives by heating with lithium halides iu HOAc afforded the thermodynamically unfavorable 3-halo-2 (Z)- alkenoic acids and their derivatives stere...
The negative ion fast atom bombardment (NIFAB) mass spectra of mono-,di-saccharides and glycosides using phenylboronic acid (PBA) as reagent have been studied.In the ion source,PBA reacts stereospecifically with the m...