PALLADIUM-CATALYZED

作品数:173被引量:138H指数:6
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相关领域:理学更多>>
相关作者:吴养洁崔秀灵张浩刘秀艳龙蓉蓉更多>>
相关机构:郑州大学南开大学辽宁石油化工大学中国人民大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划广东省自然科学基金国家教育部博士点基金更多>>
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Palladium-Catalyzed Regioselective Asymmetric Chemodivergent Allylation of Oxazolones with Morita-Baylis-Hillman Adducts被引量:1
《CCS Chemistry》2023年第12期2790-2798,共9页Rui Zhang Zibo Liu Yong Liu Haoran Yang Xiaoming Wang Zhaobin Han Zheng Wang Kuiling Ding 
financial supports from the National Key R&D Program of China(grant nos.2022YFA1503702 and 2021YFF0701602);NSFC(grant nos.22231011 and 22271303).
Oxazolones are structural subunits in numerous natural products and designed molecules with substantial pharmacological properties.Here,a palladium-catalyzed chemodivergent regio-and enantioselective allylic alkylatio...
关键词:asymmetric catalysis allylic alkylation palladium OXAZOLONES chemodivergent 
Palladium-Catalyzed One-Step Synthesis of Stereodefined Difunctionalized Glycals
《CCS Chemistry》2023年第3期741-749,共9页Xiao-Ping Gong Yuke Li Hong-Chao Liu Zhe Zhang Zhi-Jie Niu Ya-Nan Ding Yang An Xi Chen Yan-Chong Huang Rui-Qiang Jiao Xue-Yuan Liu Yong-Min Liang 
We thank the National Natural Science Foundation of China(NSF 22171114 and 21772075)for its financial support.
Efficiently modifying glycals by directly introducing functional groups into their double bonds is a longstanding challenge.Here,the strategy of introducing two different functional groups into 1-iodoglycals to obtain...
关键词:palladium catalysis GLYCALS tetrasubstitute olefins difunctionalization stereodefined threecomponent 
Excited-State Palladium-Catalyzed α-Selective C1-Ketonylation
《CCS Chemistry》2023年第1期106-116,共11页Gaoyuan Zhao Upasana Mukherjee Lin Zhou Jaclyn NMauro Yue Wu Peng Liu Ming-Yu Ngai 
The research reported in this publication was supported by the National Institutes of Health(grant no.R35-GM119652 to M.-Y.N.and grant no.R35-GM128779 to P.L.);DFT calculations were performed at the Center for Research Computing at the University of Pittsburgh,PA,USA,the Texas Advanced Computing Center(TACC)Frontera supercomputer,TX,USA,and the Extreme Science and Engineering Discovery Environment(XSEDE),TX,USA,supported by the National Science Foundation,VA,USA,grant number ACI1548562;The Shimadzu ultraperformance liquid chromatography/mass spectrometry(UPLC/MS)used for portions of this work were purchased with funds from the National Institute of General Medical Sciences(NIGMS,MD,USA)equipment administrative supplement(grant no.R35-GM119652-04S1),Shimadzu Scientific Instruments grant,and Office of the Vice President for Research at Stony Brook University,NY,USA.
C-Glycosides are important carbohydrate mimetics found in natural products,bioactive compounds,and marketed drugs.However,stereoselective preparation of this class of glycomimetics remains a significant challenge in o...
关键词:excited-state catalysis PALLADIUM glycosyl radical ketonylation silyl enol ethers 
Construction and Functionalization of Highly Strained N-Doped Zigzag Hydrocarbon Belts被引量:1
《CCS Chemistry》2023年第1期117-123,共7页Ming Xie Shuo Tong Mei-Xiang Wang 
We thank the National Natural Science Foundation of China(grant nos.22050005,21732004,and 21821001);the Tsinghua University Initiative Scientific Research Program(grant no.2019Z07L01004)for generous financial support.
Recent years have witnessed breakthroughs in the study of zigzag hydrocarbon belts.However,the synthesis of heterocycle-containing zigzag molecular belts remains very rare and challenging despite their interesting str...
关键词:zigzag molecular belt cyclacene arene[4]pyridine meta-bromination of Nacylaniline palladium-catalyzed C-N bond formation diradical dication salt 
Palladium-Catalyzed Asymmetric Allylic Alkylation/α-Iminol Rearrangement:A Facile Access to 2-Spirocyclic-Indoline Derivatives被引量:2
《CCS Chemistry》2022年第4期1414-1428,共15页Xin Chang Chao Che Zuo-Fei Wang Chun-Jiang Wang 
supported by the NSFC(nos.21525207,21772147,and 220711186);the Huibei Province Natural Science Foundation(no.2020CFA036);Support by the Fundamental Research Funds for the Central Universities;the Program of Introducing Talents of Discipline to Universities of China(111 Program)is also appreciated.
We report an unprecedented Pd-catalyzed asymmetric allylic alkylation of 1-(indol-2-yl)cyclobutanols followed by anα-iminol rearrangement.High yields with excellent chemo-,regio-,diastereo-,and enantioselectivities h...
关键词:asymmetric catalysis 2-spirocyclicindoline allylic alkylation/α-iminol rearrangement racemic allylic alcohol π-cinnamyl-palladium complex 
Site-Selective Palladium-Catalyzed 1,1-Arylamination of Terminal Alkenes
《CCS Chemistry》2022年第2期616-624,共9页Chunhua Han Libo Cai Dongquan Zhang Rui Pan Qiuyu Li Aijun Lin Hequan Yao 
supported by the National Science Foundation of China(no.22071267);the National Science and Technology Major Project“Key New Drug Creation and Manufacturing Program,”China(no.2020ZX09201015);the Innovation Team of the“DoubleFirst Class Initiative”(nos.CPU2018GY04 and CPU2018GY35);the Foundation of the Open Project of State Key Laboratory of Natural Medicines(no.SKLNMZZ202023).
Many of the commonly used pharmaceuticals and biologically active natural products are nitrogencontaining compounds.Recently,the transitionmetal-catalyzed or the radical-mediated 1,2-carboamination of alkenes has been...
关键词:ALKENE 1 1-arylamination PALLADIUM-CATALYZED site-selective nitrogen-containing molecules 
Existence of a Heterogeneous Pathway in Palladium-Catalyzed Carbon–Carbon Coupling Reaction:Evidence from Ag@Pd_(3)Cu Intermetallic Nanoplates
《CCS Chemistry》2022年第2期671-682,共12页Rui Liu Cuihong Xu Yanan Chen Huachao Zhao Jiefang Sun Zuoliang He Wanyu Shan Gang Li Qiantao Shi Liping Fang Jingfu Liu Guibin Jiang 
the National Key R&D Program of China(no.2016YFA0203102);the National Natural Science Foundation of China(nos.21577157,21777177,and 21822608)。
Palladium(Pd)-catalyzed cross-coupling reaction is a widely studied process with significant economic interest and represents one of the most successful nanocatalytic examples.Owing to the observed leaching of Pd ions...
关键词:plasmonic catalysis intermetallics carbon-carbon coupling reaction mechanism heterogeneous pathway 
Palladium-Catalyzed Asymmetric Domino Heck/Carbocyclization/Suzuki Reaction:A Dearomatization of Nonactivated Naphthalenes被引量:3
《CCS Chemistry》2021年第12期69-77,共9页Ming Chen Xucai Wang Zhi-Hui Ren Zheng-Hui Guan 
supported by generous grants from the National Natural Science Foundation of China(nos.NSFC-21971204,21622203,and 21702161);the Innovation Capability Support Program of Shaanxi Province(no.2020TD-022).
Herein,we report a novel palladium(Pd)-catalyzed asymmetric domino Heck/carbocyclization/Suzuki reaction of N-(2-bromoaryl)-2-naphthylacrylamides.The reaction involves a novel and enantioselective dearomative 1,2-inse...
关键词:asymmetric catalysis PALLADIUM-CATALYZED domino Heck reaction DEAROMATIZATION nonactivated naphthalenes 
Stereoselective 1,2-Dicarbofunctionalization of Trisubstituted Alkenes by Palladium-Catalyzed Heck/Suzuki or Heck/Sonogashira Domino Sequence
《CCS Chemistry》2021年第9期2340-2349,共10页Jia-Wen Zhu Bo Zhou Zhong-Yan Cao Ren-Xiao Liang Yi-Xia Jia 
support from the National Natural Science Foundation of China(nos.21702184,21772175,and 91956117).
Highly enantioselective and diastereoselective 1,2-diarylation and 1,2-arylalkynylation of trisubstituted alkenes are reported via the palladium-catalyzed Heck/Suzuki or Heck/Sonogashira domino sequence.These alkenes ...
关键词:asymmetric catalysis palladium SPIROOXINDOLE dicarbofunctionalization trisubstituted alkene 
Palladium-Catalyzed O- and N-Glycosylation with Glycosyl Chlorides被引量:1
《CCS Chemistry》2021年第7期1821-1829,共9页Shuang An Quanquan Wang Wanjun Zhu Qikai Sun Gang He Gong Chen 
G.C.thanks NSFC-91753124,NSFC-21672105,NSFC-21421062,and NSFC-21725204 for financial support for this work.
Despite the significant progress in carbohydrate chemistry,there remains a pressing need for efficient and practical glycosylationmethods using simple glycosyl donors and with high atom economy.Herein,a new protocol f...
关键词:GLYCOSYLATION N-GLYCOSIDES palladium catalysis chloride donor glycosyl ester 
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