The Tertiary Education Scientific Research Project of Guangzhou Municipal Education Bureau(No.202235305)is gratefully acnowledged for financial support.
The atom-economical C-F insertion chemistry is emerged as a promising technology for the synthesis of various fluorinated scaffolds,which have wide applications both in the academic and the industrial com-munities.The...
the financial support from the National Natural Science Foundation of China(Nos.21971205 and 22271231);the Natural Science Basic Research Plan in Shaanxi Province of China(No.2023-JC-YB-126);Natural Science Basic Research Plan for Distinguished Young Scholars in Shaanxi Province of China(No.2022JC-08);Key Research and Invention Program in Shaanxi Province of China(No.2021SF-299)。
An inexpensive phosphine catalyst was used effectively for a transition-metal-free acyl-transfer of N-containing heteroaryl ketones for the rapid synthesis of N-fused heterocycles.The key pre-aromatic spirocyclic inte...
National Natural Science Foundation of China (Nos.21472129 and 21871190) for financial support of this work by grants。
A new synthesis of the bridged [6-6-6] ABE tricyclic ring analogues of methyllycaconitine with the C-1 oxygenated substituents has been developed using an efficient aza-annulation of β-enamino ketone followed by a fa...
supported by the National Natural Science Foundation of China (No. 21472068);Financial support from MOE & SAFEA for the 111 Project (No. B13025)is also gratefully acknowledged
This paper reports a computational study elucidating reaction mechanism for amide bond formation from esters and amines catalyzed by acetic acid. Two optional mechanisms(namely, classic stepwise and concerted acyl su...
the National Natural Science Foundation of China (Nos. 21372203 and 21272076)for the financial support
Direct aldol condensation of various aromatic, heteroaromatic, α,β-unsaturated aldehydes and aliphatic aldehydes with acyldiazomethane was realized using Mgl2 etherate (Mgl2.(Et2O)n) as a promoter in the presenc...
Synthesis of a series of new 3,6-diaryl-[1,2,4]triazolo[3,4-b] [1,3,4]thiadiazoles(5a-o) was achieved by phophine free, C-H arylative cross-coupling of 6-aryl-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazoles(4a-o)with su...
supported by the National Natural Science Foundation of China(Nos.21462016,21262010);Natural Science Foundation of Gansu Province and the Advanced Research Fund of Jinchuan Group Co.,Ltd
A catalytic synthesis of N-benzothiazol-2-yl-amides from 1-acyl-B-(phenyl)thioureas was achieved in the presence of a palladium catalyst through the C(sp2)-H functionalization/C-S bond formation, This synthetic me...
funded in part by the NNSFC(No.20872071);the NSF of Tianjin(No.10JCZDJC17500);the National Key Project for Basic Research(No.2010CB126105);National Key Technology Research and Development Program(Nos.2011BAE06B02 and 2011BAE06B05);the Foundation of Achievements Transformation and Application of Tianjin Agricultural Science and Technology(No.201002250);Tianjin Key Technology Research and Development Program(No.11ZCGYNC00100)
A series of novel N-tert-butyl-N'-acyl-5-methyl-1,2,3-thiadiazole-4-carbohydrazides were designed and synthesized. Their structures were characterized by melting points, ^1H NMR, IR, ESI-MS, and elemental analysis. T...
support provided by the National Science Funds for Young Scientists(No. 51008152);the Nature Science Fund of Jiangsu Province(No.BK2010381);the Fundamental Research Funds for the Central Universities
The graft copolymerization of acrylic acid(AA) onto polyethylene glycol terephthalate(PET) fiber initiated by benzoy peroxide (BPO) was carried out in heterogeneous media.Moreover,modification of the grafted PET...
The present paper employed density function theory to investigate two reaction pathways for isomerization of enol ester proposed by Yang(path a) and the present authors(path a), respectively. The base catalytic effect...