This research was supported by the grants from the National Natural Science Foundation of China(No.10572097);Shanghai Natural Science Foundation(No.05ZR14111);Shanghai leading Academic Discipline Project(No.T0901).
^1H NMR has been used to determine the 2-, 4-vinyl orientation of heme active site from oxidized mouse neuroglobin (mNgb). The NOEs between 3-methyl and Hα, Hβ of 2-vinyl, together with the NOEs between 5-methyl a...