support from the National Natural Science Foundation of China(22171177);the Guangdong-Hong Kong Joint Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province(2023B1212120011);the Guangdong Basic and Applied Basic Research Foundation(2023A1515110791);the Chemistry and Chemical Engineering Guangdong Laboratory(2312002);the Guangdong Major Project of Basic and Applied Basic Research(2019B030302009);the Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme 2019(GDUPS2019).
The EDA complex-mediated reactions involving oxime esters have been few studied.Herein,an EDA complex formed by thiophenolate anion and oxime ester is reported for photoinduced divergent synthesis of thioethers,depend...
This project was supported by the National Key Research and Development Program of China(Nos.2021YFC2101500,2018YFA0902002);the National Natural Science Foundation of China(Nos.21877073,21807064,21778035,and 21961142016);Department of Science and Technology of Shandong Province(No.2020CXGC010601);the Tianjin Natural Science Foundation(No.19JCYBJC24400);the Young Scholars Program of Shandong University,Mizutani Foundation for Glycoscience,and Central Government Guide Local Science and Technology Development Funds(No.YDZX20203700002579).
A convenient and highly efficient strategy was developed for the simplification of enzymatic synthesis and purification of oligosaccharides.Glycosyl acceptors terminated with a thiol tag were extended by enzymatic mod...
We are grateful for the financial support from the NSFC(21931006 and 21961132004);the Fundamental Research Funds for the Central Universities,and China Postdoctoral Science Foundation(2019M663488);Postdoctoral Foundation of Sichuan University(2020SCU12019).
Asymmetric aminocatalysis has become one of the most powerful strategies for the transformations of carbonyl substances over the past two decades.Here,we describe the research from our laboratory that significantly ex...
We thank Shanghai Jiao Tong University and the National"1000-Youth Talents Plan"for financial support.
A visible-light-induced metal-free desulfurization method for thiols and disulfides has been explored.This radical desulfurization features mild conditions,robustness,and excellent functionality compatibility.It was s...
This work was supported by the Development Plan of YouthInnovation Team in Colleges and universities of Shandong Province (2020KJCO03);the Natural Science Foundation of ShandongProvince of China (ZR2016JL010);Key Technology Research andDevelopment Program of Shandong Province (2018GSF118172);Epidemic Prevention and Control Emergency Special Project of Linyi University (2020YJKYOO3).
Reduced thiol compounds(RTCs),such as glutathione(GSH),cysteine(Cys),and homocysteine(Hcy),are important components of many amino acids andproteins.They are also basic buiding blocks that make up organisms and play an...
The authors gratefully acknowledge the financial support from the National Natural Science Foundation of China(Nos.21625206,21632009,21421002,21572258)。
The invention of a family of optically pure electrophilic difluoromethylthiolating reagents 9a-c based on the camphorsultam skeleton was described.These reagents reacted with a variety of soft carbon nucleophiles such...
This work was financially supported by the National Natural Science Foundation of China (Nos. 50943028, 51573100).
The assembly of preformed gold nanoparticles (AuNPs) onto the thermoresponsive poly(N-isopropylacrylamide) (PNIPAM)-based microgels was achieved on the basis of the driving force of Au-thiol chemistry. The loadi...
We investigated a novel water-soluble conjugated polymer (WSCP) for thiol detection based on "turn-off" ef- fect. This WSCP was modified with poly(ethylene glycol) (PEG) by disulfide linkages to achieve good s...
A porous crosslinked organic polymer based on N-acryloxysuccinimide (NAS) and ethylene dimethacrylate (EDMA) was prepared inside 75 μm i.d. fused silica capillary as functionalizable monolithic stationary phase f...
The synthesis of a benzenethiol-derivatized porphyrin for flat-lying self-assembly on gold substrates is described. Acetyl protected thiol is not stable enough in Pd-catalyzed reactions. While acrylate derivatives pro...