National Key Research and Development Program of China(Grant No.2022YFE0208400).
The reliance on fossil fuels intensifies CO_(2) emissions,worsening political and environmental challenges.CO_(2) capture and conversion present a promising solution,influenced by industrialization and urbanization.In...
financially supported by the National Key Research and Development Program of China(No.2020YFA0210900);the National Natural Science Foundation of China(Nos.21938001 and 21878344);Guangdong Provincial Key R&D Programme(No.2019B110206002);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01C102)。
The direct epoxidation of propylene by O_(2) is a significant and challenging topic. The key factor for this homogeneous aerobic epoxidation is the activation of molecular oxygen under mild conditions. In this work,th...
This project was supported by the National Natural Science Foundation of China(Grant Nos.22122812,22075245 and 21961160742)。
Microbial electrosynthesis is a promising alternative to directly convert CO_(2)into long-chain compounds by coupling inorganic electrocatalysis with biosynthetic systems.However,problems arose that the conventional e...
the Decree of the Government of the Russian Federation No.220 of April 9,2010(Agreement No.075-15-2021-615 of June 4,2021).
Photodynamic inactivation of microorganisms known as antibacterial photodynamic therapy(APDT)is one of the most promising and innovative approaches for the destruction of pathogenic microorganisms.Among the photosensi...
support from the National Natural Science Foundation of China(No.21938001 and 21878344);the National Key Research and Development Program of China(2016YFA0602900);the National Natural Science Foundation of ChinaSINOPEC Joint Fund(No.U1663220);Guangdong Provincial Key R&D Programme(2019B110206002);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01C102);Research and Innovation Team Construction Project of Guangdong University of Petrochemical Technology.
Substrate specificity is a hallmark of enzymatic catalysis.In this work,the biomimetic catalytic oxidation of styrene and cyclohexanone by iron(III)porphyrins and molecular oxygen was carried out,and remarkable differ...
supported by the Grants from Chinese Scientific and Technological Major Special Project(2015ZX09J15104002–002,2016ZX09J16104)
AEOL-10150 is a broad-spectrum metalloporphyrin superoxidase dismutase(SOD) mimic specifically designed to neutralize reactive oxygen and nitrogen species. Research has shown that AEOL-10150 is a potent medical counte...
Funded by the National Natural Science Foundation of China(Nos.20674022,20774031,21074039);the Natural Science Foundation of Guangdong(Nos.2006A10702003,2009B090300025,2010A090100001,2014A030313241,2014B090901068,2016A010103003);the Science and Technology Program of Guangdong and Guangzhou;The Ministry of Education of the People’s Republic of China(No.20090172110011)
The porphyrin derivatives, 5,10,15,20-tetra(4-(N-pentane-carboxamide) phenyl) porphyrin(4 NC5-TPP), 5,10,15,20-tetra(4-(N-dodecane-carboxamide) phenyl) porphyrin(4 NC12-TPP) and their zinc-complexes(4 NC5...
Supported by the National Natural Science Foundation of China(21776259,21776321,21706233,21576297,21476270)
A green and efficient method for the selective aerobic oxidation of p-cresol to p-hydroxybenzaldehyde catalyzed by co-catalysts between metalloporphyrins and metal salts was investigated and developed. The relationshi...
This work was financially supported by the National Natural Science Foundation of China (Nos. 21372068, 21572049), the Science and Technology Program of Hunan Province, China (No. 2014GK3115) and the Science and Technology Program of Changsha, China (No. K1508004-11).
A bio-inspired approach for efficient conversion of cellulose to formic acid (FA) was developed in an aqueous alkaline medium. Metalloporphyrins mimicking cytochrome P450 exhibit efficiently and selectively catalyti...
funded by the Fundamental Research Funds for Jiangsu Key Lab of Biomass Energy and Material(No.JSBEM-S-201605);the National Natural Science Foundation of China(No.31600466);the Fundamental Research Funds for the Central Non-profit Research Institution of CAF(No.CAFYBB2014QA022)
Metallodeuteroporphyrins(MDPs) were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this prot...