financial support from the National Natural Science Foundation of China(Nos.22261013 and 22001049);Guangxi Natural Science Foundation(No.2020GXNSFBA297003);Magneto-Chemical Functional Materials(No.EMFM20221102)。
Rhodium-catalyzed C4aryl-H activation and ring-retentive annulation of 2H-imidazoles with internal alkynes to build imidazo[5,1-a]isoquinolinium salts with high yields and broad scope has been disclosed.These novel sa...
the financial support for this investigation from the National Natural Science Foundation of China(No.22072111;the Fundamental Research Funds for the Central Universities(No.2023IVA055).
Nucleophilic phosphine and amine catalyst-switched chemodivergent[4+1]and[3+3]annulations of allenyl imides andβ,γ-enones have been developed,furnishing highly substituted 2-cyclopentenone and 2-pyranone derivatives...
supported by the National Natural Science Foundation of China(21890723,22171189);the Fundamental Research Funds for the Central Universities(YJ201819)。
The diastereo-and enantioselective tandem cycloisomerization/[4+2]-cycloaddition reaction of cyclopropyl tethered allenyl ketones withα,β-unsaturated carbonyl compounds was realized firstly under mild reaction condi...
the National Natural Science Foundation of China(No.21702189);the Key Scientific and Technological Project of Henan Province(No.202102310004);Science and Technology Research and Development Plan Joint Fund(cultivation of superior disciplines)Project(No.222301420042);Zhengzhou University(No.JC21253007)of China for financial support of this research.
Metal/nucleophilic Lewis base dual catalysis has been recognized as a reliable and promising strategy for finishing ideal organic synthesis over the past decades.The new strategy can usually achieve some chemical reac...
financially supported by National Key Research and Development Program of China(No.2018YFA0209401);National Natural Science Foundation of China(Nos.22171053,21733003);Natural Science Foundation of Shanghai(No.21ZR1409600)。
Fluoranthenes have attracted tremendous attention due to their unique optoelectronic properties and extensive applications.Although several synthetic methodologies have been developed for the preparation of fluoranthe...
the National Natural Science Foundation of China(grant nos.21831007 and 22071229).
The cooperative catalysis of an achiral Lewis base and a chiral N-heterocyclic carbene(NHC)enables a highly enantioselective[4+3]annulation of benzoxazinanones with isatin-derived enals.DMAP serves as a nucleophilic L...
Financial support by the National Natural Science Foundation of China(No.22071211);the Science and Technology Planning Project of Hunan Province(No.2019RS2039);Hunan Provincial Natural Science Foundation of China(No.2020JJ3032);Scientific Research Fund of Education Department of Hunan Province(No.21A0079);Open Research Fund of School of Chemistry and Chemical Engineering of Henan Normal University(No.2022C02)。
O-Acyl ketoximes has been proven to be versatile building blocks for practical construction of Nheterocycles.In the last few years,diverse catalytic systems have been discovered to enable efficient transformations of ...
the National Key Research and Development Program of China(No.2016YFB0401400);the National Natural Science Foundation of China(Nos.21871163 and 22071134)。
Me OTf-catalyzed formal[4+2]annulation of styrene oxides with alkynes to afford polysubstituted naphthalenes has been realized,which undergoes sequential electrophilic cyclization/ring expansion.A range of substrates ...
the National Natural Science Foundation of China(Nos.22071242 and 21871260);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);Fujian Natural Science Foundation(No.2018J05035);Science and Technology Research Program of the Education Department of Jiangxi Province(No.GJJ1991151)。
Copper-catalyzed divergent annulations betweenα-diketones and alkynylα-diketones have been achieved,delivering a series of highly functionalized and biologically important cis-hexahydro-2Hcyclopenta[b]furan(HCPF)and...
We are grateful for the financial support from the NSFC(Nos.21931006 and 21921002);the Fundamental Research Funds for the Central Universities.
A solvent-regulated diastereodivergent[3+2]annulation reaction between Morita-Baylis-Hillman carbonates from aryl trifluoromethyl ketones and cyclic sulfonimines is developed under the catalysis of a modified cinchona...