ALLENOATES

作品数:12被引量:2H指数:1
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相关领域:理学更多>>
相关机构:重庆文理学院更多>>
相关期刊:《Chinese Journal of Chemistry》《Chemical Research in Chinese Universities》《Science Bulletin》《Green Synthesis and Catalysis》更多>>
相关基金:国家自然科学基金国家教育部博士点基金天津市自然科学基金更多>>
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Lewis Acid-catalyzed Regioselective Addition of Allenoates to Indoles for Synthesis of Bisindolylesters
《Chemical Research in Chinese Universities》2025年第1期48-58,共11页XIE Fuyu HE Jianghua ZHANG Yuetao 
supported by the National Natural Science foundation of China(Nos.22225104,92356302,22071077,21975102).
Indole derivatives,especially bisindolylesters,have attracted intense attention due to their important applications in medicinal chemistry and organic synthesis.Here we develop a Lewis acid-catalyzed efficient and reg...
关键词:B(C_(6)F_(5))_(3) Al(C_(6)F_(5))_(3) INDOLE ALLENOATE Indolylester 
A Direct Route to Tetrahydropyridazine Derivatives via DMAP-Catalyzed [4+2] Annulation of Allenoates with Arylazosulfones
《Chinese Journal of Chemistry》2023年第22期3031-3036,I0002,共7页Xin Ji Ziyang Li Jinfeng Zhang Yicheng Zhang Ling-Guo Meng 
the Independent Research Foundation of Key Laboratory of Green and Precise Synthetic Chemistry and Applications in Huaibei Normal University,Ministry of Education;the University Top Talents Academic Funding Project of Anhui Province(gxbjzD2021097);the Natural Science Foundation of Educational Committee from Anhui Province and Huaibei Normal University(KJ2020A0045,KJ2020A1199,KJ2020B01,2023ZK078,2023ZK079);the University Synergy Innovation Program of Anhui Province(GXXT-2020-078)for financial support of this work.
Herein,a DMAP-catalyzed[4+2]annulation ofα-substituted allenoates with arylazosulfones is reported,which affords facile access to tetrahydropyridazine derivative in synthetically useful yields.This reaction features ...
关键词:DMAP [4+2]Cycloaddition Tetrahydropyridazihe derivatives Pyridazin-3-one derivatives ALLENES ZWITTERIONS N-HETEROCYCLES 
Copper-catalyzed 1,4-protosilylation and 1,4-protoborylation of enynic orthoesters for synthesis of functionalized 2,3-allenoates
《Chinese Chemical Letters》2023年第9期151-155,共5页Qi Li Zi-Lu Wang Yun-He Xu 
the funding support of the National Natural Science Foundation of China(No.21871240);the Strategic Priority Research Program of the CAS(No.XDPB14);the Fundamental Research Funds for the Central Universities(No.WK2060190082)。
Herein,copper-catalyzed 1,4-protosilylation and 1,4-protoborylation of enynic orthoesters have been developed.The enynic orthoesters as precursors of unstable enynic esters were applied to produce the functionalized 2...
关键词:COPPER-CATALYZED 1 4-Protosilylation 1 4-Protoborylation 2 3-Allenoate Enynic orthoesters 
Enantioselective[3 t 2]cycloadditions of terminal allenoates withβ-sulfonyl-α,β-unsaturated ketones
《Green Synthesis and Catalysis》2023年第1期54-57,共4页Xiuzheng Li Jun Liao Xiaobin Zhuo Huamin Wang Xiaoyun Chai Yan Zou Qingjie Zhao 
The authors are grateful to NSFC(Nos.21971066 and 21772042)for financial support.Special thanks to prof;Junliang Zhang(Fudan University)for his kind suggestion on this[3 t 2]cycloaddition reaction.
A highly efficient and mild method for[3 t 2]cycloaddition ofβ-sulfonyl-α,β-unsaturated ketones with terminal allenoates was well-explored and developed.The reactions were successfully performed by applying multifu...
关键词:[3t2]Cycloadditions Terminal allenoates α β-Unsaturated ketones ENANTIOSELECTIVE Chiral phosphine 
Recent advances in tertiary amine Lewis base-promoted cycloadditions of allenoates被引量:1
《Chinese Chemical Letters》2022年第5期2372-2382,共11页Manman Song Jing Zhao Er-Qing Li 
the National Natural Science Foundation of China(No.21702189);Key Scientific and Technological Project of Henan Province(No.202102310004);Zhengzhou University(No.JC21253007)of China for financial support.
Lewis base-catalyzed annulations of allenoates have been one of the most powerful synthetic strategies for the synthesis of various valuable cycles,especially in the preparation of biologically active natural products...
关键词:Lewis base Tertiary amine Annualtion ALLENOATES OLEFIN 
Enantioselective synthesis of mixed 3,3’-bisindoles via a phosphine-catalyzed umpolung γ-addition of 3’-indolyl-3-oxindoles to allenoates被引量:1
《Science Bulletin》2020年第7期557-563,M0004,共8页Yildiz Tasdan Guang-Jian Mei Yixin Lu 
Yixin Lu thanks the Singapore National Research Foundation,Prime Minister’s Office for the NRF Investigatorship Award(R-143-000-A15-281);Financial supports from the National University of Singapore(R-143-000-695-114 and C-141-000-092-001);the National Natural Science Foundation of China(21672158)are also gratefully acknowledged.
An enantioselective umpolung γ-addition reaction of 3’-indolyl-3-oxindoles to allenoates catalyzed by amino acid-derived bifunctional phosphine catalysts has been developed. A wide range of chiral mixed 3,3’-bisind...
关键词:Umpolung c-addition Amino acid-derived bifunctional phosphine ALLENOATES Mixed 3 30-Bisindole Formal total syntheses 
Double[3+2] cycloaddition of nitrile oxides with allenoates:Synthesis of spirobidihydroisoxazoles
《Chinese Chemical Letters》2019年第2期363-366,共4页Wei Sun Feng Jiang Honglei Liu Xing Gao Hao Jia Cheng Zhang Hongchao Guo 
supported by the National Natural Science Foundation of China(Nos. 21372256, 21572264)
The double [3 + 2] cycloaddition of allenoates with nitrile oxides is presented. The reaction worked well under mild reaction conditions to give the spirobidihydroisoxazole in moderate to excellent yields with excelle...
关键词:CYCLOADDITION ALLENOATE NITRILE OXIDE SPIROCYCLIC heterocyle 
Facile Synthesis of Spirooxindole-Cyclohexenes via Phosphine-Catalyzed [4-1-2] Annulation of α-Substituted Allenoates
《Chinese Journal of Chemistry》2017年第9期1469-1473,共5页Rongshun Chen Xia Fan Zhaozhong Xu Zhengjie He 
Financial support from the Fundamental Research Funds for the Central Universities (No. KYZ201749) and the National Natural Science Foundation of China (Nos. 21272119, J1103306) are gratefully acknowledged.
A phosphine-catalyzed [4+2] annulation of a-substituted allenoate with exocyclic alkene moiety of oxindoles or indan-1,3-diones has been developed. Thus, under the catalysis of PPh3 (20 mol%), a series of spirooxin...
关键词:[4+2] annulation reaction phosphine catalysis spirocyclohexenes ALLENOATES synthesis 
Phosphine-catalyzed [4+2] Annulations of α-Aminonitriles with Allenoates: Synthesis of Functionalized Tetrahydropyridines
《Chemical Research in Chinese Universities》2016年第3期385-389,共5页JANG Hochol LIU Wei ZHANG SEAN Xiao'an LIAO Weiwei 
Supported by the National Natural Science Foundation of China(No. 21372096).
Phosphine-catalyzed [4+2] annulations of 2-(acetoxymethyl)buta-2,3-dienoates with α-aminonitriles have been developed, in which a-aminonitriles serve as C, N-bisnucleophilic reaction partners and 2-(acetoxymethyl...
关键词:ANNULATION Catalysis TETRAHYDROPYRIDINE 
N-Heterocyclic Carbene-Catalyzed [2+2+2] Annulation of Allenoates with Trifluoromethylketones
《Chinese Journal of Chemistry》2012年第1期190-194,共5页孙利辉 王统 叶松 
In contrast with the reported phosphine- and DABCO-catalyzed [3 + 2] and [2 +2] annulation of allenoates with trifluoromethylketone, the [2+2+2] annulation of allenoates and two molecules of trifluoromethylketone ...
关键词:NHC-catalyzed [2  2  2] annulations ALLENOATES trifluoromethylketones 
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