The authors regret that in the original article,the structure of(–)-swainsonine(1)in Graphical abstract,Fig.1,Schemes 1 and 3 was incorrect.The correct structure is shown here.
the Jiangsu Provincial Six Talent Peaks Project(No.XCL-090);the Cooperation Project of Yangzhou City with Yangzhou University(No.YZ2023209);Jiaxing Key Laboratory for Creation of Animal Models&Synthesis of Lead Compounds of New Drug(No.jxsz21006);the Priority Academic Program Development of Jiangsu Higher Education Institutions for support。
The synergistic effect of Se with Fe can enhance the catalytic activities of the system for oxidation reactions.Based on this principle,a series of Se/Fe materials have been invented to develop the heterogeneous catal...
supported by the National Natural Science Foundation of China(No.U21A20278);Sichuan Science and Technology Program(No.2021YJ0221).
The concise syntheses of eight 13-methylprotoberberine(13-MePB)and eight enantioenriched 13-methyltetrahydroprotoberberine(13-MeTHPB)alkaloids have been achieved in a tactically modular fashion.This synthetic work fea...
financial support from the National Natural Science Foundation of China (Nos.21672176 and 21332007);the National Key R&D Program of China (No. 2017YFA0207302)
The enantioselective total synthesis of the putative structure of versiquinazoline H and three diastereomers has been achieved,which allowed the revision of the stereochemistry of this natural product.This six-step to...
financially supported by the National Natural Science Foundation of China(Nos. 2016YFF0100901, 61274054 and 61504064)
NaTi_2 (PO_4)_3 (NTP) nanocrystals with high room-temperature ionic conductivity of 1.1×10~3 S/cm were prepared by a concise solvothermal method at 140 ℃ for 3 h, and the aspect ratios of all the NTP nanocrystals ar...
Financial support from the National Natural Science Foundation of China(No.21272240);National Science and Technology Major Projects for“Major New Drugs Innovation and Development”(No.2013ZX09508104);National Engineering Research Center for Carbohydrate Synthesis of Jiangxi Normal University
1-epi-Castanospermine(5) was synthesized from readily available 2,3,4,6-tetra-O-benzyl-1-deoxynojirimycin(11) in 9 steps and 21% overall yield, with selective debenzylation, Barbier reaction and reductive aminatio...
supported by Program for Innovative Research Team of the Ministry of Education and Program for Liaoning Innovative Research Team in University;Shenyang Shuangding Pharmaceutical Co.,LTD.,Shenyang,China
Benzyl protecting protocol was first employed in two routes for the concise synthesis of dopexamine dihydrochloride.This protecting group could be cleanly removed under mild condition and no unacceptable ion was broug...
the National Natural Science Foundation of China (Nos. 21272036, 21332010);the National Basic Research Program of China (No. 2012CB21600)
A novel gem-difluoromethylenated castanospermine analogue B was designed and synthesized, starting from 3-bromo-3,3-difluoropropene and L-(-)-malic acid. The key steps involve substitution cyclization reaction and R...
financial support from the National Basic Research Program(973 Program)of China(No. 2010CB833200);the NSF of China(Nos.21332007,21072160);the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)of Ministry of Education,China for financial support
A short formal stereoselective synthesis of (-)-swainsonine (1) is described. Our synthesis started with the versatile building block (R)-3-benzyloxyglutarimide 5. Through controlled regioselective reduction, Le...
support from The First Hospital of Jilin University
The antibiotic (-)-anisomycin was synthesized starting from D-tyrosine using Sharpless asymmetric epoxidation as a key reaction followed by formation and hydrolysis of oxazoline set up all chiral center.