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作品数:1132被引量:1374H指数:10
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相关领域:理学更多>>
相关作者:滕怀龙祝诗发陈自立姚小泉石先莹更多>>
相关机构:中国科学院南开大学郑州大学武汉大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家教育部博士点基金更多>>
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Nickel-catalyzed regiodivergent syn-hydrosilylation of disubstituted alkynes
《Science Bulletin》2024年第21期3334-3339,共6页Jixin Wang Jie Lin Zhili Cui Jianlin Yao Konstantin Karaghiosoff Jie Li 
supported by the National Natural Science Foundation of China(22322108);Natural Science Foundation of Jiangsu Province(BK20231521 and BK20221355);Jiangsu Specially Appointed Professors Plan(SR10900122),and start-up funds from Soochow University.
Given the importance of alkenylsilanes in organosilicon chemistry and material science, direct transition-metal-catalyzed selective hydrosilylation of alkynes with hydrosilanes has emerged as apowerful platform for ac...
关键词:CATALYZED ALKYNES SUBSTITUTED 
Access to N-a-quaternary chiral morpholines via Cu-catalyzed asymmetric propargylic amination/desymmetrization strategy
《Science Bulletin》2024年第22期3516-3524,共9页Peng Chen Mao-Mao Zhang Li Rao Yuan-Heng Li Yue Jia Ying Tan Wen-Jing Xiao Liang-Qiu Lu 
supported by the National Key R&D Program of China(2023YFE0110100);the National Natural Science Foundation of China(22271113,92256301,21822103,and 21820102003)。
Morpholines are widespread in many biologically and catalytically active agents,thus being an important aim of pharmaceutical and synthetic chemists.However,efficient strategies for the catalytic asymmetric synthesis ...
关键词:Chiral morpholine Copper catalysis DESYMMETRIZATION Propargylic amination 
生物信息学资源助力蛋白质磷酸化的系统层次理解
《Science Bulletin》2024年第8期989-992,共4页彭迪 贾大 夏宏光 张珞颖 黄鹏宇 薛宇 
supported by the National Key R&D Program of China(2022YFC2704300,2021YFF0702000 and 2021ZD0201300);the National Natural Science Foundation of China(32341020,32341021,and 31930021);Hubei Innovation Group Project(2021CFA005);Hubei Province Postdoctoral Outstanding Talent Tracking Support Program;the Research Core Facilities for Life Science(HUST)。
Protein phosphorylation,catalyzed by protein kinases(PKs),is one of the most prevalent post-translational modifications(PTMs)in eukaryotes.Phosphorylation occurring at different positions in a protein sequence can pos...
关键词:POSITIONS CATALYZED TRANSLATIONAL 
Synergistic Ni/Cu catalyzed migratory arylsilylation of terminal olefins被引量:1
《Science Bulletin》2021年第6期570-577,M0004,共9页Binzhi Zhao Yuqiang Li Haoyang Li MdBelal Lei Zhu Guoyin Yin 
supported by the National Natural Science Foundation of China(21702151,21774029,and 21871211);the Fundamental Research Funds for Central Universities(2042019kf0208)。
Synthesis of organosilanes from alkenes is a very important topic owing to their wide applications.A Ni/Cu dual metal-catalyzed arylsilylation of terminal alkenes,featuring migratory selectivity,has been developed.A w...
关键词:Alkene difunctionalization Arylsilylation Synergistic catalysis Regioselectivity Metal migration 
Direct conversion of lignin into arene products catalyzed by a niobium-based material被引量:1
《Science Bulletin》2017年第18期1231-1232,共2页Limin Qi 
As a complex aromatic biopolymer that constitutes 25%–35%of renewable carbon on the earth,lignin is the only large-volume renewable source of aromatic chemicals[1].Lignin has an extended network built from alcohol mo...
关键词:芳烃化合物 催化转化 木质素 直接转化 产物 材料 生物聚合物 聚合物结构 
Progress of transition metal-catalyzed cross-coupling mediated by PyBroP被引量:2
《Chinese Science Bulletin》2014年第17期1942-1949,共8页Guojun Chen Jianshi Du 
supported by the Public Welfare Technology Applied Project of Lishui City (2012JYZB32)
In the transition metal-catalyzed cross-coupling reactions,phenol and enol derivatives activated by phosphorus groups are very important electrophiles.This kind of compounds has the advantages of easy preparation,grea...
关键词:过渡金属催化 介导 交叉偶联反应 联通 亲电试剂 催化反应 衍生物 化合物 
Liquid-phase aerobic oxidation of benzyl alcohol catalyzed by mechanochemically synthesized manganese oxide
《Chinese Science Bulletin》2013年第19期2354-2359,共6页ILYAS Mohammad SIDDIQUE Mohsin SAEED Muhammad 
the Higher Education Commission of Pakistan for financial assistance under the Indigenous PhD Fellowship Program
Benzyl alcohol oxidation by molecular oxygen using solid manganese oxide as a catalyst and n-heptane as the solvent was studied in the liquid phase. The catalyst was synthesized by a simple mechanochemical process at ...
关键词:机械化学合成 催化氧化 苯甲醇 锰氧化物 液相 固体催化剂 反应混合物 化学过程 
Evidence from ^(18)O feeding studies for hydroxyl group donor in the reaction catalyzed by cytidylate hydroxymethylase MilA被引量:1
《Chinese Science Bulletin》2013年第8期864-868,共5页CHEN Cheng GAO TuLing ZHAO Gong DENG ZiXin HU ShenCai XU H Howard HE XinYi 
supported by the National Natural Science Foundation of China (31170083);the Ministry of Science and Technology (2012CB721004);the Shanghai Municipal Council of Science and Technology
5-Hydroxymethylcytosine (5hmC) was present in T-even phage and mammalian DNA. 5hmC in phage is formed by hydroxymethylation of the cytosine base in deoxycytidylate (dCMP) by deoxycytidylate hydroxymethylase (CH), whic...
关键词:催化反应 羟基化 供体 LC-MS分析 证据 饲养 羟甲基化 核苷类抗生素 
Formation of silacycles via metal-mediated or catalyzed Si-C bond cleavage
《Chinese Science Bulletin》2013年第3期307-315,共9页WANG LiLi DUAN Zheng 
supported by the National Natural Science Foundation of China (21072179)
Silacycles play a very important role in modern organic chemistry and materials science.Construction of silacyclic skeletons via metal-mediated or catalyzed Si-C bond cleavage has attracted much recent attention.Sever...
关键词:键断裂 介导 金属 材料科学 有机化学 衍生物 催化 合成 
Enantioselective benzoin condensation catalyzed by bifunctional N-heterocyclic carbenes
《Chinese Science Bulletin》2010年第17期1753-1757,共5页HUANG XueLiang YE Song 
supported by the National Natural Science Foundation of China (20602036);the Ministry of Science and Technology of China (2009ZX09501-018) and the Chinese Academy of Sciences.
Benzoin condensation is an important carbon-carbon bond-forming reaction. The benzoin reaction with good yield, high enantioselectivity and broad substrate scope is highly desired in organic synthesis. The intermolecu...
关键词:对映选择性 杂环卡宾 安息香 双功能 缩合 催化 有机合成 高选择性 
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