supported by the National Natural Science Foundation of China(21103121,21276187);Tianjin Municipal Natural Science Foundation(13JCQNJC05800);the Specialized Research Fund for the Doctoral Program of Higher Education(20121317110009)~~
Two mono iron complexes Fe(CO)2PR3(NN) (R = Cy (3), Ph (4), NN = o-phenylenediamine dianion ligand, N2H2Ph2-) derived from the ligand substitution of Fe(CO)3hPR3 by the NN ligand were isolated and structur...