the financial support from the National Natural Science Foundation of China(22007080);Zhongshan Science and Technology Bureau(CXTD2022012);Youth Innovation Promotion Association of CAS(2020258);grateful to Hi-Level New R&D Institute(2019B090904008);High-Level Innovative Research Institute(2021B0909050003)from Department of Science;Technology of Guangdong Province.Prof.Hongbin Zhang(Yunnan University)is appreciated for the assistance on this project.
Given the extreme complexity and diversity of carbohydrates,efficient approaches to the homogeneous oligosaccharide remain limited.Chemical synthesis represents one of the most reliable methods to access homogeneous s...
Developing efficient glycosylation methods and strategies is always a top priority and endless pursuit for carbohydrate chemists to acquire complex glycosidic linkages.While most glycosylation reactions are step-wise,...
This research is partially supported by the National Natural Science Foundation of China(Nos.21877043,21761132014,21772050,21672077);Wuhan Creative Talent Development Fund,the Fundamental Research Funds for the Central Universities(2019kfyRCPY034,2019JYCXJJ047);Huazhong University of Science and Technology are greatly appreciated.We thank Ana-lytical and Testing Center of HUST for NMR tests.
Summaryof main observation and conclusion A new dehydrativeglycosylation reaction has been established by capitalizing on the compropor-tionation reaction of 2-aryl-1,3-dithiane 1-oxides promoted by triflic anhydride(...
This work was supported by the National Natural Science Foundation of China (Nos. 20961007 and 21264011), the Aviation Fund (No. 2010ZF56023) and the Young Scientists Program of Jiangxi Province (No. 2008DQ00600).
Five new transition metal complexes [Cu(HL)2(H20)2] (1), [Cu(HL)z(phen)] (2), [Cu(HL)2(H20)]2(4,4′-bipy) (3), [Zn(HL)2(HzO)2].(4,4′-bipy) (4), [Ag(HL)(4,4′-bipy)]n (5), (H2L=5-chl...
Acknowledgement This work was financially supported by National Natural Science Foundation of China (No. 20802070) and the research foundation from Key Laboratory of Synthetic Organic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry (CAS). We thank Professor Ran Hong at SIOC for helpful discus- sions.
3-Aryl-l,2,4-benzotriazines were conveniently prepared in moderate to good yields from 1,1-bis(benzotriazol-1- yl)methylarenes with allylsamarium bromide/hexamethylphosphramide (allylSmBr/HMPA). Preliminary result...
The dynamic kinetic resolution of 2-aroyl-l-tetralones was achieved via asymmetric transfer hydrogenation using (S,S)-RuCl(p-cymene)TsDPEN (TsDPEN=N-(tosyl)-1,2-diphenylethylenediamine) in formic acid/triethyl...
Project supported by the National Natural Science Foundation of China'(Nol 21002102), and State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences (No. 10184).
A general synthesis of 1-aryl-l-H-indazoles from o-halogenated aryl aldehydes or ketones and aryl hydrazines was described. This protocol included an intermolecular condensation and a ligand-free copper-catalyzed intr...
The effect of metallic ions on the nitrolysis of DAPT [3,7-diacetyl-1,3,5,7-tetraazabicyclo(3.3.1)nonane] and HA (hexamine) was investigated by experimental and theoretical approaches. The combinatorial reagent, M...
A simple, efficient and green method for the synthesis of 14-aryl-14H-dibenzo[aj]xanthenes by a one-pot condensation reaction of β-naphthol and aryl aldehydes using silica gel-supported polyphosphoric acid (PPA/SiO2...
Project supported by the National Natural Science Foundation of China (No. 20072036) and the Specialized Research Fund for the Doctoral Program of Higher Education of China.
The reaction of a series of 1-(3-pyridyl)-2,2-di-substituted ethylenes with 1-benzyl-1,4-dihydronicotinamide (BNAH) in deaerated acetonitrile produces the corresponding 1-(3-pyridyl)-2,2-di-substituted ethanes i...