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作品数:1132被引量:1374H指数:10
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相关领域:理学更多>>
相关作者:滕怀龙祝诗发陈自立姚小泉石先莹更多>>
相关机构:中国科学院南开大学郑州大学武汉大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家教育部博士点基金更多>>
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  • 期刊=Chinese Journal of Chemistryx
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Energy-Saving Hydrogen Production from Methanol Electrocatalysis Catalyzed by Molybdenum Phosphide/Nitrogen-Doped Carbon Polyhedrons Supported Pt Nanoparticles
《Chinese Journal of Chemistry》2025年第2期146-154,共9页Jiaojiao Li Meng Li Fulin Yang Ligang Feng 
supported by the National Natural Science Foundation of China(Nos.22272148,22102105).
Improving the catalytic efficiency and anti-poisoning ability of Pt-based catalysts is very critical in methanol electrolysis technology for high-purity hydrogen generation.Herein,the nitrogen-doped carbon polyhedrons...
关键词:Molybdenum phosphide Methanol oxidation reaction Pt-based catalyst Hydrogen evolution reaction ELECTROCATALYST 
Reductive Synthesis of Alcohols from Carboxylic Acids and Esters Catalyzed by a Copper N-heterocyclic Carbene Complex
《Chinese Journal of Chemistry》2025年第1期73-78,共6页Hui Zhou Nana Wei Zhiqiang Ren Haojie Ma Yuqi Zhang Bo Han 
financial support from the National Natural Science Foundation of China(22061041);Key Project of Science&Technology of Shaanxi Province(2023-YBGY-430);Project of Science&Technology Bureau of Yulin City(CXY-2022-185);The Youth Innovation Team Project of Shaanxi Provincial Education Department(No.23JP193);National Science Foundation of Shaanxi Province(S2023-JC-QN-0079).
The present work prepared a copper N-heterocyclic carbene complex that could be used in catalyzing the homogeneous hydrogenation of carboxylic acid with ammonia borane(hydrogen source)to synthesize primary alcohols.Va...
关键词:HOMOGENEOUS Reduction COPPER Carboxylic acids ESTERS 
Ru(Ⅱ)-Catalyzed Selective C-H Alkynylation of Isoquinolones,Quinazolones and Phthalazinones with Bromoalkynes
《Chinese Journal of Chemistry》2024年第15期1686-1690,共5页Quan-Jian Luo Han-Chi Wang Jing Zhang Jin-Heng Li Bo Sun 
supported by the Natural Science Foundation of Shandong Province(ZR2019BB011);the Scientific Research Foundation of Qingdao University of Science&Technology(010029022).
A new,selective Ru(Ⅱ)-catalyzed alkynylation reaction of isoquinolones,quinazolones and phthalazinones with readily available bromoalkynes has been developed.This reaction enables the selective construction of a new ...
关键词:Ru(Ⅱ) ALKYNYLATION Isoquinolones Bromoalkynes Heterocyclic compounds C-H activation C-C coupling Synthetic methods 
Chemoselective Transfer Hydrogenation of Nitroarenes with Ammonia Borane Catalyzed by Copper N-Heterocyclic Carbene Complexes
《Chinese Journal of Chemistry》2024年第15期1721-1726,共6页Hui Zhou Hongmei Jiao Xing Lu Yuanyuan Gao Zhiqiang Ren Haojie Ma Yuqi Zhang Bo Han 
financial support from the National Natural Science Foundation of China(22061041);Key Project of Science&Technology of Shaanxi Province(2023-YBGY-430);Project of Science&Technology Bureau of Yulin City(CXY-2022-185);Doctoral Research Foundation of Yan'an University(YDBK2019-60);the Training Program of Innovation and Entrepreneurship for Undergraduates of Yan'an University(D2022077);Research Program of Yan'an University(YDY2020-61);the Youth Innovation Team Project of Shaanxi Provincial Education Department(No.23JP193);National Science Foundation of Shaanxi Province(S2023-JC-QN-0079).
Herein,we present a method for the homogeneous hydrogenation of nitroarenes to produce anilines using low catalyst loading(1 mo%)of copper N-heterocyclic carbene complexes as the catalyst and ammonia borane as the sou...
关键词:Homogeneous catalysis HYDROGENATION N-Heterocyclic carbene complexes NITROARENES Ammonia borane 
Lewis Base Catalyzed Selenofunctionalization of Alkynes with Acid-Controlled Divergent Chemoselectivity被引量:1
《Chinese Journal of Chemistry》2024年第14期1623-1629,共7页Ling-Ling Chen Ren-Fei Cao Hua Ke Zhi-Min Chen 
the National Natural Science Foundation of China(Nos.22071149,21871178);the Natural Science Foundation of Shanghai(23ZR1428200);the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning for financial support.
Lewis base catalyzed and Brønsted acid controlled chemodivergent electrophilic selenofunctionalizations of alkynes were developed for the first time.Various selenium-containing tetrasubstituted alkenes were readily ob...
关键词:ALKYNES Electrophilic addition CHEMOSELECTIVITY Lewis base catalysis Selenofunctionalization 
Copper Catalyzed Enantioconvergent Nucleophilic Substitutions
《Chinese Journal of Chemistry》2024年第10期1161-1174,共14页Chunxi Huang Zilong Wan Aoping Zhu Caiyou Chen 
the Key Research and Development Program of the Ministry of Science and Technology of China(2023YFA1508600);the start-up funding from Wuhan University.
As a versatile earth-abundant transition metal,Cu has long been widely applied in the C—C and C—X bond forming reactions.As for now,low-valent Cu(Ⅰ)is known to reduce the redox active electrophiles via an SET pathw...
关键词:Enantioconvergent Nucleophilic substitution COPPER Radical reactions PHOTOCATALYSIS Asymmetric catalysis 
Supported Atomically Dispersed Pd Catalyzed Direct Alkoxylation and Allylic Alkylation
《Chinese Journal of Chemistry》2024年第7期719-724,共6页Ruixuan Qin Ziwen Chen Qingyuan Wu Nanfeng Zheng Pengxin Liu 
support from National Key R&D Program of China (2022YFA1504500);the National Natural Science Foundation of China (grant no.92261207,and NSFC Center for Single-Atom Catalysis under grant no.22388102);the New Cornerstone Science Foundation.P.L.acknowledges the Shanghai Pujiang Talent Program (No.21PJ1410400);the Start-up Funding and the Double First-Class Initiative Fund of ShanghaiTech University.R.Q.acknowledges support from the Young Scientists Fund of the National Natural Science Foundation of China (22202164);the Natural Science Foundation of Fujian Province (2023J05006);the Fundamental Research Funds for the Central Universities (20720230002);the Fujian Provincial Chemistry Discipline Alliance.
A new approach to allylic alkylation is realized using an atomically dispersed palladium catalyst(Pd1/TiO2-EG).Unlike conventional methods that require derivation of substrates and utilization of additives,this method...
关键词:Atomically dispersed catalyst ALKYLATION C—C coupling Organic-inorganic Interface Hydrogen bond Tsuji-Trost reaction Green catalysis 
Recent Advances in Enantioselective Reactions of Terminal Unactivated Alkenes被引量:2
《Chinese Journal of Chemistry》2024年第7期760-776,共17页Qihang Guo Xuzhong Shen Zhan Lu 
supports were provided by National Key R&D Program of China (2021YFA1500200 and 2021YFF0701600);NSFC (22271249);the Fundamental Research Funds for the Central Universities (226-2022-00224 and 226-2023-00115).
α-Olefins as aliphatic terminal alkenes could be obtained easily from numerous contemporary synthetic reactions as well as petro-chemical industry,and also found in natural products.Compared to the alkenes attaching ...
关键词:Asymmetric catalysis Terminal unactivated alkenes Hydrofunctionalization Difunctionalization Metal-catalyzed 
Metallaphotoredox-Catalyzed Three-Component Couplings for Practical Synthesis of Ureas and Carbamates
《Chinese Journal of Chemistry》2024年第3期264-270,共7页Ernest Koranteng Zhen-Cao Shu Yi-Yin Liu Qian Yang Bin Shi Qiang-Xian Wu Fen Tan Liang-Qiu Lu Wen-Jing Xiao 
the National Natural Science Foundation of Chinaa(Nos.22271113,92256301,21822103,91956201,21820102003 and 21602052);the Natural Science Foundation of Hubei Province(No.2022CFB413);the fund from Central China Normal University for support of this research.
Ureas are widely used in drugs,materials and catalysts because of their diamide structure,which can form strong hydrogen bonds.Therefore,it is of great scientific significance to develop efficient and green methods fo...
关键词:CROSS-COUPLING NICKEL Photoredox catalysis Three-component reaction UREAS CARBAMATES 
Palladium(Ⅱ)-Catalyzed Markovnikov Hydroalkynylation of Unactivated Terminal Alkenes
《Chinese Journal of Chemistry》2024年第1期29-34,共6页Chuanqi Hou Pinhong Chen Guosheng Liu 
the National Key R&D Program of China(No.2021YFA1500100);the National Nature Science Foundation of China(Nos.22101295,21971255,91956202,92256301 and 21821002);the Science and Technology Commission of Shanghai Municipality(Nos.20JC1417000 and 21520780100);the Youth Innovation Promotion Association,CAS(Y2022074).
Alkynes are versatile synthons in organic synthesis,as well as important structural moieties in bioactive molecules.Recently,transition metal-catalyzed hydroalkynylation of alkenes has been developed with reactive alk...
关键词:Palladium catalysis Alkynylpalladation Unactivated terminal alkenes Markovnikov hydroalkynylation 
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