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国家重点基础研究发展计划(2010CB833200): 作品数：16被引量：34H指数：4; 导出分析报告; 相关作者：黄培强张丹秦勇肖开炯黄应红更多>>; 相关机构：四川大学厦门大学重庆大学四川农业大学更多>>; 相关期刊：《Science China Chemistry》《Journal of Chinese Pharmaceutical Sciences》《化学学报》《有机化学》更多>>; 相关主题：CYCLIZATION全合成ENANTIOSELECTIVERACEMIC氧化偶联更多>>; 相关领域：理学化学工程生物学环境科学与工程更多>>

Enantioselective synthesis of functionalized fluorinated dihydropyrano[2,3-c]pyrazoles catalyzed by a simple bifunctional diaminocyclohexane-thiourea被引量：7: 《Chinese Chemical Letters》2014年第4期535-540,共6页Hong-Fei Zhang Zheng-Qing Ye Gang Zhao; supported by National Basic Research Program of China(973 Program,No.2010CB833200);the National Natural Science Foundation of China(Nos.21032006,203900502,20532040,21290180);Science and Technology Commission of Shanghai Municipality(No.11XD1406400); Enantioselective synthesis of functionalized fluorinated dihydropyrano[2,3-c]pyrazoles has been achieved via a diaminocyclohexane-thiourea catalyzed cascade Michael addition and Thorpe-Ziegler type cyclization in high...; 关键词：Trifluoromethyl Pyrazoles Cyclization Organocatalysis

A novel and versatile method for the enantioselective syntheses of tropane alkaloids被引量：3: 《Science China Chemistry》2014年第2期252-264,共13页MAO ZhongYi HUANG SuYu GAO LongHui WANG AiE HUANG PeiQiang; the National Basic Research Program of China(973 Program,2010CB833200);the National Natural Science Foundation of China(21072160,21332007);the Program for Changjiang Scholars and Innovative Research Team at the University of the MOE for financial support; A full account of the novel and flexible approach to hydroxylated 8-azabicyclo[3,2,1]octan-3-ones and 9-azabicyclo[3,3,1] nonan-3-ones is presented. Using keto-lactams as the starting materials, this two-step method c...; 关键词：synthetic methods tropane alkaloids CYCLIZATION ACTIVATION AMIDES

Absolute Configuration of the Phenylpropanoid Isolated from Peperomia tetraphylla: 《Chinese Journal of Chemistry》2013年第10期1336-1340,共5页Yanchao Yu Xiaowei Lu Wenju Wu Yikang Wu Bo Liu; Acknowledgement This work was supported by the National Basic Research Program of China （the 973 Program, No. 2010CB833200）, the National Natural Science Foundation of China （Nos. 21172247, 21032002, 20921091） and the Chinese Academy of Sciences.; A recently identified phenylpropanoid isolated from Peperomia tetraphylla was synthesized in enantiopure forms using an aldol condensation of enantiopure （R）-N-acetyl 4-phenyl-oxazolidin-2-one as the key step. With ...; 关键词：ESTERS aldol condensation natural products STEREOCHEMISTRY ETHERS

氧化偶联策略在复杂吲哚生物碱全合成中的应用被引量：12: 《化学学报》2013年第2期147-150,共4页张丹秦勇; 科技部973计划(No.2010CB833200);国家自然科学基金(Nos.21202209;21132006);中央高校基本科研业务费(CQDXWL-2012-131);重庆市自然科学基金(No.cstc2012jjA10087)资助~~; 氧化偶联反应作为一种高效、经济的C—C键构建策略,在天然产物的全合成中得到了重要的应用.近年来,马大为课题组通过发展高效的LiHMDS/I2偶联条件,成功实现了四种复杂吲哚生物碱的全合成,在该领域取得了重要的进展.本文就马大为课题组...; 关键词：氧化偶联 communesin F communesin A^B vincorine 全合成

One-pot Synthesis of Aromatic Fused 2,3-Dihydroindanone by Tandem Pauson-Khand/Michael/Henry Reaction: 《Chinese Journal of Chemistry》2013年第1期49-54,共6页Mingming Li Ping Xing Zuogang Huang Biao Jiang; The intermolecular Pauson-Khand reaction between 2-ethynylbenzaldehyde and ethylene promoted by dimethyl sulfide can be utilized to synthesize 2-（2-formylphenyl）cyclopentenone efficiently. This compound and its deri...; 关键词：2-ethynylbenzaldehyde tandem Pauson-Khand/Michael/Henry reaction aromatic fused 2 3-dihydro-indanone

Towards Stereochemical Control＂ Two Approaches for the Highly anti.Diastereoselective Construction of the Spirolactone Moieties of Some Stemona Alkaloids被引量：1: 《Chinese Journal of Chemistry》2013年第1期55-62,共8页Shichuan Tuo Xuekui Liu Peiqiang Huang; Some Stemona alkaloids belonging to the tuberostemospironine group possess a spirolactone moiety with anti-configuration （C-9/C-9a）. In this paper, we describe two approaches to this structural unity. By using bromi...; 关键词：Stemona alkaloids SPIROLACTONE SmI2 organozinc reagent sessilifoliamide J

乌药烷型倍半萜及其二聚体的全合成研究进展被引量：4: 《有机化学》2013年第1期90-100,共11页乐贵洲杨立袁长春杜彪刘波; 国家自然科学基金(Nos.20872098,21021001,21172154);国家重点基础研究发展规划(973计划,No.2010CB833200)~~; 乌药烷型倍半萜及其二聚体是一大类具有cis,trans-3/5/6三并环特殊骨架的天然产物,主要是从金粟兰科植物中分离得到.大多数乌药烷型倍半萜及其二聚体具有显著的生物活性,如抗真菌、对B细胞有毒性介导的免疫抑制及对延迟整流钾电流有选...; 关键词：乌药烷倍半萜二聚体全合成

Biomimetic Cationic Cyclization toward ent-Kaurene-type Diterpenoids被引量：1: 《Chinese Journal of Chemistry》2013年第1期111-118,共8页Lili Zhu Ran Hong; Terpenoids comprise the largest family of natural products and include various structurally different genus which play important roles in living organisms. Biosynthetically, diterpenoids are derived from （E,E,E）-ger...; 关键词：DITERPENOID ent-kaurene biomimetic synthesis carbocation cyclization Birch reduction/alkylationcascade

A Clear-Cut Synthesis of Arteannuin O: 《Chinese Journal of Chemistry》2013年第1期139-142,共4页Huijun Chen Hongdong Hao Yikang Wu; Acknowledgement This work was supported by the National Basic Research Program of China （the 973 Program, 2010CB833200）, and the National Natural Science Foundation of China （Nos. 21172247, 21032002, 20921091, 20621062）.; The title compound was synthesized from dihydroqinghao acid via a sequential facial selective oxidative lac- tonization and epoxidation, a molybdenum-catalyzed perhydrolysis of the epoxy ring and dimethyl sulfide redu...; 关键词：DIOL OXIDATION EPOXIDE perhydrolysis RING-OPENING

仲酰胺经酰胺活化直接合成酮的普适性方法被引量：7: 《化学学报》2012年第18期1917-1922,共6页肖开炯黄应红黄培强; 国家重点基础研究发展计划(973计划)(No.2010CB833200);国家自然科学基金(Nos.21072160,20832005);教育部博士研究生学术新人奖(2010)资助~~; 本文报道仲酰胺经去胺基烷基化反应直接合成酮的通用性方法.这一新的C—C键形成方法是基于Tf2O对仲酰胺的活化及有机铈试剂对活化所形成活性中间体的加成而实现的.该方法可用于各种酮的合成,包括烷基-烷基酮、烷基-芳基酮、芳基-芳基酮...; 关键词：仲酰胺酮有机铈试剂分子活化 C—C键形成还原酰化

国家重点基础研究发展计划(2010CB833200)