supported by Sichuan Science and Technology Program (No.2020YJ0221)。
Doyle-Kirmse rearrangement reactions have received continuous attention as an important method for constructing complex chemical structures. Herein, we disclosed an efficient rhodium-catalyzed DoyleKirmse rearrangemen...
Sichuan Science and Technology Program(No:2020YJ0221);the Natural Science Foundation of Shandong Province,China(No.ZR2021QH362).
Comprehensive Summary Benzothiadiazine-1,1-dioxide scaffold is bioactive framework with wild utility and applications.Synthesis of benzothiadiazine-fused isoquinoline derivatives and spiro benzothiadiazine derivatives...
Support for this work was provided by the National Natural Science Foundation of China(No.21871226 and 21572194);the Hunan Provincial Innovative Foundation for Postgraduate(XDCX2020B114 and CX20200634).The Undergraduate Investigated Study and Innovated Experiment Plan from the Ministry of Education of China and Hunan Province is gratefully acknowledged.
Merging selective C-H cleavage with C-C cleavage in a tandem reaction has been a practical strategy that permits skeletal diversification from simple raw materials.Herein,we describe a rhodium(III)-catalyzed redox-neu...
the National Natural Science Foundation of China(Nos.21871235,21901230,21801224);the Natural Science Foundation of Zhejiang Province(No.LQ18B020009);the Fundamental Research Funds of Zhejiang Sci-Tech University(2019Y003);the Science Foundation of Zhejiang Sci-Tech University(ZSTU)under Grant No.18062301-Y is gratefully acknowledged.
An efficient rhodium(Ⅱ)-catalyzed[4+3]cyclization reaction of 1-sulfonyl-1,2-3-triazoles and indoles was developed.Azepino[5,4,3-ccflindoles,which are widely distributed in ergot alkaloids with various biological act...
Acid-controlled,chemodivergent and redox-neutral annulations for the synthesis of isocoumarins and isoquinolinones have been realized via Rh(Ⅲ)-cataIyzed C—H activation.Diazo compounds act as a carbene precursor,and...
financially supported by the National Natural Science Foundation of China(NSFC,Nos.21602130 and 21961023);the startup funding from Shanghai Jiao Tong University.
A Rh(Ⅰ)-catalyzed highly regio-and enantioselective allylic alkylation of Meldrum acid with racemic allylic substrates bearing alkyl groups has been developed.The applying of chiral bisoxazopinephosphine ligand is es...
financial support from the National Natural Science Foundation of China(No.21971261);Guangdong Provincial Key Laboratory of Chiral Molecule and Drug Discovery(No.2019B030301005);Key Project of Chinese National Programs for Fundamental Research and Development(No.2016YFA0602900);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01Y093)is gratefully acknowledged。
The synthesis of bo rylated orga nofluorines is of great interest due to their potential values as synthons in modular construction of fluorine-containing molecules.Reported herein is a rhodium-catalyzed hydrobo ratio...
Summary of main observation and conclusion An intermolecular [4+2] cycloaddition was realized through C-C bond cleavage in the presence of Rh(Ⅰ) catalyst.The selective ring opening of 2-alkylenecyciobutanols enables ...
supported by the National Natural Science Foundation of China(No.21503143);the Tianjin Natural Science Foundation(Nos.16JCQNJC05600 and 16JCYBJC43600);the Talent Research Start-up Fund of Tianjin Normal University(No.5RL139);support from the Shenzhen Peacock Plan(No.1208040050847074)
The rhodium-catalyzed formal C(sp^3)-H activation/spiroannulation of α-arylidene pyrazolones with alkynes was investigated by means of density functional theory calculations. The calculations indicate that the spir...
supported by the Dalian Institute of Chemical Physics,Chinese Academy of Sciences;the National Natural Science Foundation of China (21525208,21472186)~~
A mild and efficient oxidative synthesis of isoindolinones has been realized by Rh(III)‐catalyzed C?H activation of benzamides and[4+1]coupling with propargyl alcohols.This coupling system proceeds with broad substra...