RHODIUM

作品数：162被引量：179H指数：7
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相关作者：王佰全李存耀丁云杰姜淼刘佳更多>>
相关机构：南开大学中国科学院大学中国科学院华东师范大学更多>>
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相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>
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Investigation on Cu promotion effect on Ce-based solid solution-anchored Rh single atoms for three-way catalysis
《Chinese Chemical Letters》2025年第2期546-550,共5页Jianing He Xiao Wang Zijian Wang Ruize Jiang Ke Wang Rui Zhang Huilin Wang Baokang Geng Hongyi Gao Shuyan Song Hongjie Zhang 
supported by the financial aid from National Science and Technology Major Project of China(No.2020YFE0204500);National Natural Science Foundation of China(Nos.22020102003,22025506 and 11975301);Youth Innovation Promotion Association of the Chinese Academy of Sciences(No.2020286)。
The three-way catalyst(TWC),as a promising approach to control automobile exhaust emission,has been widely studied and applied.However,it still suffers from the high light-off temperature and poor stability.Herein,we ...
关键词：Three-way catalysts(TWC) Solid solution CO-PRECIPITATION Rhodium(Rh)catalyst Oxygen vacancies 
Rhodium(Ⅲ)-catalyzed diastereo-and enantioselective hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes
《Chinese Chemical Letters》2024年第9期160-164,共5页Yi-Fan Wang Hao-Yun Yu Hao Xu Ya-Jie Wang Xiaodi Yang Yu-Hui Wang Ping Tian Guo-Qiang Lin 
financial support from the National Key R&D Program of China(No.2022YFF1202600);the National Natural Science Foundation of China(Nos.22001172,22071155,and22371188);the Science and Technology Commission of Shanghai Municipality(Nos.20XD1403600 and 20400750300);the Shanghai Municipal Education Commission(No.2019-01-07-00-10-E00072);the Innovation Team and Talents Cultivation Program of National Administration of Traditional Chinese Medicine(No.ZYYCXTD-202004);the Shanghai Municipal Health Commission/Shanghai Municipal Administration of Traditional Chinese Medicine[No.ZY(2021-2023)-0501];Organizational Key R&D Program of SHUTCM(No.2023YZZ01)。
A rhodium(Ⅲ)-catalyzed hydrosilylation/cyclization reaction of cyclohexadienone-tetheredα,β-unsaturated aldehydes(1,6-dienes)with triethylsilane is described,providing a series of cishydrobenzofurans,cis-hydroindol...
关键词：Rhodium(Ⅲ)catalysis Hydrosilylation/cyclization 1 6-Dienes Silyl enol ether Diastereo-and enantioselectivity 
Elucidating ligand effects in rhodium(Ⅲ)-catalyzed arene-alkene coupling reactions
《Chinese Chemical Letters》2024年第5期130-134,共5页Kongchuan Wu Dandan Lu Jianbin Lin Ting-Bin Wen Wei Hao Kai Tan Hui-Jun Zhang 
financial support from the National Natural Science Foundation of China(Nos.21772162,21772165,22171237,22071208);Youth Innovation foundation of Xiamen(No.3502Z20206058).
Rhodium(Ⅲ)-catalyzed C-H couplings of arenes with alkenes are among the most powerful methods for C-C bond formation.For these transformations,subtle manipulation of ancillary ligands can lead to dramatic changes in ...
关键词：ORGANOMETALLICS Transition metal catalysis Arene-alkene coupling β-H elimination Rhodium hydride 
Rhodium-catalyzed Doyle-Kirmse rearrangement reactions of sulfoxoniun ylides
《Chinese Chemical Letters》2024年第4期363-366,共4页Ying-Di Hao Zhi-Qian Lin Xiao-Yu Guo Jiao Liang Can-Kun Luo Qian-Tao Wang Li Guo Yong Wu 
supported by Sichuan Science and Technology Program (No.2020YJ0221)。
Doyle-Kirmse rearrangement reactions have received continuous attention as an important method for constructing complex chemical structures. Herein, we disclosed an efficient rhodium-catalyzed DoyleKirmse rearrangemen...
关键词：Sulfoxonium ylides Rhodium(Ⅱ)-catalyzed CARBENE Rearrangement reactions One-pot process 
Recent advances of Rh-based intermetallic nanomaterials for catalytic applications
《Chinese Chemical Letters》2023年第11期52-62,共11页Lijie Zhu Chunhai Li Qinbai Yun Sumei Han Yong Lv Qipeng Lu Junze Chen 
supported by the National Natural Science Foundation of China(Nos.92061119,52102286);Guangdong Basic and Applied Basic Research Foundation(No.2022A1515140051);the Beijing NOVA Program(Nos.Z201100006820066,20220484172);Beijing Information Science&Technology University,and Key Laboratory Fund Project(No.202105509).
Rhodium(Rh)has received widespread attention in fundamental catalytic research and numerous industrial catalytic applications.Compared to homogeneous catalysts,Rh-based nanomaterials as heterogeneous catalysts are muc...
关键词：Rhodium Internetallics Heterogeneous catalysis ELECTROCATALYSIS 
Ligand enabled none-oxidative decarbonylation of aliphatic aldehydes
《Chinese Chemical Letters》2023年第7期107-111,共5页Bo Li Shihao Liu Wu Fan Xiaotong Shen Jing Xu Suhua Li 
financial support from the National Natural Science Foundation of China (No. 21971260);Guangdong Natural Science Funds for Distinguished Young Scholar (No. 2018B030306018);the Program for Guangdong Introducing Innovative and Entrepreneurial Teams (No. 2017ZT07C069);the Pearl River Talent Recruitment Program (No. 2019QN01L111);the Fundamental Research Funds for the Central Universities, Sun Yatsen University (No. 22lglj06);Innovation projects of Zhengzhou tobacco research institute (No. 442020CR0320 to Wu Fan)。
Decarbonylation of aldehydes is a basic organic transformation, which has been developed for more than six-decade. However, as comparing to well-studied aromatic aldehydes, fewer examples for catalytic decarbonylation...
关键词：DECARBONYLATION Aliphatic aldehydes RHODIUM IRIDIUM LIGAND 
Single-atom rhodium anchored on S-doped black phosphorene as a promising bifunctional electrocatalyst for overall water splitting
《Chinese Chemical Letters》2023年第7期269-273,共5页Xinyi Li Zhongxu Wang Yu Tian Xiaofeng Li Qinghai Cai Jingxiang Zhao 
financially supported by the Natural Science Funds (NSF) for Distinguished Young Scholar of Heilongjiang Province (No. JC2018004)。
Superior bifunctional electrocatalysts with ultra-high stability and excellent efficiency are crucial to boost the oxygen evolution reaction(OER) and the hydrogen evolution reduction(HER) in the overall water splittin...
关键词：Overall water splitting Bifunctional catalysts Single-atom catalysts S-doped black phosphorene Density functional theory computations 
Regiocontrolled Rh(Ⅲ)-catalyzed C-C coupling/C-N cyclization mediated by distinctive 1,2-migratory insertion of gem-difluoromethylene allenes:Reaction development and mechanistic insight
《Chinese Chemical Letters》2023年第5期250-255,共6页Zhi Zhou Kaifeng Chen Yi Wang Xiuhua Zhong Shuang Lin Hui Gao Wei Yi 
the National Natural Science Foundation of China(NSFC,Nos.21877020,22007020);Natural Science Foundation of Guangdong Province(No.2019A1515010935);Science and Technology Program of Guangzhou(No.202102020615)for financial support on this study。
By developing gem-difluoromethylene allenes as viable partners,regiocontrolled Rh(Ⅲ)-catalyzed redoxneutral C-C coupling/C-N cyclization has been realized to build the pyridin-2(1H)-one motifs with the embedment of a...
关键词：Gem-difluoromethylene allenes C-H functionalization REGIOCONTROL Rhodium(Ⅲ)catalysis DFT calculations 
Rhodium catalyzed asymmetric synthesis of Chiraphos derivatives
《Chinese Chemical Letters》2022年第12期5084-5087,共4页Ying-Ying Sun Bin Zhang Liangbin Yu Ranran Cui Qingyang Zhao Qing-Wei Zhang 
support from the National Natural Science Foundation of China (Nos. 21901235 and 22071224);the USTC Research Funds of the Double First-Class Initiative (No. YD20600002010);the Anhui Provincial Natural Science-Foundation (No. 1908085MB34);the Science, Technology and Innovation Commission of Shenzhen (No. JCYJ20190807155201669)
Herein,we report a highly efficient versatile synthetic route to Chiraphos derivatives through Rh/Ph-bod catalyzed asymmetric addition of aryl boronic acids to phosphinyl dienes.Various substituted phosphinyl dienes,b...
关键词：RHODIUM PHOSPHINE Diene ligand 1 4-Addition Chiraphos 
Rhodium-catalyzed formal[4+3]annulation reaction of N-methoxybenzamides with gem–difluorocyclopropenes:A combination of experimental and theoretical studies
《Chinese Chemical Letters》2022年第6期2987-2992,共6页Yimiao He Limei Tian Xuexue Chang Zeming Qu Yanmin Huang Chusheng Huang Qing Sun Honggen Wang 
National Natural Science Foundation of China(Nos.21861007,21702034);Natural Science Foundation of Guangxi Province(No.2021GXNSFAA075024);“BAGUI Scholar”Program of Guangxi Province of China;High-Level Innovation Team and Distinguished Scholar Program in Guangxi Colleges and Universities。
A rhodium-catalyzed[4+3]cycloaddition reaction between N-methoxybenzamides and gem–difluorocyclopropenes is described.The reaction offers a mild and efficient approach towards the synthesis of fluorinated 2 H-azepin-...
关键词：gem-Difluorocyclopropene Fluorinated 2H-azepin-2-one C-H functionalization Oxidizing directing group RHODIUM [4+3]Annulation 
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