A new solid state molybdenum-selective electrode has been developed. The electrode is composed of 20% MoS2, 60% Ag2S, and 20% Cu2S. An analytically useful potential change occurred, from 1 × 10-5 to 1 × 10-1 M molyb...
Projects(61533021,61773403)supported by the National Natural Science Foundation of China
We report herein a highly selective method for directly determining the trace Co^2+in highly concentrated zinc electrolyte.This novel method is based on a second derivative wave of catalytic adsorptive polarography ge...
Proejcr(20235020) supported by the National Natural Science Foundation of China
The sensitive second derivative waves of Cu(Ⅱ),Pb(Ⅱ),Cd(Ⅱ),Ni(Ⅱ),Zn(Ⅱ),Fe(Ⅱ)and Mn(Ⅱ),forming in the substrate solution(pH=9.26)consisting of ammonia,ammonium chlorid,gelatin and ascorbic acid were researched.T...
The cadmium(Ⅱ)-glycine system was studied by the two experimental techniques, ion sensitive electrode (ISE) and differential pulse polarography (DPP), and the experimental data obtained were used by a unified m...
Supported by the National Natural Science Foundation of P.R.China(No.2 0 4 75 0 4 3) and the Natural Science Foun-dation of Shaanxi Province(No.2 0 0 2 B0 1)
The associations of each of midecamycin and chloroquine phosphate to hydrogen peroxide were studied by using linear-potential scan polarography. In a 0.15 mol/L KH 2PO 4-NaOH(pH 7.4) buffer, the association ratio of...
supported by the National Natural Science Foundation of China(Grant No.20275030);Key Item of Science and Technology by the Ministry of Education(Grant No.02187);the Special Foundation of the Educational Committee of Shaanxi Province(Grant No.01JK076).
The voltammetric behaviors of methylhesperidine (MH) were studied by means of linear sweep voltammetry, cyclic voltammetry and normal pulse voltammetry. In the Brit ton-Robinson buffer solutions with pH values from 2....
It was found that micro amounts of oxalate showed a very strong catalytic effect on the slow reaction between K 2Cr 2O 7 and Orange Ⅳ in a diluted sulfuric acid medium in a water bath at 70 ℃ . Orange Ⅳ exhib...
Project supported by the National Natural Science Foundation of China
A new approach of polarographlc immunoassay based on the catalytic amplification of the labeled metal ions and the polarographlc detection of the catalytic product was developed.In this approach,the copper ions used a...
A now polarographic immunoassay was developed In this assay,human serum albumin (HSA) as the model antigen was covalently labeled with organic compound erythrosin B(EB) containing four non-radioactive iodides through ...
The second derivative differential pulse polarography was developed for the quantitative determination of active principles in medicinal herbs (baicalin in Scutellaria baicalensis Georgi, indigo in Baphicacanthus cusi...