supported by the National Natural Science Foundation of China (20604023);Zhejiang Provincial Natural Science Foundation (Y406301);Ningbo Municipal Natural Science Foundation (2008A610056)
Reaction of(C5Me4SiMe3)Y(CH2SiMe)2(THF) with two equivalents of iPrN=C=NiPr in hexane at room temperature afforded a mixed-ligand yttrium complex(C5Me4SiMe3)(iPrN)2CCH2SiMe32Y.X-ray diffraction revealed that...
Project supported by the National Natural Science Foundation of China (20604023);Zhejiang Provincial Natural Science Foundation (Y406301)
The reaction of 2, 6-^iPr2CbH3NHSiMe3 with Tb(CH2SiMe3)3(THF)2 in benzene at room temperature afforded a binuclear terbium complex Tb2 {μ-CH2 SiMe2 NC6 H3 ^iPr2 -2, 6}3(THF)3. X-ray diffraction revealed that Tb...
Project supported by the National Natural Science Foundation of China (Nos. 20632040, 20604023).
Reactions of 1,3-diisopropylcarbodiimide with alkali metal amides, MN(SiMe3)2 (M=Li or Na) in hexane or THF produced the alkali metal guanidinates { (i-PrN)2C [N(SiMe3)2]Li }2 (1) and { (i-PrN)2C[N(SiMe3...