support of this work by the funding of the National Natural Science Foundation of China(No.22371269);the State Key Laboratory of Elementoorganic Chemistry Nankai University(No.202001);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB0450301);the Open Project of Key Laboratory of Organosilicon Chemistry,and Material Technology of Ministry of Education,Hangzhou Normal University(No.KFJJ2022013)。
Herein,we developed the first example of copper-catalyzed silicon radical-initiated 1,4-silylcyanation of unactivated 1,3-enynes,which provided an efficient method to access CN-bearing tri-and tetrasubstituted homoall...
Financial supports were provided by the NSFC(22271249);the National Key R&D Program of China(2021YFF0701600 and 2021YFA1500200);the Fundamental Research Funds for the Central Universities(226-2022-00224 and 226-2024-00003);Zhejiang Provincial Natural Science Foundation of China(LDQ24B020001).
A mechanistically distinctive visible-light-promoted metal-free aerobic oxidation of alkenyl silanes with alcohols was disclosed to efficiently constructα-alkoxy ketones under mild conditions.The primary,secondary,an...
the financial supports from the Ministry of Science and Technology of the People's Republic of China(No.2021YFA1202400);the National Natural Science Foundation of China(No.22071122,22271158);the Fundamental Research Funds for the Central Universities(Nankai University).
Recent decades have witnessed a rapid development of the lanthanide silicon chemistry.In this research,by reacting[(THF)_(3)LisiPh_(3)]with Cp_(3)Ln(Ⅰ)(THF)(Ln(I)=Sm(Ⅰ),Tb(Ⅱ),Dy(Ⅰ),Yb(Ⅰ)or Cp_(2)Lu(Ⅱ)CI(THF),a s...
the National Natural Science Foundation of China (No. 21901191);the Fundamental Research Funds for the Central Universities and Wuhan University for financial support
Herein, we report an unprecedented regiospecific oxidative Mizoroki-Heck type reaction for the synthesis of α-difluoromethyl homoallylic alcohols. The reaction shows broad substrate scopes and high functional group t...
supported by the Natural Science Foundation of Heilongjiang Province of China(No.E2018012);the Postdoctoral Foundation of Heilongjiang Province of China(No.16190023).
MWCNTs-Co(II) and Pd(II) were prepared through grafting silylated-salicylaldimine Pd(II) and Co(II) on multiwalled carbon nanotubes(MWCNTs) for ethylene oligomerization. The structures of the two MWCNTs-supported cata...
supported by Science and Technology Development Fund, Macao SAR (File Nos.: 0052/2018/A2 and 0077/2019/ A2);the National Natural Science Foundation of China (Grant No.: 61827819)
Endogenous ribonucleotides(RNs)and deoxyribonucleotides(dRNs)are important metabolites related to the pathogenesis of many diseases.In light of their physiological and pathological significances,a novel and sensitive ...
This work was financially supported by the National Key Basic Research Program of China (No. 2014CB648300), the National Natural Science Founda- tion of China (Nos. 51173082 and 51274159), the Nat- ural Science Foundation of Jiangsu Province (No. BK20141425), the Natural Science Foundation of Colleges and Universities in Jiangsu Province (No. 13KJB150028), the Jiangsu Province Domestic Senior Visiting Scholars in Higher Vocational Colleges Project Funds to Lizhong Wang (No. 2016GRFX055), the Pri- ority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions and the Ministry of Education of China (No. IRT 1148).
Treatment of 1,2-C6H4(SiH3)(SiH3) (1) or 1,2-C6H4(SiMe2H)(SiH3) (2) with Pd(dcpe)(PEt3)2 (dcpe?=?Cy2PCH2CH2PCy2) in the ratio of 1∶1 affords two cis- bis(silyl) palladium(II) complexes {1,2-C...
Cross-linking of silyl-modified polymers occurs at the alkoxysilane groups attached to the ends of polymer chains by hydrolysis and polycondensation mechanisms in the presence of moisture. During these reactions, thre...
Supported by the National Natural Science Foundation of China(No.21102099).
Based on the formation of 2,5-bis(trimethylsilyl)-zirconacyclopentadienes from two silylalkynes with CpEZrBu2 and the Cu-mediated formation of 1,4-disilylbenzene via the cycloaddition of zirconacyclopentadienes to d...