the Natural Science Foundation of Zhejiang Province(LY22B020001);the Zhejiang Public Welfare Public Research Program(LGC22B010001);the National Natural Science Foundation of China(32201238)is greatly acknowledged.
Functionalized free radical addition/cyclization reactions represent an efficient way for introducing new functionality or coupling fragments to molecules.Ynones are good regional selectivity radical acceptors in orga...
the National Natural Science Foundation of China(22101075,U2004189);Central Plains Science and Technology Innovation Leader Project(224200510009);Postdoctoral Research Grant in Henan Province(202103085);Henan Key Laboratory of Organic Functional Molecules and Drug Innovation,and 111 Project(D17007)for financial support.
Herein,we report a condition-controlled divergent synthesis of spiro indene-2,1'-isoindolinones and spiro isochroman-3,1'-isoindolinones through cobalt-catalyzed formal[4+1]and[4+1+1]spirocyclization of aromatic amide...
We thank the support from National Key R&D Program of China(2022YFA1504302,2021YFF0701603);National Natural Science Foundation of China(U22A20388,92256302,21925109 for B.-F.S.,22271250 for T.Z.);Fundamental Research Funds for the Central Universities(226-2023-00115,226-2022-00224,226-2022-00175);Zhejiang Provincial NSFC(LD22B030003)。
Axially chiral N-arylindoles bearing a stereogenic C—N axis are unique important scaffolds in natural products,advance materials,pharmaceuticals and privileged chiral ligands or catalysts.Herein,we report the direct ...
the National Natural Science Foundation of China(No.21771098);the Shenzhen R&D Fund(No.KQ.TD20180411143418361);the Shenzhen Clean Energy Research Institute(No.CERI-KY-2019-003);the Guangdong Provincial Key Laboratory of Energy Materials for Electric Power(No.2018B030322001).
We report herein a Re-based tricarbonyl catalyst[fac-Re(L1)(CO)_(3)Cl](Re1)bearing a spiro center and a phenol group as a local proton source in the second coordination sphere.Due to the large steric spiro group,dimer...
the National Natural Science Foundation of China(21774061,2207112 and 61935017);Natural Science Foundation major research program integration project(Grant Number 91833306);Six Peak Talents Foundation of Jiangsu Province(XCLCXTD-009);Open Project from State Key Labor-atory of Supramolecular Structure and Materials at Jilin University(No.sklssm202014).
As a novel class of spirofluorenes,spirobifluorene(SBF)and spiro[fluo-rene-9,9'-xanthene]derivatives(SFXs)have orthogonal geometric config-uration,spiro-conjugation effect,and rigid steric hindrance,which can be widel...
We thank the NSFC(Nos.91956103,21772224);the CAS(Nos.QYZDY-SSW-SLH016,XDB20000000);the STCSM(No.17JC1401200)for the financial support.
of main observation and conclusion A copper catalyzed enantioselective[3+2]annulation of donor-acceptor cyclopropanes with cyclic ketones has been developed,providing a concise protocol to enantioenriched l-oxaspiro[4...
We gratefully acknowledge financial support from the National Natural Science Foundation of China (No. 21372207).
A series of spiro-oxadiazoles were synthesized from 1,4:3,6-dianhydro-D-fructose and hydrazides via a stereoselective two-step reaction sequence. The structures of newly synthesized compounds were established by spec...
The double Michael reactions between benzofuran-3-one or 1-indone and symmetric dienones in the presence of catalytic ionic liquids were successfully developed and spiro[benzofuran-2, 1′-cyclohexane]-3-one or spiro[c...
The work was partially supported by the National Natural Science Foundation of China (Nos. 21172001, 21372008), the Natural Science Foundation of Education Administration of Anhui Province (No. KJ2016A267), the Special and Excellent Research Fund of Anhui Normal University and the Doctoral Scientific Research Foundation of Anhui Normal University (No. 2016XJJ110).
A convenient and metal-flee DMAP-catalyzed domino reaction of isatins, arylamines and hydroximoyl chlorides has been developed to achieve 1,3-dipolar cycloaddition of imines into aryl nitrile oxides at ambient tempera...
The three-component reaction of N-phenacylbenzothiazolium bromides, aromatic aldehydes and indane-l,3- dione in ethanol at room temperature in the presence of triethylamine as base afforded functionalized spiro[benzo-...