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CATALYZED: 作品数：1132被引量：1374H指数：10; 导出分析报告; 相关领域：理学更多>>; 相关作者：滕怀龙祝诗发陈自立姚小泉石先莹更多>>; 相关机构：中国科学院南开大学郑州大学武汉大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家教育部博士点基金更多>>

Bifunctional organocatalyst-catalyzed dynamic kinetic resolution of hemiketals for synthesis of chiral ketals via hydrogen bonding control: 《Chinese Chemical Letters》2025年第1期248-252,共5页Meng Shan Yongmei Yu Mengli Sun Shuping Yang Mengqi Wang Bo Zhu Junbiao Chang; supported by the National Natural Science Foundation of China(Nos.82130103,82151525 and 81903465);the Central Plains Scholars and Scientists Studio Fund(2018002);the Natural Science Foundation of Henan Province(No.212300410051);the Science and Technology Major Project of Henan Province(No.221100310300)。; Herein,we report the dynamic kinetic resolution asymmetric acylation ofγ-hydroxy-γ-perfluoroalkyl butenolides/phthalides catalyzed by amino acid-derived bifunctional organocatalysts,and a series of ketals were obtai...; 关键词：Bifunctional organocatalyst Dynamic kinetic resolution Hemiketal Chiral ketals Hydrogen bonding

Highly enantio-stereoselective Ni-catalyzed reductive cyclization to cyclopentanes with chiral quaternary centres of trisubstituted allylic siloxanes: 《Green Synthesis and Catalysis》2024年第4期282-289,共8页Wanjun Chen Xinlong Yan Lin Fan Xu Guo Jian Yang Yiming Chen Shaofang Zhou Guodu Liu; financial support provided by the National Natural Science Foundation of China(No.22061032);Natural Science Foundation of Inner Mongolia(Nos.2020MS02022,and 2022QN02005);Science and Technology Program of Inner Mongolia(No.2020GG0134);Opening-fund from State Key Laboratory of Bio-organic and Natural Products Chemistry of SIOC(No.21300-5206002);“JUN-MA”Highlevel Talents Program of Inner Mongolia University(No.21300-5185121);“Grassland Talents”Program of Inner Mongolia(No.12000-12102414);High-level Recruit Program of Inner Mongolia(No.12000-13000603);Key Project at Central Government Level:the ability establishment of sustainable use for valuable Chinese medicine resources(No.2060302)is sincerely acknowledged。; The construction of chiral quaternary carbon stereocenters is a significant challenge in asymmetric synthesis.Catalytic synthesis of these structures with trisubstituted allylic alcohols is highly important. However, ...; 关键词：All carbon 1 6-alkynone Ni-catalyzed reductive cyclization Stereoselective asymmetric catalysis Cyclopentane with chiral allylic quaternary stereocenter P-Chiral monophosphine ligand

Access to N-a-quaternary chiral morpholines via Cu-catalyzed asymmetric propargylic amination/desymmetrization strategy: 《Science Bulletin》2024年第22期3516-3524,共9页Peng Chen Mao-Mao Zhang Li Rao Yuan-Heng Li Yue Jia Ying Tan Wen-Jing Xiao Liang-Qiu Lu; supported by the National Key R&D Program of China(2023YFE0110100);the National Natural Science Foundation of China(22271113,92256301,21822103,and 21820102003)。; Morpholines are widespread in many biologically and catalytically active agents,thus being an important aim of pharmaceutical and synthetic chemists.However,efficient strategies for the catalytic asymmetric synthesis ...; 关键词：Chiral morpholine Copper catalysis DESYMMETRIZATION Propargylic amination

A Machine Learning Model for Predicting Enantioselectivity in Hypervalent Iodine(III)Catalyzed Asymmetric Phenolic Dearomatizations: 《CCS Chemistry》2024年第10期2515-2528,共14页Ben Gao Liu Cai Yuchen Zhang Huaihai Huang Yao Li Xiao-Song Xue; supported by the Ministry of Science and Technology of China(grant no.2021YFF0701700);the National Natural Science Foundation of China(grant nos.22122104,22193012,and 21933004);the CAS Project for Young Scientists in Basic Research(grant nos.YSBR-052 and YSBR-095);the Strategic Priority Research Program of the Chinese Academy of Sciences(grant no.XDB0590000).; Catalytic asymmetric dearomatization(CADA)of phenols has emerged as a powerful strategy for constructing stereochemically complicated architectures from planar aromatic feedstocks.However,the development of novel cata...; 关键词：machine learning chiral hypervalent iodine CATALYSIS DEAROMATIZATION ENANTIOSELECTIVITY

Chiral boryl radical catalyzed asymmetric radical cycloisomerization: 《Science China Chemistry》2024年第7期2121-2123,共3页Jiamiao Jin Shi-Chao Ren Yonggui Robin Chi; Asymmetric catalytic organic synthesis is of profound importance in modern research and industries,providing optically enriched molecules with diverse structures and functions[1].Enzymes,transition metal complexes,and...; 关键词：RADICAL CATALYZED ASYMMETRIC

Quinoxaline-specific enantioselective sulfa-michael reaction catalyzed by chiral phosphoric acid: 《Chinese Chemical Letters》2023年第12期172-176,共5页Xiongfei Deng Shiqi Zhang Hesen Huang Xin Cui Zhuo Tang Guangxun Li; supported by the West Light Foundation of the Chinese Academy of Sciences(No.25E0C304);the Sichuan Science and Technology Program(No.2021ZYD0061).; Highly enantioselective sulfa-Michael additions(SMA)between 2-alkenyl quinoxalines and aromatic thiols are accomplished using a low loading of chiral phosphoric acid catalyst(1 mol%).It was confirmed by an investigati...; 关键词：Sulfa-Michaela ddition QUINOXALINE Chiral phosphoric acid Regioselectivity ENANTIOSELECTIVITY

Remote Stereocontrol of All-Carbon Quaternary Centers via Cobalt-Catalyzed Asymmetric Olefin Isomerization被引量：2: 《CCS Chemistry》2023年第6期1293-1300,共8页Xianle Rong Jie Yang Shihan Liu Yu Lan Qiang Liu; We gratefully acknowledge funding from the National Key R&D Program of China(grant no.2021YFF0701600);the National Natural Science Foundation of China(grant nos.22171159 and 22225103).; Asymmetric olefin isomerization has become a powerful tool for positional migration of C=C double bonds to afford valuable chiral olefins.However,the synthesis of optically active all-carbon quaternary stereocenters v...; 关键词：olefin isomerization remote stereocontrol all-carbon quaternary stereocenter cobalt catalysis chiral cyclohexene

The first N-ligand assisted Pd catalyzed asymmetric synthesis of 3-arylsuccinimides as novel antifungal leads: 《Organic Chemistry Frontiers》2022年第1期183-189,共7页Jixing Lai Juan Yang Chen Yang RenéCsuk Baoan Song Shengkun Li; supported by the National Natural Science Foundation of China(No.21772094,21977049);the Natural Science Foundation of Jiangsu Province(BK20191306).; The first palladium/chiral nitrogenous ligand-catalyzed enantioselective addition of aryl boronic acids to various maleimides was reported.This protocol features mild conditions combined with good functional group tol...; 关键词：CATALYZED CHIRAL PALLADIUM

Chiral Phosphoric Acid Catalyzed Asymmetric Synthesis of Axially Chiral Compounds被引量：10: 《Chinese Journal of Chemistry》2021年第7期1787-1796,共10页Bing-Chao Da Shao-Hua Xiang Shaoyu Li Bin Tan; The well-defined conformational properties of axially chiral compounds bring extraordinary values to an assortment of bioactive molecules,advanced materials,organocatalysts as well as chiral ligands in asymmetric tran...; 关键词：Axial chirality ORGANOCATALYSIS Chiral phosphoric acid BIARYLS Asymmetric synthesis

Transition-Metal-Catalyzed Synthesis of Chiral Allylboronates: 《Chinese Journal of Chemistry》2021年第6期1716-1725,共10页Wenbo Ming Xiaocui Liu Lujia Mao Xiao Gu Qing Ye; NSFC(Grant No.22071095);National Young Talents Program and SUSTech for financial support.; Since the pioneering work on Cr(Ⅲ)-catalyzed enantioselective[4+2]/allylboration reported by Hall and co-workers,a variety of catalytic methodologies for the asymmetric allylic borylation reactions have been develope...; 关键词：Allylboronates Homoallyl Alcohols Asymmetric Synthesis Homogeneous Catalysis Transition Metals

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