supported by the financial aid from National Science and Technology Major Project of China(No.2020YFE0204500);National Natural Science Foundation of China(Nos.22020102003,22025506 and 11975301);Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2020286)。
The three-way catalyst(TWC),as a promising approach to control automobile exhaust emission,has been widely studied and applied.However,it still suffers from the high light-off temperature and poor stability.Herein,we ...
financial support from the National Key R&D Program of China(No.2022YFF1202600);the National Natural Science Foundation of China(Nos.22001172,22071155,and22371188);the Science and Technology Commission of Shanghai Municipality(Nos.20XD1403600 and 20400750300);the Shanghai Municipal Education Commission(No.2019-01-07-00-10-E00072);the Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine(No.ZYYCXTD-202004);the Shanghai Municipal Health Commission/Shanghai Municipal Administration of Traditional Chinese Medicine[No.ZY(2021-2023)-0501];Organizational Key R&D Program of SHUTCM(No.2023YZZ01)。
A rhodium(Ⅲ)-catalyzed hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes(1,6-dienes)with triethylsilane is described,providing a series of cishydrobenzofurans,cis-hydroindol...
We thank the National Key R&D Program of China(2021YFA1500100);National Natural Science Foundation of China(21821002,92256302,22071260);Science and Technology Commission of Shanghai Municipality(21520780100)for generous financial support.S.-L.Y.thanks the supports from the New Cornerstone ScienceFoundation.
Rhodium(III)-catalyzed enantioselective C-H indolylization of isoquinolines was developed.The C-H coupling reactions between 1-aryl isoquinoline derivatives and 3-indolylphenyliodonium salts proceeded smoothly in the ...
financially supported by the National Natural Science Foundation of China(NSFC,Nos.21602130 and 21961023);the startup funding from Shanghai Jiao Tong University.
A Rh(Ⅰ)-catalyzed highly regio-and enantioselective allylic alkylation of Meldrum acid with racemic allylic substrates bearing alkyl groups has been developed.The applying of chiral bisoxazopinephosphine ligand is es...
supported by the Deutsche Forschungsgemeinschaft(ME 1805/17-1)
Racemicα-chloro imidazol-2-yl-ketones undergo an enantioconvergent photoactivated C–C bond formation with N-aryl glycines catalyzed by a single bis-cyclometalated chiral-at-rhodium catalyst in yields of up to 80%and...
Rhodium (Rh) is a critical component of many catalysts for a variety of chemical transformation processes. Controlling the shape of Rh nanocrystals offers an effective route to the optimization of their catalytic pe...
This work was supported by the National Natural Science Foundation of China (Grant Nos. 20132010 and 20272026); the Major State Basic Research Development Program (Grant No. G2000077506); the Ministry of Education of China and the Committee of Science and Technology of Tianjin City for financial support.
The activity and enantiocontrol ability of the chiral catalysts prepared from spiro di-phosphine ligands, SDP, and rhodium precursor were investigated in the asymmetric catalytic Pau-son-Khand reaction. The results sh...
The financial support of the National Natural Science Foundation of China (grant no. 29906001) and the Research Institute of Petroleum Processing; China Petroleum & Chemical Corporation is gratefully acknowledged.
Effects on the recycling efficiency of thermoregulated phase-separable Rh/PETPP (P-[p-C6H4O(CH2CH2O)nH]3, N=3n) complex catalyst involved in hydroformylation of 1-decene are for the first time presented. It was found...
Three diphosphinites were synthesized for preparing rhodium-diphosphinite complexes. The complexes were used for asymmetric catalytic hydrogenation of amino acid precursor alpha-acetamidocinnamic acid and its methyl e...
The project is supported by the National Natural Science Foundation of China.
A series of polymer-supported tetranuclear rhodium carbonyl cluster catalysts were prepared b the reaction of Rh4(CO)12with several kinds of polymer supports such as crosslinked poly (N-vinylpyrrolidone) (PNVP)...