RHODIUM

作品数:162被引量:179H指数:7
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相关领域:理学更多>>
相关作者:王佰全李存耀丁云杰姜淼刘佳更多>>
相关机构:南开大学中国科学院大学中国科学院华东师范大学更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金国家高技术研究发展计划更多>>
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Rhodium-catalyzed Doyle-Kirmse rearrangement reactions of sulfoxoniun ylides
《Chinese Chemical Letters》2024年第4期363-366,共4页Ying-Di Hao Zhi-Qian Lin Xiao-Yu Guo Jiao Liang Can-Kun Luo Qian-Tao Wang Li Guo Yong Wu 
supported by Sichuan Science and Technology Program (No.2020YJ0221)。
Doyle-Kirmse rearrangement reactions have received continuous attention as an important method for constructing complex chemical structures. Herein, we disclosed an efficient rhodium-catalyzed DoyleKirmse rearrangemen...
关键词:Sulfoxonium ylides Rhodium(Ⅱ)-catalyzed CARBENE Rearrangement reactions One-pot process 
Derivation of Benzothiadiazine-1,1-dioxide Scaffolds via Transition Metal-Catalyzed C-H Activation/Annulation
《Chinese Journal of Chemistry》2023年第16期1973-1978,共6页Ruizhi Lai Shuran Xu Qingyao Zhang Hui Zhou Cankun Luo Yuerong Wang Li Hai Yong Wu 
Sichuan Science and Technology Program(No:2020YJ0221);the Natural Science Foundation of Shandong Province,China(No.ZR2021QH362).
Comprehensive Summary Benzothiadiazine-1,1-dioxide scaffold is bioactive framework with wild utility and applications.Synthesis of benzothiadiazine-fused isoquinoline derivatives and spiro benzothiadiazine derivatives...
关键词:C-H activation ANNULATION RUTHENIUM RHODIUM HETEROCYCLES Fused-ring systems Spiro compounds Diazo compounds 
Rhodium(III)-catalyzed successive C(sp^(2))-H and C(sp^(2))-C(sp^(2))bond activation of aryl oximes:synthetic and mechanistic studies
《Organic Chemistry Frontiers》2022年第3期822-830,共9页Cheng Li Huawen Huang Fuhong Xiao Bin Zhao Guo-Jun Deng 
Support for this work was provided by the National Natural Science Foundation of China(No.21871226 and 21572194);the Hunan Provincial Innovative Foundation for Postgraduate(XDCX2020B114 and CX20200634).The Undergraduate Investigated Study and Innovated Experiment Plan from the Ministry of Education of China and Hunan Province is gratefully acknowledged.
Merging selective C-H cleavage with C-C cleavage in a tandem reaction has been a practical strategy that permits skeletal diversification from simple raw materials.Herein,we describe a rhodium(III)-catalyzed redox-neu...
关键词:materials CATALYZED CLEAVAGE 
Rhodium(Ⅱ)-Catalyzed [4+3] Cyclization of Triazoles with Indole Derivatives and Its Application in the Total Synthesis of (±)-Aurantioclavine被引量:1
《Chinese Journal of Chemistry》2021年第5期1145-1152,共8页Shengguo Duan Bing Xue Hui Meng Zihang Ye Ze-Feng Xu Chuan-Ying Li 
the National Natural Science Foundation of China(Nos.21871235,21901230,21801224);the Natural Science Foundation of Zhejiang Province(No.LQ18B020009);the Fundamental Research Funds of Zhejiang Sci-Tech University(2019Y003);the Science Foundation of Zhejiang Sci-Tech University(ZSTU)under Grant No.18062301-Y is gratefully acknowledged.
An efficient rhodium(Ⅱ)-catalyzed[4+3]cyclization reaction of 1-sulfonyl-1,2-3-triazoles and indoles was developed.Azepino[5,4,3-ccflindoles,which are widely distributed in ergot alkaloids with various biological act...
关键词:TRIAZOLES RHODIUM ALKALOIDS CYCLIZATION Aurantioclavine 
Rhodium(Ⅲ)-catalyzed chemodivergent annulations between phenyloxazoles and diazos via C-H activation
《Chinese Chemical Letters》2021年第2期695-699,共5页Xueguo Zhang Peigen Wang Liangwei Zhu Baohua Chen 
Acid-controlled,chemodivergent and redox-neutral annulations for the synthesis of isocoumarins and isoquinolinones have been realized via Rh(Ⅲ)-cataIyzed C—H activation.Diazo compounds act as a carbene precursor,and...
关键词:Rhodium(Ⅲ)-catalyzed C-H activation Acid-controlled ISOCOUMARIN One-pot process Ring opening/ring closure 
Rh(Ⅰ)-catalyzed regio-and enantioselective allylic alkylation of Meldrum's acid
《Chinese Chemical Letters》2021年第1期385-388,共4页Min Liu Haiying Zhao Changkun Li 
financially supported by the National Natural Science Foundation of China(NSFC,Nos.21602130 and 21961023);the startup funding from Shanghai Jiao Tong University.
A Rh(Ⅰ)-catalyzed highly regio-and enantioselective allylic alkylation of Meldrum acid with racemic allylic substrates bearing alkyl groups has been developed.The applying of chiral bisoxazopinephosphine ligand is es...
关键词:RHODIUM Bisoxazolinephosphine Allylic substitution Meldrum’s acid Asymmetric catalysis 
Synthesis of difluoromethylated benzylborons via rhodium(Ⅰ)-catalyzed fluorine-retainable hydroboration of gem-difluoroalkenes被引量:1
《Chinese Chemical Letters》2021年第1期417-420,共4页Yuanhong Cai Donghang Tan Qiqi Zhang Wenxin Lv Qingjiang Li Honggen Wang 
financial support from the National Natural Science Foundation of China(No.21971261);Guangdong Provincial Key Laboratory of Chiral Molecule and Drug Discovery(No.2019B030301005);Key Project of Chinese National Programs for Fundamental Research and Development(No.2016YFA0602900);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01Y093)is gratefully acknowledged。
The synthesis of bo rylated orga nofluorines is of great interest due to their potential values as synthons in modular construction of fluorine-containing molecules.Reported herein is a rhodium-catalyzed hydrobo ratio...
关键词:RHODIUM HYDROBORATION Difluoromethy gem-Difluoroalkene β-F elimination 
Rhodium(Ⅰ)-Catalyzed [4+2] Cycloaddition Reactions of 2-Alkylenecyclobutanols with Alkynes and (E)+-2-Nitroethenylbenzene through C(sp2)-C(sp3) Bond Cleavage被引量:2
《Chinese Journal of Chemistry》2019年第8期786-792,共7页Xinxin Zheng Guozhu Zhang Dayong Zhang 
Summary of main observation and conclusion An intermolecular [4+2] cycloaddition was realized through C-C bond cleavage in the presence of Rh(Ⅰ) catalyst.The selective ring opening of 2-alkylenecyciobutanols enables ...
关键词:PRESENCE ring step was 
Mechanism of rhodium(Ⅲ)-catalyzed formal C(sp^3)-H activation/spiroannulation of a-arylidene pyrazolones with alkynes:A computational study
《Chinese Chemical Letters》2018年第9期1355-1358,共4页Hongyan Zou Zhong-Liang Wang Yang Cao Genping Huang 
supported by the National Natural Science Foundation of China(No.21503143);the Tianjin Natural Science Foundation(Nos.16JCQNJC05600 and 16JCYBJC43600);the Talent Research Start-up Fund of Tianjin Normal University(No.5RL139);support from the Shenzhen Peacock Plan(No.1208040050847074)
The rhodium-catalyzed formal C(sp^3)-H activation/spiroannulation of α-arylidene pyrazolones with alkynes was investigated by means of density functional theory calculations. The calculations indicate that the spir...
关键词:RHODIUM Spiroannulation C-H activation Reaction mechanism DFT calculations 
Rhodium(Ⅲ)-catalyzed selective access to isoindolinones via formal [4+1] annulation of arylamides and propargyl alcohols
《Chinese Journal of Catalysis》2017年第8期1390-1398,共9页Youwei Xu Fen Wang Songjie Yu Xingwei Li 
supported by the Dalian Institute of Chemical Physics,Chinese Academy of Sciences;the National Natural Science Foundation of China (21525208,21472186)~~
A mild and efficient oxidative synthesis of isoindolinones has been realized by Rh(III)‐catalyzed C?H activation of benzamides and[4+1]coupling with propargyl alcohols.This coupling system proceeds with broad substra...
关键词:RHODIUM C-H activation [4+1] annulation Propargyl alcohol ISOINDOLINONES 
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