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PALLADIUM-CATALYZED: 作品数：173被引量：138H指数：6; 导出分析报告; 相关领域：理学更多>>; 相关作者：吴养洁崔秀灵张浩刘秀艳龙蓉蓉更多>>; 相关机构：郑州大学南开大学辽宁石油化工大学中国人民大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划广东省自然科学基金国家教育部博士点基金更多>>

Palladium-catalyzed vinylation of indoles with vinyl ethers via deoxygenative coupling: 《Science China Chemistry》2024年第11期3785-3790,共6页Bowen Wang Jianxiao Li Wanqing Wu Liangbin Huang Huanfeng Jiang; supported by the National Key Research and Development Program of China (2022YFB4101800);the National Natural Science Foundation of China (22231002);the Guangdong Basic and Applied Basic Research Foundation (2024B1515040027)。; Indole is a promising heteroarene in many natural products and pharmaceuticals;therefore, various synthetic methods for indole functionalizations have arisen in recent years. Herein, we report a Pd-catalyzed deoxygena...; 关键词：INDOLE VINYLATION regioselectivity N-vinyl indole palladium catalyst

Palladium-catalyzed S_(N)2 glycosylation of phenols: 《Science China Chemistry》2024年第4期1037-1038,共2页Yu Zhu P.Andrew Evans; Glycosides are essential structural motifs present in an array of important medicines,materials,and natural products[1].Nevertheless,the chemo-and stereoselective construction of the glycosidic linkage is a long-stand...; 关键词：PROPERTIES PALLADIUM CATALYZED

Synergistic silver-mediated and palladium-catalyzed nondirected olefination of aryl C–H bond: quick access to multi-substituted aryl olefins: 《Science China Chemistry》2024年第3期882-889,共8页Jian Yao Lili Shao Xiaohong Huo Xiaoming Wang; supported by the National Key R&D Program of China(2021YFA1500100);the National Natural Science Foundation of China(21821002,92256303,22171278);Shanghai Science and Technology Committee(23ZR1482400);the Natural Science Foundation of Ningbo(2023J034)。; Transition metal-catalyzed olefination of aryl C-H bond is a powerful tool for the synthesis of alkenes. While the Pd-catalyzed oxidative C-H olefination of arenes, also known as Fujiwara-Moritani reaction, has been e...; 关键词：direct C–H olefination multi-substituted aryl alkenes bimetallic Pd/Ag cooperation C–H functionalization

Palladium-catalyzed allylic alkylation enabled by ketone umpolung via Pudovik addition/[1,2]-phospha-Brook rearrangement: 《Science China Chemistry》2023年第10期2810-2816,共7页Jian Zhang Jia-Yi Su Yang-Zi Liu Hao Li Quannan Wang Wei-Ping Deng; supported by the National Key Research and Development Program of China(2021YFA0804900);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang(2022R01007);Shanghai Frontiers Science Center of Optogenetic Techniques for Cell Metabolism。; Palladium-catalyzed allylic alkylation enabled by ketone umpolung via Pudovik addition/[1,2]-phospha-Brook rearrangement with phosphites has been developed.The protocol offers a straightforward method for the synthesi...; 关键词：PALLADIUM UMPOLUNG allylic alkylation Pudovik addition [1 2]-phospha-Brook rearrangement

Synergistic catalysis for stereocontrol of prochiral nucleophiles in palladium-catalyzed asymmetric allylic substitution被引量：1: 《Science China Chemistry》2023年第8期2238-2255,共18页Xi Wang Youbin Peng Ling Zhao Xiaohong Huo Wanbin Zhang; supported by the National Natural Science Foundation of China(21831005,21991112,22171183);the Science and Technology Commission of Shanghai Municipality(19JC1430100)。; In contrast to the stereocontrol of the stereocenter at the allyl unit,the asymmetric induction of prochiral nucleophiles remains a challenge in Pd-catalyzed asymmetric allylic substitutions due to the remote distance...; 关键词：asymmetric allylic substitution palladium catalysis synergistic catalysis remote stereocontrol bimetallic catalysis

Palladium-catalyzed 3,4-hydroaminocarbonylation of conjugated dienes for formation ofβ,γ-unsaturated amides: 《Science China Chemistry》2023年第5期1474-1481,共8页Hui-Yi Yang Liang-Quan Lin Na-Qi Li Zhi-Hui Ren Zheng-Hui Guan; supported by the National Natural Science Foundation of China(22171224,21971204);the Innovation Capability Support Program of Shaanxi Province(2020TD-022);the Fund of Education Department of Shaanxi Provincial Government(22JP082)。; Hydrocarbonylation of conjugated dienes is one of the most promising yet challenging methods for the synthesis of carbonyl compounds.Herein,we reported the development of an unprecedented palladium-catalyzed branched ...; 关键词：PALLADIUM-CATALYZED carbonylation reaction regioselectivity conjugated diene amides synthesis

Photoinduced and palladium-catalyzed hydrogen atom transfer triggered 1,2-difunctionalization of 1,3-dienes with hydroxamides: 《Science China Chemistry》2022年第5期863-869,共7页Xiao-Yun Ruan Tao Zhang Wen-Ao Li Yi-Zhuo Yin Zhi-Yong Han Liu-Zhu Gong; supported by the National Natural Science Foundation of China (22188101, 21831007, 21971231, 21772184)。; The discovery of novel catalysis modes to generate a significant increase in structural complexity from readily available reactants is a fundamental goal in modern organic synthesis.Here,we report a photoinduced palla...; 关键词：photoinduced palladium catalysis C–H activation hydrogen atom transfer 1 3-dienes ALLYLATION

Palladium-catalyzed enantioselective carbonylation reactions被引量：3: 《Science China Chemistry》2022年第3期441-461,共21页Jin-Bao Peng Xin-Lian Liu Lin Li Xiao-Feng Wu; supported by the National Natural Science Foundation of China(21801225);the Science Foundation for Young Teachers(2019td02);High-level Talent Research Start-up Project(2018TP018)of Wuyi University;the Guangdong Province Universities and Colleges Pearl River Scholar Funded Scheme(2019);the Department of Education of Guangdong Province(2020KCXTD036)。; Carbonylation,one of the most powerful approaches to the preparation of carbonylated compounds,has received significant attention from researchers active in various fields.Indeed,impressive progress has been made on t...; 关键词：palladium catalyst ENANTIOSELECTIVE CARBONYLATION CHIRAL

Access to chiral homoallylic vicinal diols from carbonyl allylation of aldehydes with allyl ethers via palladium-catalyzed allylic C-H borylation: 《Science China Chemistry》2022年第2期298-303,共6页Tian-Ci Wang Pu-Sheng Wang Dian-Feng Chen Liu-Zhu Gong; supported by the National Natural Science Foundation of China (21831007)。; Chiral homoallylic vicinal diols are found in many bioactive compounds and are among the most versatile functional groups in organic chemistry. Here, we describe an asymmetric carbonyl allylation of aldehydes with all...; 关键词：asymmetric catalysis palladium allylic C–H borylation allyl ethers chiral phosphoric acid ALDEHYDES

Diboron-mediated palladium-catalyzed asymmetric transfer hydrogenation using the proton of alcohols as hydrogen source: 《Science China Chemistry》2021年第10期1743-1749,共7页Bo Wu Jimin Yang Shu-Bo Hu Chang-Bin Yu Zi-Biao Zhao Yi Luo Yong-Gui Zhou; the National Natural Science Foundation of China(21901239,21532006);the Strategic Priority Program of Chinese Academy of Sciences(XDB17020300,QYZDJ-SSW-SLH035)。; The developments of hydrogen sources stand at the forefront of asymmetric reduction. In contrast to the well-studied alcohols as hydrogen sources via β-hydride elimination, the direct utilization of the proton of alc...; 关键词：proton of alcohols hydrogen source asymmetric reduction

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