RHODIUM

作品数:162被引量:179H指数:7
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相关领域:理学更多>>
相关作者:王佰全李存耀丁云杰姜淼刘佳更多>>
相关机构:南开大学中国科学院大学中国科学院华东师范大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>
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Investigation on Cu promotion effect on Ce-based solid solution-anchored Rh single atoms for three-way catalysis
《Chinese Chemical Letters》2025年第2期546-550,共5页Jianing He Xiao Wang Zijian Wang Ruize Jiang Ke Wang Rui Zhang Huilin Wang Baokang Geng Hongyi Gao Shuyan Song Hongjie Zhang 
supported by the financial aid from National Science and Technology Major Project of China(No.2020YFE0204500);National Natural Science Foundation of China(Nos.22020102003,22025506 and 11975301);Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2020286)。
The three-way catalyst(TWC),as a promising approach to control automobile exhaust emission,has been widely studied and applied.However,it still suffers from the high light-off temperature and poor stability.Herein,we ...
关键词:Three-way catalysts(TWC) Solid solution CO-PRECIPITATION Rhodium(Rh)catalyst Oxygen vacancies 
Rhodium(Ⅲ)-catalyzed diastereo-and enantioselective hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes
《Chinese Chemical Letters》2024年第9期160-164,共5页Yi-Fan Wang Hao-Yun Yu Hao Xu Ya-Jie Wang Xiaodi Yang Yu-Hui Wang Ping Tian Guo-Qiang Lin 
financial support from the National Key R&D Program of China(No.2022YFF1202600);the National Natural Science Foundation of China(Nos.22001172,22071155,and22371188);the Science and Technology Commission of Shanghai Municipality(Nos.20XD1403600 and 20400750300);the Shanghai Municipal Education Commission(No.2019-01-07-00-10-E00072);the Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine(No.ZYYCXTD-202004);the Shanghai Municipal Health Commission/Shanghai Municipal Administration of Traditional Chinese Medicine[No.ZY(2021-2023)-0501];Organizational Key R&D Program of SHUTCM(No.2023YZZ01)。
A rhodium(Ⅲ)-catalyzed hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes(1,6-dienes)with triethylsilane is described,providing a series of cishydrobenzofurans,cis-hydroindol...
关键词:Rhodium(Ⅲ)catalysis Hydrosilylation/cyclization 1 6-Dienes Silyl enol ether Diastereo-and enantioselectivity 
Rhodium(III)-Catalyzed Atroposelective C-H Indolylization of 1-Aryl Isoquinolines with 3-Indolylphenyliodonium Salts
《Chinese Journal of Chemistry》2023年第20期2684-2690,共7页Dong-Song Zheng Jun Zheng Qiang Wang Qing Gu Shu-Li You 
We thank the National Key R&D Program of China(2021YFA1500100);National Natural Science Foundation of China(21821002,92256302,22071260);Science and Technology Commission of Shanghai Municipality(21520780100)for generous financial support.S.-L.Y.thanks the supports from the New Cornerstone ScienceFoundation.
Rhodium(III)-catalyzed enantioselective C-H indolylization of isoquinolines was developed.The C-H coupling reactions between 1-aryl isoquinoline derivatives and 3-indolylphenyliodonium salts proceeded smoothly in the ...
关键词:Asymmetric catalysis Axially chiral biaryl compounds C-H indolization CROSS-COUPLING ENANTIOSELECTIVITY Rh catalysis 
Rh(Ⅰ)-catalyzed regio-and enantioselective allylic alkylation of Meldrum's acid
《Chinese Chemical Letters》2021年第1期385-388,共4页Min Liu Haiying Zhao Changkun Li 
financially supported by the National Natural Science Foundation of China(NSFC,Nos.21602130 and 21961023);the startup funding from Shanghai Jiao Tong University.
A Rh(Ⅰ)-catalyzed highly regio-and enantioselective allylic alkylation of Meldrum acid with racemic allylic substrates bearing alkyl groups has been developed.The applying of chiral bisoxazopinephosphine ligand is es...
关键词:RHODIUM Bisoxazolinephosphine Allylic substitution Meldrum’s acid Asymmetric catalysis 
Enantioconvergent photoredox radical-radical coupling catalyzed by a chiral-at-rhodium complex
《Science China Chemistry》2019年第11期1512-1518,共7页Zijun Zhou Xin Nie Klaus Harms Radostan Riedel Lilu Zhang Eric Meggers 
supported by the Deutsche Forschungsgemeinschaft(ME 1805/17-1)
Racemicα-chloro imidazol-2-yl-ketones undergo an enantioconvergent photoactivated C–C bond formation with N-aryl glycines catalyzed by a single bis-cyclometalated chiral-at-rhodium catalyst in yields of up to 80%and...
关键词:PHOTOREDOX CATALYSIS asymmetric CATALYSIS VISIBLE light enantioconvergent RADICAL recombination chiral-at-metal RHODIUM 
Shape-controlled syntheses of rhodium nanocrystals for the enhancement of their catalytic properties被引量:10
《Nano Research》2015年第1期82-96,共15页Shuifen Xie Xiang Yang Liu Younan Xia 
Rhodium (Rh) is a critical component of many catalysts for a variety of chemical transformation processes. Controlling the shape of Rh nanocrystals offers an effective route to the optimization of their catalytic pe...
关键词:Rhodium nanocrystals shape control material synthesis surface structure CATALYSIS 
Rhodium catalyzed asymmetric Pauson-Khand reaction using SDP ligands
《Science China Chemistry》2006年第1期81-87,共7页FAN Baomin1, LI Shen2, XIE Jianhua2, WANG, Lixin2, TU Yongqiang1 & ZHOU Qilin2 1. State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,China 2. State Key Laboratory of Elemento-organic Chemistry,Nankai University,Tianjin 300071, China 
This work was supported by the National Natural Science Foundation of China (Grant Nos. 20132010 and 20272026); the Major State Basic Research Development Program (Grant No. G2000077506); the Ministry of Education of China and the Committee of Science and Technology of Tianjin City for financial support.
The activity and enantiocontrol ability of the chiral catalysts prepared from spiro di-phosphine ligands, SDP, and rhodium precursor were investigated in the asymmetric catalytic Pau-son-Khand reaction. The results sh...
关键词:Pauson-Khand reaction  ASYMMETRIC catalysis  DIPHOSPHINE ligand  rhodium. 
Studies on the Recycling Efficiency of Thermoregulated Phase-separable Rh/PETPP Complex Catalyst被引量:1
《Chinese Chemical Letters》2003年第1期91-93,共3页Yan Hua WANG Fang CHENG Xiao Wei WU Zi Lin JIN 
The financial support of the National Natural Science Foundation of China (grant no. 29906001) and the Research Institute of Petroleum Processing; China Petroleum & Chemical Corporation is gratefully acknowledged.
Effects on the recycling efficiency of thermoregulated phase-separable Rh/PETPP (P-[p-C6H4O(CH2CH2O)nH]3, N=3n) complex catalyst involved in hydroformylation of 1-decene are for the first time presented. It was found...
关键词:Thermoregulated phase-separable catalysis (TPSC) HYDROFORMYLATION nonionic phosphine ligand rhodium. 
Asymmetric Catalytic Hydrogenation Using Rhodium Diphosphinites Derived From D-glucose and D-mannitol被引量:1
《Chinese Chemical Letters》2000年第7期587-588,共2页Peng JIANG Shi Jie LU(State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000) 
Three diphosphinites were synthesized for preparing rhodium-diphosphinite complexes. The complexes were used for asymmetric catalytic hydrogenation of amino acid precursor alpha-acetamidocinnamic acid and its methyl e...
关键词:asymmetric catalysis hydrogenation rhodium diphosphinites alpha-acetamidocinnic acid 
HYDROFORMYLATION CATALYSIS USING POLYMER-SUPPORTED MULTINUCLEAR RHODIUM CARBONYL CLUSTER CATALYSTS
《Chinese Journal of Polymer Science》1990年第2期158-164,共7页何炳林 孙君坦 李弘 桑俊杰 
The project is supported by the National Natural Science Foundation of China.
A series of polymer-supported tetranuclear rhodium carbonyl cluster catalysts were prepared b the reaction of Rh4(CO)12with several kinds of polymer supports such as crosslinked poly (N-vinylpyrrolidone) (PNVP)...
关键词:Rhodium cluster Polymer catalysts HYDROFORMYLATION 
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