SILYL

作品数:36被引量:11H指数:2
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相关领域:理学更多>>
相关作者:朱丽娟柴永海刘子奇张琦更多>>
相关机构:延边大学淮北师范大学陕西师范大学中国石油大学(华东)更多>>
相关期刊:《Science China Chemistry》《Open Journal of Polymer Chemistry》《Chinese Journal of Structural Chemistry》《Advances in Microbiology》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中央高校基本科研业务费专项资金陕西省自然科学基金更多>>
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Copper-catalyzed 1,4-silylcyanation of 1,3-enynes:A silyl radical-initiated approach for synthesis of difunctionalized allenes
《Chinese Chemical Letters》2025年第3期277-281,共5页Qi Li Zi-Lu Wang Yun-He Xu 
support of this work by the funding of the National Natural Science Foundation of China(No.22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(No.202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(No.KFJJ2022013)。
Herein,we developed the first example of copper-catalyzed silicon radical-initiated 1,4-silylcyanation of unactivated 1,3-enynes,which provided an efficient method to access CN-bearing tri-and tetrasubstituted homoall...
关键词:Copper-catalyst Unactivated enynes 1 4-Difunctionalization Radical silylation CYANATION 
Visible Light-Promoted Aerobic Oxidation ofα-Silyl Styrenes with Alcohols
《Chinese Journal of Chemistry》2024年第24期3243-3247,共5页Yan Tan Bo Yang Jiale Ying Bing Yu Zhan Lu 
Financial supports were provided by the NSFC(22271249);the National Key R&D Program of China(2021YFF0701600 and 2021YFA1500200);the Fundamental Research Funds for the Central Universities(226-2022-00224 and 226-2024-00003);Zhejiang Provincial Natural Science Foundation of China(LDQ24B020001).
A mechanistically distinctive visible-light-promoted metal-free aerobic oxidation of alkenyl silanes with alcohols was disclosed to efficiently constructα-alkoxy ketones under mild conditions.The primary,secondary,an...
关键词:Alkenyl silanes Aerobic oxidation ALCOHOLS α-Alkoxy ketones Visible light photocatalysis Radical reactions Synthetic methods Redox reactions 
Light-, Middle- and Heavy-Lanthanide Ate-Complexes Bearing Ln(Ⅲ)-Si bonds: Structural, Spectroscopic, and Bonding Analysis被引量:1
《Chinese Journal of Chemistry》2023年第22期2995-3002,I0002,共9页Xiaowei Pan Changjiang Wu Huayi Fang Chunhua Yan 
the financial supports from the Ministry of Science and Technology of the People's Republic of China(No.2021YFA1202400);the National Natural Science Foundation of China(No.22071122,22271158);the Fundamental Research Funds for the Central Universities(Nankai University).
Recent decades have witnessed a rapid development of the lanthanide silicon chemistry.In this research,by reacting[(THF)_(3)LisiPh_(3)]with Cp_(3)Ln(Ⅰ)(THF)(Ln(I)=Sm(Ⅰ),Tb(Ⅱ),Dy(Ⅰ),Yb(Ⅰ)or Cp_(2)Lu(Ⅱ)CI(THF),a s...
关键词:Lanthanide ate-complex Silyl ligand Lanthanide-silicon bond Structure elucidation Density functional calculations METALLOCENES 
MnBr_(2)catalyzed regiospecific oxidative Mizoroki-Heck type reaction
《Chinese Chemical Letters》2022年第5期2391-2396,共6页Xiang Chen Zhihong Zhu Shanshan Liu Yi-Hung Chen Xiao Shen 
the National Natural Science Foundation of China (No. 21901191);the Fundamental Research Funds for the Central Universities and Wuhan University for financial support
Herein, we report an unprecedented regiospecific oxidative Mizoroki-Heck type reaction for the synthesis of α-difluoromethyl homoallylic alcohols. The reaction shows broad substrate scopes and high functional group t...
关键词:FLUOROALKYLATION Mizoroki-Heck Mn catalysis Radical 1 2-silyl transfer Homoallylic alcohols 
Multiwalled Carbon Nanotubes Modified with Silylated-salicylaldimine Co(II) and Pd(II) Complexes as Precatalysts in Ethylene Oligomerization
《Chemical Research in Chinese Universities》2022年第2期552-561,共10页XUE Jingqi LI Feng ZHAI Xue LI Dan GUO Lijun LI Cuiqin 
supported by the Natural Science Foundation of Heilongjiang Province of China(No.E2018012);the Postdoctoral Foundation of Heilongjiang Province of China(No.16190023).
MWCNTs-Co(II) and Pd(II) were prepared through grafting silylated-salicylaldimine Pd(II) and Co(II) on multiwalled carbon nanotubes(MWCNTs) for ethylene oligomerization. The structures of the two MWCNTs-supported cata...
关键词:Ethylene oligomerization Multiwalled carbon nanotube Confinement effect Heterogeneous catalyst 
MTBSTFA derivatization-LC-MS/MS approach for the quantitative analysis of endogenous nucleotides in human colorectal carcinoma cells
《Journal of Pharmaceutical Analysis》2022年第1期77-86,共10页Huixia Zhang Yan Li Zheng Li Christopher Wai-Kei Lam Peng Zhu Caiyun Wang Hua Zhou Wei Zhang 
supported by Science and Technology Development Fund, Macao SAR (File Nos.: 0052/2018/A2 and 0077/2019/ A2);the National Natural Science Foundation of China (Grant No.: 61827819)
Endogenous ribonucleotides(RNs)and deoxyribonucleotides(dRNs)are important metabolites related to the pathogenesis of many diseases.In light of their physiological and pathological significances,a novel and sensitive ...
关键词:RIBONUCLEOTIDES Deoxyribonucleotides DERIVATIZATION N-(t-butyldimethylsilyl)-N-methyltrifluoroacetamide High-performance liquid chromatography tandem mass spectrometry 
Diverse Fates of β-Silyl Radical under Manganese Catalysis: Hydrosilyla-tion and Dehydrogenative Silylation of Alkenes被引量:2
《Chinese Journal of Chemistry》2018年第11期1047-1051,共5页Xiaoxu Yang Congyang Wang 
Synthesis, Structural Studies and Reactivity of Two cis-Bis(phosphine)bis(silyl) Palladium(ll) Complexes被引量:1
《Chinese Journal of Chemistry》2017年第4期507-511,共5页Lizhong Wang Jinfei Guo Yajuan Li Yanrong Su Jiawei Liu Yonghua Li Shi Wang Shigeru Shimada Wei Huang 
This work was financially supported by the National Key Basic Research Program of China (No. 2014CB648300), the National Natural Science Founda- tion of China (Nos. 51173082 and 51274159), the Nat- ural Science Foundation of Jiangsu Province (No. BK20141425), the Natural Science Foundation of Colleges and Universities in Jiangsu Province (No. 13KJB150028), the Jiangsu Province Domestic Senior Visiting Scholars in Higher Vocational Colleges Project Funds to Lizhong Wang (No. 2016GRFX055), the Pri- ority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions and the Ministry of Education of China (No. IRT 1148).
Treatment of 1,2-C6H4(SiH3)(SiH3) (1) or 1,2-C6H4(SiMe2H)(SiH3) (2) with Pd(dcpe)(PEt3)2 (dcpe?=?Cy2PCH2CH2PCy2) in the ratio of 1∶1 affords two cis- bis(silyl) palladium(II) complexes {1,2-C...
关键词:silyl hydride CHELATING PALLADIUM multinuclear NMR 
Contactless Raman Spectroscopy-Based Monitoring of Physical States of Silyl-Modified Polymers during Cross-Linking
《Green and Sustainable Chemistry》2016年第4期151-166,共17页Boris Colin Olivier Lavastre Stéphane Fouquay Guillaume Michaud Frédéric Simon Olivier Laferte Jean-Michel Brusson 
Cross-linking of silyl-modified polymers occurs at the alkoxysilane groups attached to the ends of polymer chains by hydrolysis and polycondensation mechanisms in the presence of moisture. During these reactions, thre...
关键词:Silyl Modified Polymers Physical States Micro Contactless Monitoring Raman Spectroscopy Cross-Linking 
Zirconium-mediated Selective Synthesis of 1,4-Dialkyl(aryl)-hexa-substituted Benzenes from Two Silyl-substituted Alkynes and One Internal Alkyne
《Chemical Research in Chinese Universities》2016年第3期366-372,共7页LI Junqiu ZHANG Jiqian QU Hongmei LIU Jun LI Juan ZHOU Lishan 
Supported by the National Natural Science Foundation of China(No.21102099).
Based on the formation of 2,5-bis(trimethylsilyl)-zirconacyclopentadienes from two silylalkynes with CpEZrBu2 and the Cu-mediated formation of 1,4-disilylbenzene via the cycloaddition of zirconacyclopentadienes to d...
关键词:ZIRCONIUM Hexa-substituted benzene IODINATION Coupling reaction 
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