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Study on the mechanism of hydrodesulfurization of tetrahydrothiophene catalyzed by nickel phosphide被引量：1
《Petroleum Science》2022年第3期1390-1400,共11页Chuan-Tao Zhu Li-Qiang Zhang Mei-Ling Zhou Xin-Wei Wang Zheng-Da Yang Ri-Yi Lin De-Wei Yang 
the financial support provided by the National Science and Technology Major Project of the Ministry of Science and Technology of China(2016ZX05012002-005);National Natural Science Foundation of China(No.51874333);Natural Science Foundation of Shandong Province,China(No.ZR2017MEE030)
Hydrodesulfurization(HDS)reaction can significantly reduce the viscosity and sulfur content of heavy oil,while the HDS reaction mechanism of tetrahydrothiophene as the main sulfide in heavy oil is still unclear.The HD...
关键词：TETRAHYDROTHIOPHENE Nickel phosphide HYDRODESULFURIZATION Hydrogen sulfide DFT 
Synthesis of arylsulfonyl-substituted indolo[2,1-a]isoquinolin-6(5H)-one derivatives via a TBAI-catalyzed radical cascade cyclization
《Chinese Chemical Letters》2022年第1期276-279,共4页Shengxian Zhai Shuxian Qiu Shuai Yang Bingyan Hua Yongsheng Niu Chuchu Han Youzhu Yu Yuchao Li Hongbin Zhai 
the State Key Basic Research Program of the People’s Republic of China (No. 2018YFC0310900);National Natural Science Foundation of China (Nos. 21871018, 21801005, 21732001);Shenzhen Science and Technology Innovation Committee (Nos. KQTD20190929174023858, JCYJ20180504165454447);Industry and Information Technology Bureau of Shenzhen Municipality (No. 201806151622209330);Guangdong Science and Technology Program (No. 2017B030314002);Shenzhen-Hong Kong Institute of Brain Science-Shenzhen Fundamental Research Institutions (No. 2019SHIBS0004);the National Ten Thousand Talent Program (the Leading Talent Tier) for the financial support;the Science and Technology Project of Henan Province (No. 202102310328);the Henan Postdoctoral Foundation;the Postdoctoral Innovation Base of Anyang Institute of Technology for financial support
We have developed a metal-free radical cascade reaction of N-substituted 2-aryl indoles with readily available sulfonyl hydrazides for the rapid construction of arylsulfonyl-substituted indolo[2,1-a]isoquinolin-6(5H)-...
关键词：TBAI-catalyzed METAL-FREE Radical cascade CYCLIZATION Nitrogen-containing heterocycles Fused-indole derivatives 
Iron phthalocyanine-catalyzed radical phosphinoylazidation of alkenes:A facile synthesis of β-azido-phosphine oxide with a fast azido transfer step
《Chinese Journal of Catalysis》2021年第10期1634-1640,共7页Xiaoxu Ma Mong-Feng Chiou Liang Ge Xiaoyan Li Yajun Li Li Wu Hongli Bao 
国家重点基础研究发展计划(2017YFA0700103);国家自然科学基金(21922112,21871258,22001251);中国科学院战略性重点研究计划(XDB20000000).
Phosphinoylazidation of alkenes is a direct method to build nitrogen-and phosphorus-containing compounds from feed-stock chemicals.Notwithstanding the advances in other phosphinyl radical related difunctionalization o...
关键词：Iron phthalocyanine Phosphinoylazidation Difunctionalization Radical group transfer Density functional theory calculation 
Cobalt-Catalyzed C-H Allylation of Arenes with Allylic Amines被引量：1
《Chinese Journal of Chemistry》2021年第5期1205-1210,共6页Rui Yan Hang Yu Zhong-Xia Wang 
the National Natural Science Foundation of China(No.21372212);the National Basic Research Program of China(No.2015CB856600)is greatly acknowledged.
[Cp^(*)Co(CO)l_(2)]effectively catalyzes pyridyl-directed C-H allylation of arenes with allylic amines in the presence of AgOAc and CF_(3)COOAg.The reaction features ortho-position monoallylation of 2-pyridylarenes,gi...
关键词：C-H activation C-N activation Homogeneous catalysis Cobalt catalysis ALLYLATION 
Iron Catalyzed Isomerization of a-Alkyl Styrenes to Access Trisubstituted Alkenes被引量：3
《Chinese Journal of Chemistry》2021年第3期585-589,共5页Songgen Xu Guixia Liu Zheng Huang 
the National Natural Science Foundation of China(Nos.21825109,21821002,21732006);the National Basic Research Program of China(No.2016YFA0202900);the Strategic Priority Research Program of Chinese Academy of Sciences(No.XDB20000000);the Chinese Academy of Sciences Key Research Program of Frontier Sciences(No.QYZDB-SSW-SLH016);the K.C.Wong Education Foundation,and the Science and Technology Commission of Shanghai Municipality(No.17JC1401200)is gratefully acknowledged.
Main observation and conclusion Stereoselective isomerization of a-alkyl styrenes is accomplished using a new iron catalyst supported by phosphine-pyridine-oxazoline(PPO)ligand.The protocol provides an atom-efficient ...
关键词：CATALYSIS IRON lsomerization Trisubstituted alkenes STEREOSELECTIVITY 
Cp^*Co(Ⅲ)-catalyzed C—H amidation of azines with dioxazolones
《Chinese Chemical Letters》2020年第12期3237-3240,共4页Yanzhen Huang Chao Pi Zhen Tang Yangjie Wu Xiuling Cui 
the Ministry of Science and Technology of China(No.2016YFE0132600);Henan Center for Outstanding Overseas Scientists(No.GZS2020001)。
Cp^*Co(Ⅲ)-catalyzed direct C—H amidation of azines has been developed.This co nversion could proceed smoothly in the absence of external oxidants,acids or bases,with excellent regioselectivity and broad functional g...
关键词：Cp^*Co(Ⅲ)-catalyzed AZINES AMIDATION Dioxazolone 
Visible Light Driven Copper(I )Catalyzed Oxyamination of Electron Deficient Alkenes被引量：5
《Chinese Journal of Chemistry》2020年第10期1116-1122,共7页Sanliang Li Qiaoyu Chen Wenbo Li Guangxin Gu Junliang Zhang 
We are grateful to the Shanghai Sailing Program(No.16YF1402800);the 973 programs(No.2015CB856600);the National Natural Science Foundation of China(No.21425205)。
Summary of main observation and conclusion A vible light driven Cu()-catalyzed intermolecular oxyamination of electron-deficient olefins has been achieved by using O-benzoylhydroxylamines as donors both for amine and ...
关键词：ALCOHOLS ELECTRON COPPER 
Rhodium^Ⅲ/Silver^ⅠRelay Catalyzed C-H Aminomethylation with Imine Equivalents and Lewis Acid Catalyzed[4+2]Cycloaddition of Indoles with Triarylhexahydrotriazine
《Chinese Journal of Chemistry》2020年第9期947-951,共5页Ruixing Liu Yin Wei Min Shi 
We are grateful for the financial support from the National Basic Research Program of China(No.(973J-2015CB856603);the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDB20000000);sioczz201808,the National Natural Science Foundation of China(Nos.21421091,21372250,21121062,21302203,20732008,21772037,21772226,21861132014,and 91956115).
Summary of main observation and conclusion A Rh^Ⅲ/Ag^Ⅰrelay-catalyzed C(sp^2)—H coupling of indoles with triarylhexahydrotriazine(THT)is reported in this context.Upon merging Rh^Ⅲ-catalyzed C(sp^2)—H bond activat...
关键词：SILVER CATALYZED conclusion 
Superior de/hydrogenation performances of MgH2 catalyzed by 3D flower-like TiO2@C nanostructures被引量：10
《Journal of Energy Chemistry》2020年第7期191-198,I0006,共9页Meng Zhang Xuezhang Xiao Bosang Luo Meijia Liu Man Chen Lixin Chen 
financial supports for this research from the National Basic Research Program of China(2018YFB1502104);the National Natural Science Foundation of China(51571179 and 51671173);the Open Fund of the Guangdong Provincial Key Laboratory of Advance Energy Storage Materials。
Magnesium hydride has been seen as a potential material for solid state hydrogen storage,but the kinetics and thermodynamics obstacles have hindered its development and application.Three-dimensional flower-like TiO2@C...
关键词：Hydrogen storage Magnesium hydride TIO2 Flower-like structure Catalytic effects 
Ming-Phos/Gold(Ⅰ)-Catalyzed Stereodivergent Synthesis of Highly Substituted Furo[3,4-d][i,2]oxazines被引量：1
《Chinese Journal of Chemistry》2020年第6期577-582,共6页Lujia Zhou Bing Xu Danting Ji Zhan-Ming Zhang Junliang Zhang 
the fundi ng support of NSFC(Nos.21425205,21672067,21801078);973 Program(No.2015CB856600);the Program of Eastern Scholar at Shanghai Institutions of Higher Learning and the China Postdoctoral Science Foundation(Nos.2019M650071,2019M661418).
A gold(Ⅰ)-catalyzed asymmetric intermolecular tandem[3+3]-cyclization reaction of 2-(l-alkynyl)-2-alken-l-ones with nitrones has been developed by using Ming-Phos as a chiral ligand.This method enables access to the ...
关键词：SUBSTITUTED HIGHLY 
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