supported by the National Natural Science Foundation of China(Nos.22272148,22102105).
Improving the catalytic efficiency and anti-poisoning ability of Pt-based catalysts is very critical in methanol electrolysis technology for high-purity hydrogen generation.Herein,the nitrogen-doped carbon polyhedrons...
financial support from the National Natural Science Foundation of China(22061041);Key Project of Science&Technology of Shaanxi Province(2023-YBGY-430);Project of Science&Technology Bureau of Yulin City(CXY-2022-185);The Youth Innovation Team Project of Shaanxi Provincial Education Department(No.23JP193);National Science Foundation of Shaanxi Province(S2023-JC-QN-0079).
The present work prepared a copper N-heterocyclic carbene complex that could be used in catalyzing the homogeneous hydrogenation of carboxylic acid with ammonia borane(hydrogen source)to synthesize primary alcohols.Va...
supported by the Natural Science Foundation of Shandong Province(ZR2019BB011);the Scientific Research Foundation of Qingdao University of Science&Technology(010029022).
A new,selective Ru(Ⅱ)-catalyzed alkynylation reaction of isoquinolones,quinazolones and phthalazinones with readily available bromoalkynes has been developed.This reaction enables the selective construction of a new ...
financial support from the National Natural Science Foundation of China(22061041);Key Project of Science&Technology of Shaanxi Province(2023-YBGY-430);Project of Science&Technology Bureau of Yulin City(CXY-2022-185);Doctoral Research Foundation of Yan'an University(YDBK2019-60);the Training Program of Innovation and Entrepreneurship for Undergraduates of Yan'an University(D2022077);Research Program of Yan'an University(YDY2020-61);the Youth Innovation Team Project of Shaanxi Provincial Education Department(No.23JP193);National Science Foundation of Shaanxi Province(S2023-JC-QN-0079).
Herein,we present a method for the homogeneous hydrogenation of nitroarenes to produce anilines using low catalyst loading(1 mo%)of copper N-heterocyclic carbene complexes as the catalyst and ammonia borane as the sou...
the National Natural Science Foundation of China(Nos.22071149,21871178);the Natural Science Foundation of Shanghai(23ZR1428200);the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning for financial support.
Lewis base catalyzed and Brønsted acid controlled chemodivergent electrophilic selenofunctionalizations of alkynes were developed for the first time.Various selenium-containing tetrasubstituted alkenes were readily ob...
the Key Research and Development Program of the Ministry of Science and Technology of China(2023YFA1508600);the start-up funding from Wuhan University.
As a versatile earth-abundant transition metal,Cu has long been widely applied in the C—C and C—X bond forming reactions.As for now,low-valent Cu(Ⅰ)is known to reduce the redox active electrophiles via an SET pathw...
support from National Key R&D Program of China (2022YFA1504500);the National Natural Science Foundation of China (grant no.92261207,and NSFC Center for Single-Atom Catalysis under grant no.22388102);the New Cornerstone Science Foundation.P.L.acknowledges the Shanghai Pujiang Talent Program (No.21PJ1410400);the Start-up Funding and the Double First-Class Initiative Fund of ShanghaiTech University.R.Q.acknowledges support from the Young Scientists Fund of the National Natural Science Foundation of China (22202164);the Natural Science Foundation of Fujian Province (2023J05006);the Fundamental Research Funds for the Central Universities (20720230002);the Fujian Provincial Chemistry Discipline Alliance.
A new approach to allylic alkylation is realized using an atomically dispersed palladium catalyst(Pd1/TiO2-EG).Unlike conventional methods that require derivation of substrates and utilization of additives,this method...
supports were provided by National Key R&D Program of China (2021YFA1500200 and 2021YFF0701600);NSFC (22271249);the Fundamental Research Funds for the Central Universities (226-2022-00224 and 226-2023-00115).
α-Olefins as aliphatic terminal alkenes could be obtained easily from numerous contemporary synthetic reactions as well as petro-chemical industry,and also found in natural products.Compared to the alkenes attaching ...
the National Natural Science Foundation of Chinaa(Nos.22271113,92256301,21822103,91956201,21820102003 and 21602052);the Natural Science Foundation of Hubei Province(No.2022CFB413);the fund from Central China Normal University for support of this research.
Ureas are widely used in drugs,materials and catalysts because of their diamide structure,which can form strong hydrogen bonds.Therefore,it is of great scientific significance to develop efficient and green methods fo...
the National Key R&D Program of China(No.2021YFA1500100);the National Nature Science Foundation of China(Nos.22101295,21971255,91956202,92256301 and 21821002);the Science and Technology Commission of Shanghai Municipality(Nos.20JC1417000 and 21520780100);the Youth Innovation Promotion Association,CAS(Y2022074).
Alkynes are versatile synthons in organic synthesis,as well as important structural moieties in bioactive molecules.Recently,transition metal-catalyzed hydroalkynylation of alkenes has been developed with reactive alk...