We thank the National Natural Science Foundation of China(No.21625203 and 21871126);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(No.2021ZD01)for financial support.
A new method for the synthesis of 3-ethynyl-1-methylene-1,2-dihydronaphthalenes via copper-pro-moted palladium-catalyzed intermolecular alkynylative[5+1]carboannulation of 1-arylphenyl-prop-2-yn-1-yl acetates involvin...
We acknowledge the financial support from the Natural Science Foundation of Zhejiang Province(LY21B020010);K.C.Wong Education Foundation(GJTD-2020-08).
A palladium-catalyzed cascade Heck-type cyclization and carbonylation reaction has been developed for the synthesis of functionalized thioesters.With arylsulfonyl chlorides as odorless and readily available sulfur sou...
This research was supported financially by the National Natural Science Foundation of China(No.32070360 and 31970375);the Innovation and Promotion Project for Forestry Science and Technology of Jiangsu Province(No.LYKJ[2021]18);the Open Fund of Jiangsu Key Laboratory for the Research and Utilization of Plant Resources(No.JSPKLB202201).
Described herein is a palladium-catalyzed decarbonylative methylation of aryl carboxylic acids using tri-methylboroxine(TMB)as the methylating reagent.The Pd(OAc)_(2)/XantPhos system is compatible with a wide range of...
We are grateful for the financial support from the National Natural Science Foundation of China(21790333 and 21925111);the Strategic Priority Research Program of the CAS(XDPB14).
A palladium-catalyzed tandem carbonylative lactonization and cycloaddition reaction of 2-vinyl acetophenones with alkenes and CO has been established.This reaction enables an efficient conversion of the easily availab...
We gratefully acknowledge the National Natural Science Foundation of China(21772198,21871268,22071250);the Frontier Research Program of Bioland Laboratory(Guangzhou Regenerative Medicine and Health Guangdong Laboratory)(2018GRZ110105017);the Natural Science Foundation of Guangdong Province of China(2020A1515011428);the“BAGUI Scholar”Program of Guangxi Province of China for financial support and Prof.Wenjun Tang at Shanghai institute of Organic Chemistry for providing some of ligands for free.
An unprecedented tandem carbonylation/aminocarbonylation triggered by palladium-catalyzed enantio-selective Heck-type exocyclopalladation delivering chiral heterocyclicα-ketoamides has been developed.The uncommon dou...
We thank the National Natural Science Foundation of China(21971071);the Natural Science Foundation of Guangdong Province(2021A1515010155 and 2019B090905007);the Fundamental Research Funds for the Central Universities(2020ZYGXZR075)for financial support.
The catalytic conversion of biomass-derived feedstocks into functional molecules is of significance to synthetic organic chemistry.Herein,through a palladium-catalyzed reductive annulation reaction of resorcinols and ...
Financial support for this work was provided by the National Natural Science Foundation of China(No.21878037);Science and Technology Innovation Fund of Dalian(No.2021JJ12GX025).We also acknowledge Prof.Baomin Wang,Dr Yuming Song,and Dr Ying Peng(Dalian University of Technology,China)for valuable discussions.
An efficient catalytic methodology for trifluoromethylated allylic alkylation of 3-substituted oxindoles usingα-(trifluoromethyl)alkenyl acetates as the trifluoromethyl-containing allylic alkylation partner is descri...
supported by National Natural Science Foundation of China(21901168);“1000-Youth Talents Plan”;Sichuan Science and Technology Program(2021YJ0395);“1.3.5 project for disciplines of excellence,West China Hospital,Sichuan University”.
A dual nickel-/palladium-catalyzed gem-difluorovinylation of alkynyl bromoarenes is presented.This method proceeds smoothly to afford various dihydrobenzofuran compounds containing gem-difluorovinyl fragments with exc...
The NSFC(no.21772063);the Open Project of State Key Laboratory for Supramolecular Structure and Materials(sklssm2021010)are acknowledged.
An efficient construction of oxazoline-containing polycyclic scaffolds is presented through a Pd-catalyzed addition/cyclization of(hetero)arene tethered O-acyl cyanohydrin units and arylboronic acids.Diverse oxazoline...
supported by the“Fundamental Research Funds for Central Universities”(No.1191329135);the Key Laboratory Construction Program of Xi’an Municipal Bureau of Science and Technology(No.201805056ZD7CG40);the starting fund of Xi’an Jiao Tong University(No.7121182002).
Based on palladium-catalyzed allylic amination reaction,the first general example of enantioselective formation of a tetrazole-bearing quaternary stereocenter has been developed.The protocol uses ambivalent tetrazole ...