国家自然科学基金(20832008)

作品数：5被引量：5H指数：2
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相关作者：邢磊杨振军关注陆世芳赵延川更多>>
相关机构：北京大学中国科学院更多>>
相关期刊：《Journal of Chinese Pharmaceutical Sciences》《中国科学：化学》《Chinese Journal of Chemistry》《Science China Chemistry》更多>>
相关主题：NEW氟修饰二氟聚合物电解质膜更多>>
相关领域：理学医药卫生化学工程更多>>
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Synthesis and the anti-HIV activity of novel dinucleotides containing L-isonucleosides
《Journal of Chinese Pharmaceutical Sciences》2013年第4期314-318,共5页王萌 邢磊 陆世芳 关注 杨振军 张礼和 
National Natural Science Foundation of China (Grant No. 20832008 and 21002004)
Three dinucleotides containing L-isonucleosides at 5＇-end were synthesized by an elegant phosphoramidite one-pot method. Their binding modes with HIV integrase were simulated and their anti-HIV activities in pseudoty...
关键词：HIV integrase DINUCLEOTIDES SYNTHESIS ANTI-HIV Binding modes 
以二氟烷基磺酸修饰的聚降冰片烯为基础的聚合物电解质薄膜的制备被引量：3
《中国科学：化学》2011年第12期1833-1839,共7页赵延川 张丽君 许国峰 郑吉 胡金波 
国家自然科学基金(20825209,20832008和20772144);中国科学院知识创新工程重要方向性项目资助
合成了一种新型的二氟烷基磺酰氟单体2-(双环[2.2.1]庚-5-烯-2)-1,1-二氟-2-甲氧基丙基-1-磺酰氟.首先利用二氟甲基2-吡啶基砜和2-乙酰基-5-降冰片烯发生亲核加成反应,在低温下用三氟甲磺酸甲酯保护加成产物中的羟基,之后在KOH/MeOH的...
关键词：聚合物电解质膜 亲核二氟甲基化 二氟烷基磺酰氟 开环烯烃复分解聚合 
Difluoromethylation of O-, S-, N-, C-Nucleophiles Using Difluoromethyltri（n-butyl）ammonium Chloride as a New Difluorocarbene Source被引量：2
《Chinese Journal of Chemistry》2011年第12期2717-2721,共5页王飞 黄维洲 胡金波 
Projrct supportted by the National Natural Science Foundation of China （Nos. 20772144, 20825209, 20832008） and the Chinese Academy of Sciences （Hundreds-Talent Program and Knowledge Innovation Program）.
Difluoromethyltri（n-butyl）ammonium chloride 1 was found to be an effective difluorocarbene reagent for O-, S-, N-, C-difluoromethylation under basic conditions. It is particularly remarkable that, when only 1.2 equi...
关键词：DIFLUOROCARBENE CF2H group DIFLUOROMETHYLATION difluoromethyltri（n-butyl）ammonium chloride 
Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides
《Science China Chemistry》2011年第1期95-102,共8页ZHU JieMing,WANG Fei & HU JinBo CAS Key Laboratory of Organofluorine Chemistry Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China 
financially supported by the National Natural Science Foundation of China (20825209, 20832008, 20772144);the Chinese Academy of Sciences (Hundreds-Talent Program and Knowledge Innovation Program)
Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides has been successfully achieved.It was found that both the catalytic amount of sodium dithionite (Na2S2O4) and the stoi...
关键词：radical fluoroalkylation SULFONAMIDE fluorine ALKENE ALKYNE 
A new strategy for the synthesis of 3-deazaneplanocin A
《Journal of Chinese Pharmaceutical Sciences》2010年第6期436-442,共7页李天舒 陆世芳 邢磊 林桂椿 关注 杨振军 
National Natural Science Foundation of China (Grant No.20472006 and 20832008)
3-Deazaneplanocin A （3-DNPA, 2）, an antiviral and antitumor agent, has been synthesized in an optimized procedure in 10 steps, with an increased overall yield of 11.2%. Started from 2,4-dihyroxyl-3-nitropyridine, re...
关键词：3-Deazaneplanocin A 3-Deazaadenine Neplanocin A 1-Deazapurine 
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