National Natural Science Foundation of China(Nos.21973056,21972079);Natural Science Foundation of Shandong Province,China(No.ZR2019MB050);Project of the Key Laboratory of Agricultural Film Application of Ministry of Agriculture and Rural Affairs,China.
The mechanism is investigated for Cp^(tBu)Rh(OH)_(2)-catalyzed annulation of 2-biphenylboronic acid with three activated alkenes using M06-2X functional.The reaction comprises transmetalation via two steps and followi...
Supported by the Natural Science Foundation of Shandong Province,China(Nos.ZR2019QB022,ZR2019MB043).
We reported an economic and practical ball-milling method for the synthesis of tetrahvdroquinoline derivatives via a wone-pot"three-component Diels-Alder reaction of anilines,aldehydes and alkenes catalyzed by phos-ph...
Supported by the National Natural Science Foundation of China(No.21772190).
On the basis of a series of control experiments and nuclear magnetic resonance analyses,it is discovered that Boc-protected amino acid ligand coordinated to Pd center is partly replaced by N,N-dimethylformamide,and H2...
Supported by the National Natural Science Foundation of China(No.21878166);the Taishan Scholar Project of Shandong Province,China(No.ts201511033);the Emphasis Development Plan of Shandong Province,China(Nos.2017GGX70102,2017GGX40107);the Open Project of the Chemistry Department in Qingdao University of Science and Technology of China(No.QUSTHX201811).
A series of amino-acid-based ionic liquids was synthesized via one-step protonation of the corresponding L-amiiio acid by utilizing an array of proton sources.The catalytic activity of the amino-acid-based ionic liqui...
Supported by the Natural Science Foundation of Technology Department of Liaoning Province, China(No.2014020109).
Modified hierarchical porous Hβ zeolite was obtained by metal modification of Hβ zeolite, which was treated with alkaline solution, and the catalysts before and after modification were characterized by means of X-ra...
Supported by the National Natural Science Foundation of China(Nos.21572215, 21602215).
A general and efficient coupling of aryl bromides with diethyl malonate is presented. The reaction provided the α-arylated diethyl malonates in moderate to good yields with a low loading of CUC12(5%, molar fraction...
Kojic dipalmitate(KDP) was synthesized by the way of esterification ofpalmitic and kojic acids in organic solvent, with double-lipase as the biocatalyst. Four commercially available lipases(Amano PS, Novozym 435, L...
Supported by the State Hi-tech Research and Development Project of the Ministry of Science and Technology of China(No. 2013AA030705) and the National Natural Science Foundation of China(Nos. 21177016, 21277019).
K+-doped Bi0.02Co was investigated as catalyst for N2O decomposition. It was found that the catalytic performance of the Bi0.02Co catalyst, which was prepared by coprecipitation method, can be effectively modified by...
This study details Ni-catalyzed cross coupling of aryl Grignard reagents with aryl halides in toluene, a nonpolar solvent with a high boiling point. The reaction was applied for the synthesis of various biaryls in goo...
Supported by the National Natural Science Foundation of China(Nos.21172001, 21372008), the Program for the New Century Excellent Talents in University of China(No.NCET-10-0004) and the Natural Science Foundation of Anhui Province of China(No. 1308085QB39).
A convenient and efficient method was developed for the synthesis of naphtho[2,1-blfurans via 4-dimethylaminopyridine(DMAP)-catalyzed cascade reaction of 2-hydroxy-l-naphthaldehydes and a-halogenated ketones in mode...