support from the National Natural Science Foundation of China(nos.21671142,21875150,and 21720102006);the 111 Project(no.D20015);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD);Shanxi Natural Science Foundation(no.201901D111018);the OIT program of Shanxi Higher Education Institutions.
Exploring the unusual orbital hybridization types of atoms and their new connection modes contributes to the development of chemical bond theory and can inspire compounds with unique molecular configurations.Dicoordin...